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61.
The intramolecular Diels-Alder reaction of N-3,5-hexadienoyl ethyl acrylimidates provides an efficient method for the synthesis of cis-fused hexahydroisoquinolones. As a demonstration of the stereochemical control offered by this cycloaddition, two approaches to the construction of the DE rings of reserpine are reported. In the second entry, N-((4-(trimethylsilyl)ethoxymethoxy)methyl-6-benzyloxy-3Z,5E-hexadienoyl)-1-aza-2-ethoxy-1,3-butadiene (40) undergoes cycloaddition to produce as the major product (4aS,7R,8aS)-7-benzyloxy-5-((2-trimethylsilyl)ethoxymethoxy)methyl-3,4,4a,7,8,8a-hexahydroisoquinol-3-one (41). Cycloadduct 41 is then stereospecifically elaborated to (4aS,5S,6R,7R,8aR)-6-methoxy-5-methoxycarbonyl-7-(3,4,5-trimethoxy)benzoyldecahydroisoquinoline-2-carboxylic acid methyl ester (3), a key intermediate previously transformed to reserpine. 相似文献
62.
The microwave spectrum has been investigated for the molecule of Benzenesulphonyl chloride within the 8–18 Ghz frequency region. Several a and b type bands corresponding to the Cl35 and Cl37 Isotopes were observed and assigned. We have also used the CNDO/2 method in order to estimate some molecular parameters and the dipole moment. The theoretical calculation and the experimental data have been joined to derive a reliable structure of the molecule concluding that the Cl is located on the plane of the benzene ring. 相似文献
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Vitor Matos Julio D. Silva Dan Marchesin 《Bulletin of the Brazilian Mathematical Society》2016,47(2):545-559
Themain goal of ourwork is to showthat there exists a class of 2×2 Riemann problems for which the solution comprises a singlewave group for an open set of initial conditions. This wave group comprises a 1-rarefaction joined to a 2-rarefaction, not by an intermediate state, but by a doubly characteristic shock, 1-left and 2-right characteristic. In order to ensure that perturbations of initial conditions do not destroy the adjacency of the waves, local transversality between a composite curve foliation and a rarefaction curve foliation is necessary. 相似文献
64.
Unexpected reactivity of pyridinium salts toward alkynyl Fischer complexes to produce oxo‐heterocycles 下载免费PDF全文
María Inés Flores‐Conde Fabiola N. de la Cruz Julio López J. Óscar C. Jiménez‐Halla Eduardo Peña‐Cabrera Marcos Flores‐Álamo Francisco Delgado Miguel A. Vázquez 《应用有机金属化学》2018,32(3)
The unprecedented reaction of ketone‐containing aromatic pyridinium salts 3a ‐ e and alkynyl Fischer complexes 1a ‐ f proceeds via a mild domino process to provide 4,6‐disubstituted pyran‐2‐ones 5a ‐ k and 2,3,5‐trisubstituted furans 6a ‐ h (45‐97%). According of the results of isotopic labeling experiments, a mechanism involving an initial Michael addition appears to be the key step, obtaining a mesomeric structure responsible for the formation of both products. 相似文献
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Nonlinear Dynamics - In this paper, type V intermittency is studied using the M function methodology developed in the last years. This methodology is applied on two different maps to evaluate the... 相似文献
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