Nonadiabatic effects in the B, C, B′, and D states of H2

The Kolos-Wolniewicz potentials for the H₂$\text{B}{}^1\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ and C¹Π_u states were used together with the hypothesis of pure precession for the rotation-electronic interaction, to calculate the nonadiabatic energy levels of these states for J = 1 to 5. The complete coupling matrix was computed using accurate numerical vibrational wavefunctions. The calculated Λ-doubling of the v = 0 to 12 C vibrational levels generally agrees well with experimental values, and the nonadiabatic shifts in the B rotational constants qualitatively explain the difference between the theoretical and RKR potentials for this state.The interaction of the B′${}^1\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ and D¹Π_u states was also investigated, but only qualitatively since adiabatic potentials of sufficient accuracy do not exist for these states. The Λ-doubling of the Dv = 0 rotational levels agrees well with the experimental values. An appreciable “background” nonadiabatic shift in the B′ rotational constants was found. This shift, which is nearly 5 percent of B_v, is in addition to that of strong local two-level interactions and was not “deperturbed” in constructing the B′ RKR potential. The result is that the RKR turning points differ by about 0.04 au from the “true” adiabatic turning points. This conclusion is supported by a Hartree-Fock calculation of the B′ potential to the left of R_e.     

Collision properties of ultracold 133Cs atoms

We present a theoretical analysis of numerous magnetically tunable Feshbach resonances measured by Chin et al. [preceding Letter, Phys. Rev. Lett. 85, 2717 (2000)] at fields of up to 25 mT. This analysis provides the most accurate characterization of the collisional properties of ground state Cs atoms currently available and clearly shows, in contrast to previous work, that Bose-Einstein condensation of 133Cs cannot be ruled out. The X1Sigma(+)(g) and a(3)Sigma(u) scattering lengths are constrained to (280+/-10)a(0) and (2400+/-100)a(0), respectively ( 1a(0) = 0.052 917 7 nm), and the van der Waals C6 coefficient to 6890+/-35 a.u.(1 a.u. = 0.095 734 5 x10(-24) &Jdot;nm(6)).     

Palladium-catalyzed C-P coupling reactions between vinyl triflates and phosphine-boranes: efficient access to vinylphosphine-boranes

Vinylphosphine-borane complexes are easily synthesized by palladium-catalyzed C-P cross-coupling of vinyl triflates with secondary phosphine-boranes. This method allows the synthesis of phosphine derivatives not always easily accessible by other approaches. The vinylphosphine derivatives are purified by chromatography on silica gel. The versatility of the method is proved by using various triflates and diaryl-, dialkyl- and alkylarylphosphine-borane precursors. Chiral enantiopure phosphine-boranes are synthesized from chiral triflates.     

Surface chemical modifications and surface reactivity of nanodiamonds hydrogenated by CVD plasma

The present study focuses on the interaction of hydrogen microwave CVD plasma with nanodiamonds (NDs). Hydrogen treated NDs (H-NDs) were characterized using electron spectroscopies (XPS, AES) without air exposure. A surface temperature higher than 700 °C is needed to remove the oxygen present on raw NDs. The kinetics of oxygen removal were investigated. Moreover, UHV annealings of H-NDs after ageing in ambient air clearly underline that 75% of the oxygen is related to physisorbed species. Finally, H-NDs were efficiently grafted using photochemical reaction with alkenes and a spontaneous coupling of aryldiazonium salts. These results confirm similar electronic surface properties between bulk and nano diamond materials.     

Exploring an ultracold fermi-fermi mixture: interspecies feshbach resonances and scattering properties of 6Li and 40K

We report on the observation of Feshbach resonances in an ultracold mixture of two fermionic species, (6)Li and (40)K. The experimental data are interpreted using a simple asymptotic bound state model and full coupled channels calculations. This unambiguously assigns the observed resonances in terms of various s- and p-wave molecular states and fully characterizes the ground-state scattering properties in any combination of spin states.