Enzymatic Synthesis of a Diastereomer of Neoabyssomicin Derivative Using the Diels-Alderase AbyU

Main observation and conclusion The enzyme AbyU catalyses a Diels-Alder (DA) reaction during abyssomicin C biosynthesis.In this study,AbyU is shown to convert t...     

双极性固态直线变压器驱动器的研制

在针对脉冲电磁场肿瘤消融的应用场合,双极性脉冲比单极性脉冲效果更均匀,而要产生ns级前沿的双极性高压纳秒或亚微秒脉冲难度大,电磁干扰强,控制要求更高。设计了一台双极性全固态直线型变压器驱动源(SSLTD),双极性SSLTD由结构完全相同的LTD模块经过副边绕组反向串联构成,在负载上实现双极性窄脉冲。双极性SSLTD输出波形稳定的脉冲的关键在于磁芯复位,通过电阻负载实验,重点对比分析了复位电流的形式对复位效果的影响,以及采用直流复位时幅值、脉宽、正负脉冲时间间隔、单级模块中开关管并联数量、复位电流大小对双极性SSLTD输出的影响。实验结果表明,所设计的双极性SSLTD能够在500 Ω负载上稳定产生重频双极性纳秒脉冲,输出电压0～±5 kV可调,脉宽200～400 ns可调,正负脉冲时间间隔0～1 ms可调,上升沿和下降沿20～50 ns;反向串联的直流复位电路结构简单、复位效果好。该脉冲源使用模块化设计,结构紧凑,电气绝缘要求较低,可灵活输出双极性、正极性与负极性高压亚微秒脉冲。     

1.54μmEr3+,Yb3+共掺玻璃激光器的速率方程及数值分析

LD抽运共掺Er,Yb玻璃激光器中的跃迁过程较复杂,针对双掺离子之间的能量传递和Er3+的多种跃迁过程,给出了详细的准三能级系统的速率方程,在合理简化后进行了数值分析,分析了Er3+掺杂浓度和介质长度、抽运光斑、输出镜透过率、谐振腔长、抽运光的椭圆度等因素对激光阈值及斜率效率的影响. 关键词： 1.54μm激光 Er3+玻璃 速率方程 数值分析     

等离子体喷射X光时空分辨测量

在“神光”强激光装置上对０．５３μｍ激光产生的等离子体喷射进行了Ｘ光时空分辨诊断。首次利用多针孔阵列成像技术结合软Ｘ光扫描相机观察激光加热区和Ｘ光加热区等离子体的运动，获得了初级和次级等离子体膨胀速度等结果．     

Highly efficient toughening effect of ultrafine full-vulcanized powdered rubber on poly(lactic acid)(PLA)

A unique ultrafine full-vulcanized powdered ethyl acrylate rubber (EA-UFPR) was used as the toughening modifier for poly (lactic acid) (PLA). Largely improved tensile toughness was successfully achieved with the incorporation of only 1 wt% EA-UFPR, while the tensile strength and modulus of the blends were almost the same as pure PLA. The highly efficient toughening of PLA by UFPR is mainly ascribed to the strong interfacial interaction between PLA and UFPR and good dispersion of UFPR particles in PLA matrix. Our work provides an effective toughening method to largely improve the mechanical properties of PLA without sacrificing its stiffness, which is very important for the wide application of PLA materials.     

火焰原子吸收光谱法测定饲料级硫酸盐中的铜

建立了火焰原子吸收光谱法测定饲料级硫酸盐中铜的方法,讨论了共存离子的干扰情况.在最佳实验条件下,该方法测定铜的特征浓度为0.019μg/mL,相对标准偏差为0.24％,样品加标回收率为99.2％-105.6％.被分析的饲料级硫酸盐中的共存离子对铜的测定基本无干扰.方法简便、快速,具有较高的准确度和精密度,适合用于饲料级硫酸盐中微量铜的测定.     

Impacts of air pressure on the evolution of nanosecond pulse discharge products

Based on the nonequilibrium plasma dynamics of air discharge, a dynamic model of zero-dimensional plasma is established by combining the component density equation, the Boltzmann equation, and the energy transfer equation. The evolution properties of nanosecond pulse discharge (NPD) plasma under different air pressures are calculated. The results show that the air pressure has significant impacts on the NPD products and the peak values of particle number density for particles such as O atoms, O3 molecules, N2(A3) molecules in excited states, and NO molecules. It increases at first and then decreases with the increase of air pressure. On the other hand, the peak values of particle number density for N2(B3) and N2(C3) molecules in excited states are only slightly affected by the air pressure.     

掺杂对CH样品Rayleigh-Taylor不稳定性增长的影响

在神光II激光装置上进行了辐射驱动不同掺杂样品的单模Rayleigh-Taylor(RT)不稳定性实验.结果显示:与纯碳氢(CH)样品相比,掺Br的CH样品的扰动更早、更快地进入非线性区,产生二次谐波,并且掺Br比例越高,CH样品扰动进入非线性区的时间越早,相同时刻扰动的二次谐波的幅度越高.这是因为密度梯度效应抑制了二次谐波的产生,掺Br比例越高,密度梯度标长越小;同时密度梯度效应还抑制三次谐波对基模增长的负反馈,造成基模具有更大的线性增长,导致线性饱和幅值大于经典值0.1λ.     

黄芩素激发态分子内质子转移耦合电荷转移反应的实验和理论研究

通过稳态光谱实验和量子化学计算相结合,研究了黄芩素激发态质子转移耦合电荷转移的反应. 实验和计算中S₁态吸收峰的缺失表明S₁态是暗态. S₁暗态导致在实验中观察不到黄芩素在乙醇溶液中的荧光峰,且固体的荧光峰很弱. 黄芩素分子的前线分子轨道和电荷差异密度表明S₁态是电荷转移态,然而S₂态是局域激发态. 计算的黄芩素分子的势能曲线在激发态只有一个稳定点,这表明了黄芩素激发态分子内质子转移的过程是一个无     

广义线性回归极大似然估计的强相合性

设有该文第1节所描述的广义线性回归模型,以$\underline{\lambda}_n$和$\overline{\lambda}_n$分别记$\sum\limits_{i=1}^{n}Z_iZ_i^{\prime}$的最小和最大特征根,$\hat{\beta}_n$记$\beta_0$的极大似然估计.在文献[1]中,当\{$Z_i,i\ge1$\}有界时得到$\hat{\beta}_n$强相合的充分条件,在自然联系和非自然联系下分别为$\underline{\lambda}_n\rightarrow\infty$, $(\overline{\lambda}_n)^{1/2+\delta}=O(\underline{\lambda}_n)$（对某$\delta>0$)以及$\underline{\lambda}_n\rightarrow\infty$, $\overline{\lambda}_n=O(\underline{\lambda}_n)$.作者将后一结果改进为只要求$(\overline{\lambda}_n)^{1/2+\delta}=O(\underline{\lambda}_n)$,从而与自然联系情况下的条件达到一致.