Synthesis and characterization of wholly aromatic poly(azomethine)s containing donor–acceptor triphenylamine moieties

N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine was synthesized from N‐(4‐nitrophenyl)‐diphenylamine by the Vilsmeier‐Haack reaction. Soluble aromatic poly(azomethine)s (PAMs) were prepared by the solution polycondensation of N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine and aromatic diamine in N‐methyl‐2‐pyrrolidone (NMP) at room temperature under reduced pressure. All the PAMs are highly soluble in various organic solvents, such as N,N‐dimethylacetamide (DMAc), chloroform (CHCl₃), and tetrahydrofuran (THF). Differential scanning calorimetry (DSC) indicated that these PAMs had glass‐transition temperatures (T_gs) in the range of 170–230 °C, and a 10% weight‐loss temperatures in excess of 490 °C with char yield at 800 °C in nitrogen higher than 60%. These PAMs in NMP solution showed UV‐Vis charge‐transfer (CT) absorption at 405–421 nm and photoluminescence peaks around 462–466 nm with fluorescence quantum efficiency (Φ_F) 0.10–0.99%. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels of these PAMs can be determined from cyclic voltammograms as 4.86–5.43 and 3.31–3.34 eV, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4921–4932, 2007     

年龄相关的种群扩散系统的最优分布控制

本文讨论年龄相关的种群扩散系统的最优分布控制 ,证明了最优分布控制的存在性 ,得到了分布控制为最优的充分必要条件及确定最优控制的最优性组 .     

Stationary Intensity Distribution of Single-Mode Laser Driven by Additive and Multiplicative Colored Noises with Colored Cross-Correlation

Applying the approximate Fokker-Planck equation we derived, we obtain the analytic expression of thestationary laser intensity distribution Pst(Ⅰ) by studying the single-mode laser cubic model subject to colored cross-correlation additive and multiplicative noise, each of which is colored. Based on it, we discuss the effects on the stationarylaser intensity distribution Pst(Ⅰ) by cross-correlation between noises and “color“ of noises (non-Markovian effect) whenthe laser system is above the threshold. In detail, we analyze two cases: One is that the three correlation-times (i.e.the self-correlation and cross-correlation times of the additive and multiplicative noise) are chosen to be the same value(τ1 = τ2 = τ3 = τ). For this case, the effect of noise cross-correlation is investigated emphatically, and we detect thatonly when λ≠ 0 can the noise-induced transition occur in the Pst(Ⅰ) curve, and only when τ≠ 0 and λ≠ 0, can the“reentrant noise-induced transition“ occur. The other case is that the three correlation times are not the same value,τ1 ≠τ2 ≠τ3. For this case, we find that the noise-induced transition occurring in the Pst (Ⅰ) curve is entirely differentwhen the values of τ1, τ2, and τ3 are changed respectively. In particular, when τ2 (self-correlation time of additivenoise) is changing, the ratio of the two maximums of the Pst(Ⅰ) curve R exhibits an interesting phenomenon, “reentrantnoise-induced transition“, which demonstrates the effect of noise “color“ (non-Markovian effect).     

Hg1-xCdxTe/Cd1-zZnzTe的X射线反射率及半峰全宽的动力学研究

X射线衍射摇摆曲线的计算机模拟是一种获得材料晶体质量参量的有效方法，其中材料本征摇摆曲线的计算是计算机模拟的基础。用X射线动力学理论计算了Hg1-xCdxTe和Cd1-zZnzTe本征反射率曲线，并研究了组分、膜厚分别对本征反射率和半峰全宽的影响。结果表明Hg1-xCdxTe和Cd1-zZnzTe的本征反射率和半峰全宽与材料组分和厚度有明显的依赖关系，且该依赖关系取决于X射线在材料中的散射和吸收的相对强弱。薄膜的厚度也是直接影响本征摇摆曲线峰形、半峰全宽和反射率的重要因素，当薄膜厚度小于穿透深度时，表征本征反射率曲线的各个参量均与薄膜厚度有直接的关系。对于(333)衍射面，碲镉汞材料厚度大于7μm后，本征反射率和半峰全宽将不再发生明显变化。     

FREE BOUNDARY PROBLEM ARISING FROM EVAPORATION FROM POROUS MEDIUM

ＦＲＥＥＢＯＵＮＤＡＲＹＰＲＯＢＬＥＭＡＲＩＳＩＮＧＦＲＯＭＥＶＡＰＯＲＡＴＩＯＮＦＲＯＭＰＯＲＯＵＳＭＥＤＩＵＭＹＡＮＧＬＩＰＩＮＧ（杨力平）（ＤｅｐａｒｔｍｅｎｔｏｆＡｐｐｌｉｅｄＭａｔｈｅｍａｔｉｃｓ，ＴｓｉｎｇｈｕａＵｎｉｖｅｒｓｉｔｙ，Ｂｅ...     

第Ⅰ种强度不对称三态叠加多模叠加态光场N次方Y压缩—第一正交相位分量的压缩情况

根据量子力学中的线性叠加原理,构造了由三个强度不等的多模相干态光场|{Z_j^(A)}>_q、|{Z_j^(B)}>_q和|{Z_j^(C)}>_q的线性叠加所组成的第Ⅰ种强度不对称三态叠加多模叠加态光场|ψ_l^(ABC)>_q.利用多模压缩态理论,研究了态|ψ_l^(ABC)>_q的第一正交方分量(即磁场分量)的广义非线性等幂次N次方Y压缩特性.结果发现:①在上述各多模相干态光场中各模的强度和各模的初始相位各不相等的情况下,态|ψ_l^(ABC)>_q的第一正交分量-磁场分量在一定的条件下,总可呈现出周期性变化的、任意等幂次的N次方Y压缩效应;②当上述各多模相干态光场的强度和各模的初始相位相等时,态|ψ_l^(ABC)>_q的磁场分量的N次方Y压缩现象消失,态|ψ_l^(ABC)>_q可恒处于等幂次N-Y最小测不准态.     

亚细胞器诱导的2,4,6-三硝基甲苯阴离子自由基的ESR研究

本文在无氧条件下利用ESR分别观察了肝脏和晶状体的微粒体及线粒体酶在NADPH存在下还原三硝基甲苯(TNT)的过程,检测到参数为g=2.0048±0.0005,A_对位~N=1.215mT,A~N=0.800±0.010mT,A~H=0.122±0.0206mT的自由基信号,并通过电子计算机对ESR谱的模拟证明该自由基信号为TNT硝基阴离子自由基,根据其超精细分裂常数认为,其不配对电子的电子云密度主要分布在对位硝基上。     

非线性物理简介:8.光学孤子及其在光纤通讯中的应用

本文介绍了光学孤子的形成、特性及其在光纤通讯中的应用．