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91.
Yasumitsu Tamura Yasuyoshi Miki Jun-Ichi Minamikawa Masazunu Ikeda 《Journal of heterocyclic chemistry》1974,11(5):675-679
The mono-N-amino salts of 3-phenylcinnoline, phthalazine, 1-phenylphthalazine, 4-phenylquinazoline, 2-phenylquinoxaline, 1,5- and 1,8-naphthyridines are in high yields prepared by direct N-amination of the parent heterocycles with O-mesitylenesulfonylhydroxylamine. With the one expection of 3-phenylcinnoline, the site of N-amination was determined by mass and nmr spectral techniques. The results indicate that the N-amination occurs preferentially at the least sterically hindered nitrogen atom. 相似文献
92.
93.
H. Suematsu K. Ohmatsu K. Sugiyama T. Sakakibara M. Motokawa M. Date 《Solid State Communications》1981,40(3):241-243
The whole magnetization curve of the first stage compound C6Eu has been measured by using pulsed fields up to 400 kG below 40 K. For H ⊥ c, c being the crystal c-axis, four regions are observed in the magnetization curve; I) the initial magnetization region with an apparent moment of ~ 0.6microB per Eu ion (H < 12 kG), II) the intermediate region with nearly constant moment of 2.2 – 2.7 microB, which corresponds to the full moment of Eu2+ ion (22 < H < 82 kG), III) the region of a linear field dependence (82 < H < 205 kG), and IV) the saturation region above 205 kG, where the saturation moment is found as 6.2 microB. For H//c, the magnetization increases monotonically and approaches to a saturation value corresponding to 6 microB above 240 kG. 相似文献
94.
Subwavelength optical imaging through a metallic nanorod array 总被引:1,自引:0,他引:1
We propose a subwavelength imaging system without a lens or a mirror but with an array of metallic nanorods. The near-field components of dipole sources were plasmonically transferred through the rod array to reproduce the source distribution in the other side. We calculated the field distribution at the different planes of imaging process using the finite-difference time-domain algorithm and found that the spatial resolution was 40 nm given by the rod size and spacing. A typical configuration is a hexagonal arrangement of silver rods of 50 nm height and 20 nm diameter. We also show that the image formation highly depends on the coherence and the polarization of the source distribution and the source-array distance. 相似文献
95.
To explore the structure-dependent hydrogen abstraction in antiparallel and parallel G-quartet DNA structures, the photochemical reactivity of 5-iodouracil ((I)U)-containing human telomeric DNA 22-mers was investigated under the 302 nm UV irradiation conditions. We discovered that only antiparallel ODN 4, in which the second T residue in the diagonal loop of the antiparallel G-quartet is substituted with (I)U, was rapidly consumed as compared with parallel ODN 4 and the other (I)U-containing 22-mers under the irradiation conditions. Product analysis of the photolyzate of antiparallel ODN 4 indicated that a 2'-deoxyribonolactone residue was effectively produced at the 5' side of the (I)U residue in the diagonal loop. Photochemical 2'-deoxyribonolactone formation was also found in the (I)U-containing diagonal loop of antiparallel G-quartets d(GGGGTTT(I)UGGGG)(2) and d(GGGGTT(I)UTGGGG)(2), whereas the reaction did not occur at other DNA structures, including the single-stranded form, the loop region of the hairpin, and linear four-stranded G-quartets. The results clearly indicate that this type of 2'-deoxyribonolactone formation efficiently occurrs only in the diagonal loop of the antiparallel G-quartet. Furthermore, we found that 2'-deoxyribonolactone was formed at the (I)U-containing G-rich sequence of the IgG switch regions and the 5' termini of the Rb gene, suggesting the formation of an antiparallel G-quartet with a diagonal loop in these sequences. These results suggest that the present photochemical method can be used as a specific probe for the antiparallel G-quartet with the diagonal loop. 相似文献
96.
Acceleration waves propagating in isotropic solids at finite temperatures are studied by applying the method of singular surfaces to a new continuum model derived statistical-mechanically from a three-dimensional lattice model. The continuum model explicitly takes into account the microscopic thermal vibrations of the constituent atoms as one of the field variables. The propagation speeds and the ratios of mechanical and thermal amplitudes for both longitudinal and transverse waves are consistently determined. The differential equations that govern the time variation of the amplitudes of the waves are also derived. The analytical results, which are valid over a wide temperature range that includes the melting point, are evaluated numerically for several materials, and their physical implications are discussed. One of the findings to be emphasized is that of the singularities of the characteristic quantities at the melting point.Received: 13 March 2003, Accepted: 20 June 2003PACS:
62.30. + d, 65.40.-bM. Sugiyama: Correspondence to
Dedicated to Prof. Ingo Müller on the occasion of his 65th birthday. 相似文献
97.
[reaction: see text] Naphthopyran derivatives with aminoxyl substituents (4a,b) gave the corresponding open-formed isomers (5a,b) by irradiation, which could be changed back to the starting closed-formed naphthopyrans by the treatment with SiO(2) as a catalyst. The tuning of intermolecular magnetic interactions between the isomer couples was found to be possible in these reversible systems. 相似文献
98.
Let A be a finite-dimensional algebra over a field k. The derived Picard group DPic
k
(A) is the group of triangle auto-equivalences of D>
b( mod A) induced by two-sided tilting complexes. We study the group DPic
k
(A) when A is hereditary and k is algebraically closed. We obtain general results on the structure of DPic
k
, as well as explicit calculations for many cases, including all finite and tame representation types. Our method is to construct a representation of DPic
k
(A) on a certain infinite quiver irr. This representation is faithful when the quiver of A is a tree, and then DPic
k
(A) is discrete. Otherwise a connected linear algebraic group can occur as a factor of DPic
k
(A). When A is hereditary, DPic
k
(A) coincides with the full group of k-linear triangle auto-equivalences of Db( mod A). Hence, we can calculate the group of such auto-equivalences for any triangulated category D equivalent to Db( mod A. These include the derived categories of piecewise hereditary algebras, and of certain noncommutative spaces introduced by Kontsevich and Rosenberg. 相似文献
99.
100.