稀土-赤霉素配合物的合成与光谱表征

为了研究稀土与赤霉素的相互作用及其生物效应,在乙醇溶液中合成了两种新型稀土(Sm,Dy)-赤霉素(GA3)配合物,并对其进行了元素分析、质谱、紫外光谱、红外光谱、差热分析等表征。结果表明:配合物的组成为RE(GA3-)2Cl.6H2O(RE:Sm3+,Dy3+),镝-赤霉素配合物的热稳定性略高于钐-赤霉素配合物的。所得的两种配合物均易溶于二甲基甲酰胺、二甲基亚砜、甲醇、乙醇,不溶于水和丙酮中。     

稀土元素在含残余砷、锡09Cr2AlMoRE钢中的作用

对加稀土前后09Cr2AlMoRE钢取样分析化学成分,制备金相样用SEM-EDS研究了钢中析出物特征,制备透射电镜(TEM)试样通过TEM研究元素的晶界偏聚,并用热力学计算了稀土Ce,La,S和残余元素As反应固定残余元素As的可能性。研究结果表明:在低氧、硫的条件下,稀土镧可以和09Cr2AlMoRE钢中较低含量的砷(130×10-6)作用生成镧砷金属间化合物;铈、镧主要是通过形成稀土砷硫夹杂物固定钢中残余元素砷。另外,在本实验条件下稀土元素(64×10-6)只有很微量的偏聚在晶界,残余元素As不在晶界偏聚。     

微波消解样品-火焰原子吸收光谱法测定焦炭灰中钾、钠含量

0.100 0g焦炭灰样品经氢氟酸-硝酸(1+3)溶液8mL消解,用火焰原子吸收光谱法测定其中钾和钠的含量。钾和钠的质量浓度分别在4mg.L-1及2mg.L-1以内与其吸光度呈线性关系,检出限(3σ)分别为12μg.L-1及6μg.L-1。方法用于分析焦炭灰标准物质,测定值与认定值相符,钾和钠的相对标准偏差(n=11)依次在2.7%～3.8%和1.3%～3.1%之间。     

共沉淀富集-氢化物发生-原子荧光光谱法测定山药中砷和硒含量

山药样品经硝酸和过氧化氢微波消解后,所得消解液在pH 11～12的介质中,加入0.1mol.L-1氯化镧溶液达到共沉淀分离,所得沉淀经离心分离后用盐酸(1+1)溶液溶解,并用于氢化物发生-原子荧光光谱法分析。砷和硒的质量浓度均在40.0μg.L-1以内与荧光强度呈线性关系,方法的检出限(3σ)依次为砷0.014μg.L-1和硒0.022μg.L-1。应用此法对山药样品进行分析,测得砷和硒的回收率分别为102%,96.8%。     

水声通信中基于信道辨识的盲turbo均衡方法

水声信道多途效应明显,造成接收信号存在严重的码间干扰(ISI,Intersymbol interference)。基于最小均方误差(MMSE,Minimum mean square error)准则的turbo均衡器级联了均衡和信道译码,能够有效去除ISI,并获得优良的性能。由于水声信道的时变性,传统MMSE-turbo均衡需要周期性的训练序列,以实现连续可靠的通信。训练序列虽然提高了通信的可靠性,但降低了信息的有效传输速率。因此,为提高通信效率,本文提出了一种盲turbo均衡方法,该方法通过引入新的盲信道辨识器来同时获得信道估计响应和已去除部分ISI的初步均衡输出信号,并为turbo均衡提供初始的响应参数和比特软信息。与水声通信中应用较多的盲判决反馈均衡器(DFE,Decision feedback equalizer)相比,海上实验结果证明本文提出的盲turbo均衡方法抗信道多途衰落的能力较强,并且与传统MMSE-turbo均衡相比无需训练序列,因此提高了信息的有效传输速率。     

Efficient approach to allylated quinolines via palladium-catalyzed cyclization–allylation of 1-azido-2-(2-propynyl) benzenes with allyl methyl carbonate

The palladium-catalyzed cyclization–allylation reaction of ortho-azido propynylbenzenes 1 and allyl methyl carbonate 2d gives the corresponding allylated quinolines in moderate to good yields. The reaction of 1-azido-2-(2-propynyl)benzene 1a proceeds smoothly with 10 mol % Pd(PPh₃)₄ and 5 equiv K₃PO₄ or NaOAc in DMF at 100 °C to afford 3,4-diallylquinoline 3a in 69% yield in the case of R² = H and 3-allylquinoline 4 in 67% yield in the case of R² ≠ H.     

Synthesis and characterization of a fluorescent adenosine derivative for detection of intermolecular RNA G-quadruplexes

We synthesized a fluorescent adenosine derivative, rA^py, as a probe to study RNA structural transitions, in particular the intermolecular G-quadruplex formation. rA^py was incorporated into the dangling positions of guanine-rich oligonucleotides, which under physiological conditions undergo π-stacking on top of each other exhibiting a strong emission signal in their G-quadruplex conformation, but not in their single-stranded state.     

Synthesis and application of moisture-stable methallylsilanated phosphorylcholine as a surface modifier

New methallylsilanated phosphorylcholine (MASPCs) were synthesized via a copper-catalyzed ‘click’ reaction and demonstrated excellent moisture stability. Hydroxylated silicon compounds, silanol, and silica were grafted or modified by MASPCs in the presence of triflic acid (TfOH) and they possessed a good grafting efficiency and high loading rate.     

Divergent strategy in natural product total synthesis

Divergent strategy in natural product synthesis allows the comprehensive synthesis of family natural products. Efficient formulation of this idea requires the biosynthetic/biosynthesis-inspired insight toward the well-orchestrated design of a pluripotent late-stage intermediate, in concomitant with the applicability of the intermediates for versatile transformations. This digest focuses on the actual applications of those strategies in natural product synthesis with an emphasis on the recipes for the choice of the common intermediates.     

Two Coordination Polymers Constructed from 5‐(4‐Pyridyl)‐1H‐tetrazole Ligands with Different Organic Carboxylates: Structure and Luminescence Properties

Two coordination polymers (CPs), namely, [Cu(Hptz)₂(Hhba)₂]_n ( 1 ) [Hptz = 5‐(4‐pyridyl)‐1H‐tetrazole, H₂hba = 2‐hydroxybenzoic acid] and [Zn₃(ptz)₂(hpa)₂]_n ( 2 ) (H2hpa = 2‐hydroxy‐2‐phenylacetic acid), were synthesized by solvothermal reactions. Both complexes were characterized by elemental analysis, infrared spectroscopy, powder X‐ray diffraction, thermogravimetric analysis, and single‐crystal X‐ray diffraction analysis. Compound 1 exhibits a 2D (4,4) network, where each layer connects to four adjacent layers to construct a 3D supramolecular framework. Compound 2 has a 3D framework structure composed of 1D SUBs, which are formed by both carboxyl and tetrazole groups. The complexes represent two rare examples of CPs constructed from Hptz and organic carboxyl acid ligands. Complex 2 exhibits intense, red‐shifted emissions in the visible region at room temperature.