C60二取代化合物与环状二卟啉相互作用研究

通过紫外-可见吸收光谱研究了环状二卟啉与trans-2,trans-3,trans-4和e型4种吡咯烷二取代C₆₀衍生物（bis-C₆₀）异构体之间的弱相互作用。研究表明,吡咯烷取代基团的引入使富勒烯与二卟啉的结合常数按C₆₀ >单取代C₆₀ >二取代C₆₀的顺序降低。4种bis-C₆₀与二卟啉的结合常数变化顺序为trans-2 >trans-3≈trans-4> e,表明2个取代基间的相对位置对二取代C₆₀与环状二卟啉间作用有一定影响,分析认为主,客体分子间空间位阻效应的差异是导致这一变化的主要原因。以trans-3 bis-C₆₀/二卟啉复合物为代表,通过密度泛函理论模拟了其几何结构和吸收光谱。     

Canonical Quantization of Field Theories with Boundaries

The problem of canonical quantization of singular systems in a finite volume is studied by analysing a non-relativistic field theory. Firstly, we take the boundary conditions (BCs) as primary Dirac constraints. The quantization is performed canonically using Dirac’s procedure. Then, we quantize this model canonically in the classical solution space. We show that these two different quantization schemes are equivalent although they start from different settings.     

点对点移动水声通信技术研究

点对点移动水声通信是实现由活动和静止节点共同构成的水声数据通信网的关键技术之一. 对移动水声通信声信道特性进行了分析,指出不同途径到达的声线对应的多普勒频偏不一致,进一步加大了多途扩展产生的码间干扰的复杂性,不利于水声通信. 提出单阵元被动式相位共轭镜信道均衡技术,可实时自动补偿多普勒频偏,并聚焦多途信号. 将单阵元被动式相位共轭应用于Pattern时延差编码移动水声通信系统,进行了移动水声通信试验,湖试结果验证了其消除码间干扰性能及本文水声通信系统的鲁棒性. 关键词： 移动水声通信 被动式相位共轭镜 时变信道 码间干扰     

In situ lattice tuning of quasi-single-crystal surfaces for continuous electrochemical modulation

The ability to control the atomic-level structure of a solid represents a straightforward strategy for fabricating high-performance catalysts and semiconductor materials. Herein we explore the capability of the mechanically controllable surface strain method in adjusting the surface structure of a gold film. Underpotential deposition measurements provide a quantitative and ultrasensitive approach for monitoring the evolution of surface structures. The electrochemical activities of the quasi-single-crystalline gold films are enhanced productively by controlling the surface tension, resulting in a more positive potential for copper deposition. Our method provides an effective way to tune the atom arrangement of solid surfaces with sub-angstrom precision and to achieve a reduction in power consumption, which has vast applications in electrocatalysis, molecular electronics, and materials science.

We reported a new method capable of adjusting the lattice structure of solid surfaces with sub-angstrom precision and achieved in situ and continuous control over electrochemical activity.     

含1,2,3-噻二唑的邻甲酰胺基苯甲酰胺类化合物的合成、晶体结构与生物活性

以取代邻氨基苯甲酸为起始原料, 设计并合成了一系列未见文献报道的含1,2,3-噻二唑的邻甲酰胺基苯甲酰胺类化合物. 所有化合物的结构均经元素分析和1H NMR确证, 并且采用X射线单晶衍射分析方法测定了化合物7g的结构. 初步的生物活性试验结果表明, 部分化合物具有一定的杀菌活性.