The synthesis of d-C-mannopyranosides

This article reviews the different methods and highlights the general trends that have been developed to selectively obtain α- or β-d-C-mannopyranosides.     

A set of global bounded solutions for a Volterra system of retarded equations on \Bbb R3+ {\Bbb R}^3_+

It is proved the existence of a compact set , invariant under the flow of a Volterra system of retarded equations on , with lag r > 0; is homeomorphic to a solid tri-dimensional cylinder. The boundary of is the union of a closed bi-dimensional cylinder with two open disks (the two basis of the cylinder ). is the union of a continuous one-parameter family of r-periodic orbits of the retarded Volterra system and any r-periodic orbit of the retarded system is contained in . The flow, restricted to , of the system of retarded equations, is the flow of a C ¹-vector-field.     

Precise predictions for same-sign W-boson scattering at the LHC

Vector-boson scattering processes are of great importance for the current run-II and future runs of the Large Hadron Collider. The presence of triple and quartic gauge couplings in the process gives access to the gauge sector of the Standard Model (SM) and possible new-physics contributions there. To test any new-physics hypothesis, sound knowledge of the SM contributions is necessary, with a precision which at least matches the experimental uncertainties of existing and forthcoming measurements. In this article we present a detailed study of the vector-boson scattering process with two positively-charged leptons and missing transverse momentum in the final state. In particular, we first carry out a systematic comparison of the various approximations that are usually performed for this kind of process against the complete calculation, at LO and NLO QCD accuracy. Such a study is performed both in the usual fiducial region used by experimental collaborations and in a more inclusive phase space, where the differences among the various approximations lead to more sizeable effects. Afterwards, we turn to predictions matched to parton showers, at LO and NLO: we show that on the one hand, the inclusion of NLO QCD corrections leads to more stable predictions, but on the other hand the details of the matching and of the parton-shower programs cause differences which are considerably larger than those observed at fixed order, even in the experimental fiducial region. We conclude with recommendations for experimental studies of vector-boson scattering processes.     

Subnanometer-scale measurements of the interaction of ultrafast soft x-ray free-electron-laser pulses with matter

At the recently built FLASH x-ray free-electron laser, we studied the reflectivity of Si/C multilayers with fluxes up to 3 x 10(14) W/cm2. Even though the nanostructures were ultimately completely destroyed, we found that they maintained their integrity and reflectance characteristics during the 25-fs-long pulse, with no evidence for any structural changes over lengths greater than 3 A. This experiment demonstrates that with intense ultrafast pulses, structural damage does not occur during the pulse, giving credence to the concept of diffraction imaging of single macromolecules.     

Laser-polarized Xe NMR and MRI at Ultralow Magnetic Fields

Laser-polarized ¹²⁹Xe and a high-T_csuperconducting quantum interference device (SQUID) are used to obtain magnetic resonance images in porous materials at a magnetic field of 2.3 mT, corresponding to a Larmor frequency of 27 kHz. Image resolution of 1 mm is obtained with gradients of only 1 mT/m. The resolution of xenon chemical shifts in different physicochemical environments at ultralow fields is also demonstrated. Details of the circulating flow optical pumping apparatus and the SQUID spectrometer are presented.     

Measurement of spin-transfer observables in p p-->Lambda Lambda at 1.637 GeV/c

Spin-transfer observables for p p-->Lambda Lambda have been measured using a transversely polarized frozen-spin target and a beam momentum of 1.637 GeV/c. Current models of the reaction near threshold are in good agreement with existing measurements performed with unpolarized particles in the initial state but produce conflicting predictions for the spin-transfer observables Dnn and Knn (the normal-to-normal depolarization and polarization transfer), which are measurable only with polarized target or beam. Measurements of Dnn and Knn presented here are found to be in disagreement with predictions from these models.     

Revisiting radiation patterns in e^+e^- collisions

We propose four simple event-shape variables for semi-inclusive $e^+e^- \rightarrow 4$ -jet events. The observables and cuts are designed to be especially sensitive to subleading aspects of the event structure, and allow to test the reliability of phenomenological QCD models in greater detail. Three of them, $\theta _{14}$ , $\theta ^*$ , and $C_2^{(1/5)}$ , focus on soft emissions off 3-jet topologies with a small opening angle, for which coherence effects beyond the leading QCD dipole pattern are expected to be enhanced. A complementary variable, $M_L^2/M_H^2$ , measures the ratio of the hemisphere masses in 4-jet events with a compressed scale hierarchy (Durham $y_{23}$ – $y_{34}$ ), for which subleading $1\rightarrow 3$ splitting effects are expected to be enhanced. We consider several different parton-shower models, spanning both conventional and dipole/antenna ones, all tuned to the same $e^+e^-$ reference data, and show that a measurement of the proposed observables would allow for additional significant discriminating power between the models.     

Confinement of THz surface waves on the subwavelength size metal waveguide

We investigate surface plasmon waves propagating on planar Goubau lines, so-called Goubau modes, using a guided-wave terahertz spectroscopy system based on a freely positionable electrooptic probe. We show the radial nature of the Goubau mode and its confinement around the Goubau line over a few tenths of microns (??/10).     

Few-photon multiple ionization of ne and ar by strong free-electron-laser pulses

Few-photon multiple ionization of Ne and Ar atoms by strong vacuum ultraviolet laser pulses from the free-electron laser at Hamburg was investigated differentially with the Heidelberg reaction microscope. The light-intensity dependence of Ne2+ production reveals the dominance of nonsequential two-photon double ionization at intensities of I<6x10(12) W/cm2 and significant contributions of three-photon ionization as I increases. Ne2+ recoil-ion-momentum distributions suggest that two electrons absorbing "instantaneously" two photons are ejected most likely into opposite hemispheres with similar energies.