全文获取类型
收费全文 | 1876篇 |
免费 | 108篇 |
国内免费 | 4篇 |
专业分类
化学 | 1214篇 |
晶体学 | 12篇 |
力学 | 75篇 |
数学 | 247篇 |
物理学 | 440篇 |
出版年
2023年 | 12篇 |
2022年 | 31篇 |
2021年 | 45篇 |
2020年 | 59篇 |
2019年 | 34篇 |
2018年 | 36篇 |
2017年 | 41篇 |
2016年 | 77篇 |
2015年 | 87篇 |
2014年 | 83篇 |
2013年 | 106篇 |
2012年 | 167篇 |
2011年 | 203篇 |
2010年 | 116篇 |
2009年 | 72篇 |
2008年 | 152篇 |
2007年 | 143篇 |
2006年 | 116篇 |
2005年 | 93篇 |
2004年 | 61篇 |
2003年 | 46篇 |
2002年 | 34篇 |
2001年 | 13篇 |
2000年 | 17篇 |
1999年 | 17篇 |
1998年 | 16篇 |
1997年 | 7篇 |
1996年 | 15篇 |
1995年 | 7篇 |
1994年 | 8篇 |
1993年 | 8篇 |
1992年 | 8篇 |
1991年 | 7篇 |
1990年 | 4篇 |
1989年 | 6篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 6篇 |
1984年 | 3篇 |
1982年 | 3篇 |
1981年 | 4篇 |
1980年 | 2篇 |
1975年 | 1篇 |
1974年 | 2篇 |
1973年 | 1篇 |
1965年 | 1篇 |
1964年 | 2篇 |
1877年 | 2篇 |
1868年 | 1篇 |
排序方式: 共有1988条查询结果,搜索用时 15 毫秒
51.
S Sun J Kroll Y Luo L Zhang 《Synlett : accounts and rapid communications in synthetic organic chemistry》2012,2012(1):54-56
A gold-catalyzed regioselective homodimerization of aliphatic terminal alkynes is described. Bulky and less Lewis acidic tBuXPhosAuNTf(2) is the preferred catalyst, and the additive, anhydrous NaOAc, substantially facilitates the reaction. 相似文献
52.
Julien Iehl Thi Le Anh Nguyen Stéphane Frein Uwe Hahn Joaquín Barberá Jean-François Nierengarten 《Liquid crystals》2017,44(12-13):1852-1860
ABSTRACTLiquid-crystalline [60]fullerodendrimers were constructed via click chemistry based on the reaction between hexa-adducts of [60]fullerene (C60) bearing 12 azide groups and alkyne-terminated cyanobiphenyl dendrons of first- and second-generation. The structure of all the new compounds was confirmed by IR, UV, 1H and 13C NMR spectroscopies and mass spectrometry. The mesomorphic properties were studied by polarised optical microscopy, differential scanning calorimetry and small-angle X-ray scattering. The hexa-adduct of C60 functionalised with the first-generation dendrons gave rise to the formation of a smectic A phase and a rectangular columnar phase (c2mm symmetry) while the hexa-adduct of C60 decorated with the second-generation dendrons displayed only a rectangular columnar phase (c2mm symmetry). Our results show that the hexa-adduct of C60 is a unique synthetic platform for the design of fullerodendrimers and dendronised materials. 相似文献
53.
We have studied the effect of interface heterogeneity on fracture, at both local and global scales. The single cantilever beam adhesion test was used to investigate interfacial fracture between polycarbonate plates and an elastic/fragile epoxy adhesive. Two surface treatments were applied to a (given) polycarbonate plate giving zones of strong and weak adhesion parallel to the crack direction. Calculated fracture energies differed from those expected from a simple rule-of-mixtures. A perturbation method, proposed by Rice, was used and results compared with crack fronts observed in situ. The technique was applied successfully but the difference in values of stress intensity factor between the zones was found substantially different from the experimental value. In an attempt to explain discrepancies, specimens with discontinuous crack fronts (adhesive and/or plates severed along the strong/weak adhesion frontier) were tested. Good agreement was found with the rule-of-mixtures predictions raising questions about the role of crack front continuity in load transfer. 相似文献
54.
Dr. Tim Schleif Dr. Jörg Tatchen Julien F. Rowen Frederike Beyer Prof. Dr. Elsa Sanchez-Garcia Prof. Dr. Wolfram Sander 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(46):10452-10458
The Cope rearrangement of selectively deuterated isotopomers of 1,5-dimethylsemibullvalene 2 a and 3,7-dicyano-1,5-dimethylsemibullvalene 2 b were studied in cryogenic matrices. In both semibullvalenes the Cope rearrangement is governed by heavy-atom tunneling. The driving force for the rearrangements is the small difference in the zero-point vibrational energies of the isotopomers. To evaluate the effect of the driving force on the tunneling probability in 2 a and 2 b , two different pairs of isotopomers were studied for each of the semibullvalenes. The reaction rates for the rearrangement of 2 b in cryogenic matrices were found to be smaller than the ones of 2 a under similar conditions, whereas differences in the driving force do not influence the rates. Small curvature tunneling (SCT) calculations suggest that the reduced tunneling rate of 2 b compared to that of 2 a results from a change in the shape of the potential energy barrier. The tunneling probability of the semibullvalenes strongly depends on the matrix environment; however, for 2 a in a qualitatively different way than for 2 b . 相似文献
55.
The research on the electrodes of Li-ion batteries aims to increase the energy density and the power density, improve the calendar and the cycling life, without sacrificing the safety issues. A constant progress through the years has been obtained owing to the surface treatment of the particles, in particular the coating of the particles with a layer that protects the core region from side reactions with the electrolyte, prevents the loss of oxygen, and the dissolution of the metal ions in the electrolyte, or simply improve the conductivity of the powder. The purpose of the present work is to review the different surface modifications that have been tried in the past for the different electrodes that are currently commercialized, or considered as promising, including the three families of positive electrodes (lamellar, spinel, and olivine families) and the three negative electrodes (carbon, Li4Ti5O12, and silicon). The role of the different coats used to improve either the surface conductivity, or the thermal stability, or the structural integrity is discussed. The limits in the efficiency of these different coats are also analyzed along with the understanding of the surface modifications that have been proposed. 相似文献
56.
57.
58.
59.
Rupert L. Frank Elliott H. Lieb Julien Sabin 《Geometric And Functional Analysis》2016,26(4):1095-1134
We give a necessary and sufficient condition for the precompactness of all optimizing sequences for the Stein–Tomas inequality. In particular, if a well-known conjecture about the optimal constant in the Strichartz inequality is true, we obtain the existence of an optimizer in the Stein–Tomas inequality. Our result is valid in any dimension. 相似文献
60.
Triangle centers such as the center of gravity, the circumcenter, the orthocenter are well studied by geometers. Recently, under the guidance of Clark Kimberling, an electronic encyclopedia of triangle centers (ETC) has been developed, it contains more than 7000 centers and many properties of these points. In this paper, we describe how we created a certified version of ETC such that some of the properties described come along with a computer checked proof of its validity. 相似文献