The quark spin structure of the nucleon

Some non-perturbative aspects of the nucleon quark spin structure are reviewed. The first part is a brief summary of early theoretical developments in the field of polarized deep inelastic scattering of electrons on polarized nucleons and an illustration of the non-perturbative power of lattice QCD 25 years later. The second part is a short pedagogical introduction to the analysis of high energy scattering in the complex angular momentum plane, with particular emphasis on spin-dependent deep inelastic electron-nucleon scattering. The third part comprises a brief introduction to lattice QCD and its applications in the non-perturbative determination of the spin-dependent structure functions.     

Molecular Recognition with Model Systems

How structures fit together is the principal domain of molecular recognition, and current studies are evolving from the host–guest chemistry of ions to interactions between two molecules. Recent advances in the synthesis of sizable concave molecules, especially those featuring convergent functional groups, make it possible to bind smaller convex structures with considerable selectivity. One result is that hydrogen bonding can be addressed in model systems. The present review emphasizes the use of cleftlike structures as a means of probing the forces involved in nucleic acid recognition. The application of such molecules to the catalysis of chemical reactions, particularly those involved in self-replicating systems, is also described. Some implications for future pharmaceutical agents are suggested as a result of access to synthetic receptors for biologically relevant targets.     

An adjoint-based pressure correction scheme

Incompressible flows are solenoidal, i. e. the divergence of the flow field is zero. This is an algebraic constraint on the solution in time. The pressure has to be determined, so that the constraint is fulfilled. To calculate the pressure often a Poisson equation is derived, which is then solved by an iterative method. Instead of this the constraint is here formulated as an optimization problem. The objective functional is taken as the square of the norm of the divergence. A gradient based optimization is performed to calculate the pressure in every time step of the simulation. By this an alternative iterative scheme is derived. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

A carbohydrate-conjugated deep cavitand permits observation of caviplexes in human serum

A deep cavitand was covalently modified with carbohydrates to provide solubility in biologically relevant environments and to investigate its receptor function. Specifically, a tetrakis(β-D-glucosyl) cavitand (1) that was soluble in neutral water or acid/base-buffered solutions was synthesized, and it formed complexes with hydrophobic small molecules. Extraction of the cavitand into aqueous sodium dodecyl sulfate micelles as simple membrane mimetics increased the scope of guests bound by 1 beyond that observed in only aqueous media. Complex formation was also detected in human serum. The findings show the functional compatibility of the receptor in both micelle-bound and serum-soluble forms.     

Ueber die Darstellung von arsenfreiem Wismuthmetall und das Atomgewicht des Wismuths

Ohne Zusammenfassung     

Ueber das Verhalten von Chlor-, Brom- und Jodsilber gegen Brom und Jod

Ohne Zusammenfassung     

Ueber Kupferoxydhydrat

Ohne Zusammenfassung     

Über Diresorcin und Diresorcinphtalëin

Ohne Zusammenfassung