Multistep ionization of argon clusters in intense femtosecond extreme ultraviolet pulses

The interaction of intense extreme ultraviolet femtosecond laser pulses (lambda = 32.8 nm) from the FLASH free electron laser (FEL) with clusters has been investigated by means of photoelectron spectroscopy and modeled by Monte Carlo simulations. For laser intensities up to 5x10(13) W/cm(2), we find that the cluster ionization process is a sequence of direct electron emission events in a developing Coulomb field. A nanoplasma is formed only at the highest investigated power densities where ionization is frustrated due to the deep cluster potential. In contrast with earlier studies in the IR and vacuum ultraviolet spectral regime, we find no evidence for electron emission from plasma heating processes.     

High temperature mechanical field-cycling setup

A new design of a mechanical field-cycling setup, operating in the wide temperature range up to 1200 K has been implemented. The sample is moved by a stepping motor in the stray field of a superconducting magnet inside a furnace of homogeneous temperature profile. For a field range from 0.75 to 7 T (transfer length 24 cm), the transfer time is less than 100 ms. The temperature profile is homogenized to better than 1% of the absolute set temperature. The main objective of this design is to extend the T1 relaxation dispersion range covered by electronic field-cycling to higher frequencies.     

Precise predictions for same-sign W-boson scattering at the LHC

Vector-boson scattering processes are of great importance for the current run-II and future runs of the Large Hadron Collider. The presence of triple and quartic gauge couplings in the process gives access to the gauge sector of the Standard Model (SM) and possible new-physics contributions there. To test any new-physics hypothesis, sound knowledge of the SM contributions is necessary, with a precision which at least matches the experimental uncertainties of existing and forthcoming measurements. In this article we present a detailed study of the vector-boson scattering process with two positively-charged leptons and missing transverse momentum in the final state. In particular, we first carry out a systematic comparison of the various approximations that are usually performed for this kind of process against the complete calculation, at LO and NLO QCD accuracy. Such a study is performed both in the usual fiducial region used by experimental collaborations and in a more inclusive phase space, where the differences among the various approximations lead to more sizeable effects. Afterwards, we turn to predictions matched to parton showers, at LO and NLO: we show that on the one hand, the inclusion of NLO QCD corrections leads to more stable predictions, but on the other hand the details of the matching and of the parton-shower programs cause differences which are considerably larger than those observed at fixed order, even in the experimental fiducial region. We conclude with recommendations for experimental studies of vector-boson scattering processes.     

Limit analysis,rammed earth material and Casagrande test

The present paper is concerned with the simulation of the Casagrande test carried out on a rammed earth material for wall-type structures in the framework of Limit Analysis (LA). In a preliminary study, the material is considered as a homogeneous Coulomb material, and existing LA static and kinematic codes are used for the simulation of the test. In each loading case, static and kinematic bounds coincide; the corresponding exact solution is a two-rigid-block mechanism together with a quasi-constant stress vector and a velocity jump also constant along the interface, for the three loading cases. In a second study, to take into account the influence of compressive loadings related to the porosity of the material, an elliptic criterion (denoted Cohesive Cam–Clay, CCC) is defined based on recent homogenization results about the hollow sphere model for porous Coulomb materials. Finally, original finite element formulations of the static and mixed kinematic methods for the CCC material are developed and applied to the Casagrande test. The results are the same than above, except that this time the velocity jump depends on the compressive loading, which is more realistic but not satisfying fully the experimental observations. Therefore, the possible extensions of this work towards non-standard direct methods are analyzed in the conclusion section.     

Coherently combined fiber laser system delivering 120 μJ femtosecond pulses

We report on the coherent combination of two chirped pulsed fiber lasers. The beams coming from two 100?μm core diameter ytterbium-doped rod-type fibers were coupled in a Mach-Zehnder-type interferometer by means of a polarization beam splitter. Active stabilization of the interferometer was achieved by using a piezo-mounted mirror driven by a H?nsch-Couillaud polarization detection system. Pulses with 120?μJ energy and a compressed duration of 800?fs were obtained. This, compared with the 66?μJ coming from each single amplifier, results in a combining efficiency as high as 91%.     

The effect of titanium dioxide on the biochemical constituents of the brain of Zebrafish (Danio rerio): an FT-IR study

During recent years, the use of nanoparticles (NPs) in commercial products and industrial applications has increased greatly. One of the most widely used nanoparticles is titanium dioxide (nTiO(2)). It is a very versatile compound that has many uses, depending on its particle size. In the present paper an attempt is made to study the effect of TiO(2) nanoparticles and its bulk material on the biochemical constituents of the brain of Zebrafish (Danio rerio) by using FT-IR technique. FT-IR spectra reveals significant differences in absorbance intensities between the control and TiO(2) exposed brain tissues, reflecting alterations on the major biochemical constituents such as proteins, lipids and nucleic acids in the brain tissues of D. rerio due to TiO(2) exposure. The results further reveal that TiO(2) nanoparticles are more toxic than their bulk counterparts. The higher ratio of integrated area of carbonyl-to-CH(2) peaks (1743 cm(-1):1458 cm(-1)) observed in the present study in the nTiO(2) exposed brain tissues suggests that lipids are being oxidized. Since oxidation can cause an increase in carbonyls and a degradation of lipids, both of these changes could be contributed to the elevated ratio. Further, the observed decreasing ratio of integrated areas of both 1458 cm(-1):1542 cm(-1) and 1743 cm(-1):1542 cm(-1) in the TiO(2) exposed tissues suggests that lipid degradation predominates over carbonyl formation. The observed changes in the biochemical constituents in the brain tissues of D. rerio could be due to the overproduction of ROS.     

Revisiting radiation patterns in e^+e^- collisions

We propose four simple event-shape variables for semi-inclusive $e^+e^- \rightarrow 4$ -jet events. The observables and cuts are designed to be especially sensitive to subleading aspects of the event structure, and allow to test the reliability of phenomenological QCD models in greater detail. Three of them, $\theta _{14}$ , $\theta ^*$ , and $C_2^{(1/5)}$ , focus on soft emissions off 3-jet topologies with a small opening angle, for which coherence effects beyond the leading QCD dipole pattern are expected to be enhanced. A complementary variable, $M_L^2/M_H^2$ , measures the ratio of the hemisphere masses in 4-jet events with a compressed scale hierarchy (Durham $y_{23}$ – $y_{34}$ ), for which subleading $1\rightarrow 3$ splitting effects are expected to be enhanced. We consider several different parton-shower models, spanning both conventional and dipole/antenna ones, all tuned to the same $e^+e^-$ reference data, and show that a measurement of the proposed observables would allow for additional significant discriminating power between the models.     

Summing large-N towers in colour flow evolution

We consider soft-gluon evolution in the colour flow basis. We give explicit expressions for the colour structure of the (one-loop) soft anomalous dimension matrix for an arbitrary number of partons, and we show how the successive exponentiation of classes of large- \(N\) contributions can be achieved to provide a systematic expansion of the evolution in terms of colour-suppressed contributions.     

SYNTHESE DE SELS DE VINYLPHOSPHONIUMS β-SUBSTITUES ET DE SELS D'ALKYLPHOSPHONIUMS β-DISUBSTITUES

Abstract

Vinylene-1,2 bisphosphoniums salts react, in the presence of a base, with compounds ZH having a mobile hydrogen, to give a way of synthesis of β-substituted vinylphosphoniums salts 2 or β-disubstituted alkylphosphoniums salts 3. We have studied the limits of these synthesis depending on the experimental conditions and the nature of compounds ZH (alcohols, phenols, thiols, phosphines, amines).

Les sels de vinylène-1,2 bisphosphoniums réagissent, en présence d'une base, avec les composés à hydrogène mobile ZH pour fournir ainsi une méthode d'obtention de sels de vinylphosphoniums β-substitués 2 ou de sels d'alkylphosphoniums β-disubstitués 3. Nous avons étudié les limites de ces synthèses en faisant varier les conditions opératoires et la nature des composés ZH (alcools, phénols, thiols, phosphines, amines).