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91.
Reinaldo Y. Morita Fábio S. Richart Ronilson V. Barbosa Marilda Munaro Juliana R. Kloss 《Macromolecular Symposia》2012,319(1):108-113
Summary: Disposal of petroleum-derived polymers is a growing global environmental problem of alarming proportions, which has increased interest in the use and production of biodegradable materials. In addition to biodegradation, investment in research and development in the nanotechnology area is also significant. This study evaluated the effect of incorporation of an organophilic nanoclay ammonium-free salt (Novaclay™) on the mechanical properties and biodegradation of a biodegradable polyester (Ecoflex®), according to ASTM G 160. Ecoflex with and without incorporated Novaclay was characterized before and after biodegradation in organically enriched soil for up to 180 days, by visual analysis, optical microscopy, weight loss, differential scanning calorimetry, dynamic mechanical analysis, mechanical testing, and scanning electron microscopy. The pure Ecoflex and the Ecoflex/Novaclay nanocomposite were partially biodegraded by the method used, and showed changes in their morphological and mechanical properties. 相似文献
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93.
Dr. Daniela Mélanie Delannoy López Dr. Dong Tien Tran Dr. Guillaume Viault Dr. Sofiane Dairi Dr. Philippe Alexandre Peixoto Yoan Capello Laëtitia Minder Prof. Laurent Pouységu Dr. Elisabeth Génot Dr. Carmelo Di Primo Dr. Denis Deffieux Prof. Stéphane Quideau 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(17):5498-5508
A selection of bioactive polyphenols of different structural classes, such as the ellagitannins vescalagin and vescalin, the flavanoids catechin, epicatechin, epigallocatechin gallate (EGCG), and procyanidin B2, and the stilbenoids resveratrol and piceatannol, were chemically modified to bear a biotin unit for enabling their immobilization on streptavidin-coated sensor chips. These sensor chips were used to evaluate in real time by surface plasmon resonance (SPR) the interactions of three different surface-bound polyphenolic ligands per sensor chip with various protein analytes, including human DNA topoisomerase IIα, flavonoid leucoanthocyanidin dioxygenase, B-cell lymphoma 2 apoptosis regulator protein, and bovine serum albumin. The types and levels of SPR responses unveiled major differences in the association, or lack thereof, and dissociation between a given protein analyte and different polyphenolic ligands. Thus, this multi-analysis SPR technique is a valuable methodology to rapidly screen and qualitatively compare various polyphenol–protein interactions. 相似文献
94.
ThetheoryofnonlinearpolymerizationwasinitiatedbyFlory[1]andStockmayer[2].Forsimplifyingtheevaluationofaveragepolymerquantities,manyotherstatisticalmethodssuchastheprobabilityofgeneratingfunctionmethod[3],thelawoftotalprobabilitymethod[4,5]andtheothermethods[6… 相似文献
95.
96.
Atif Hussain Juliana Calabria-Holley Yunhong Jiang Mike Lawrence 《Journal of Sol-Gel Science and Technology》2018,86(1):187-197
For the first time, the hydrophilicity of hemp shiv was modified without the compromise of its hygroscopic properties. This research focused on the use of sol–gel method in preparation of coatings on the natural plant material, hemp shiv, that has growing potential in the construction industry as a thermal insulator. The sol–gel coatings were produced by cohydrolysis and polycondensation of tetraethyl orthosilicate (TEOS) using an acidic catalyst. Methyltriethoxysilane (MTES) was added as the hydrophobic precursor to provide water resistance to the bio-based material. Scanning electron microscopy (SEM) and focused ion beam (FIB) have been used to determine the morphological changes on the surface as well as within the hemp shiv. It was found that the sol–gel coatings caused a reduction in water uptake but did not strongly influence the moisture sorption behaviour of hemp shiv. Fourier transformed infrared (FTIR) spectroscopy shows that the coating layer on hemp shiv acts a shield, thereby lowering peak intensity in the wavelength range 1200–1800?cm?1. The sol–gel coating affected pore size distribution and cumulative pore volume of the shiv resulting in tailored porosity. The overall porosity of shiv decreased with a refinement in diameter of the larger pores. Thermal analysis was performed using TGA and stability of coated and uncoated hemp shiv have been evaluated. Hemp shiv modified with sol–gel coating can potentially develop sustainable heat insulating composites with better hygrothermal properties. 相似文献
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98.
David A. Selck Brian F. Woodfield Juliana Boerio‐Goates Daniel E Austin 《Rapid communications in mass spectrometry : RCM》2012,26(1):78-82
A low‐cost mass spectrometer attachment for thermogravimetric analysis has been constructed from readily available commercial instruments and components. The benefits of this set‐up include excellent mass‐flow repeatability, simple design, and significantly lower adoption cost as opposed to ready‐built commercial solutions. The inclusion of an open source software package allows semi‐automated, highly simplified data analysis. The results from the instrument show excellent sensitivity for small volumes of evolved gas, as well as highly reproducible signal strengths. The GUI‐based software package provides data analysis in a way that is very intuitive and that can be easily modified to work with a broad range of TG instruments. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
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100.
Pedro Nunes Angelis Juliana Casarin Affonso Celso Gonçalves Júnior Luana Rianne Rocha Maiyara Carolyne Prete César Ricardo Teixeira Tarley 《Electroanalysis》2022,34(5):854-862
This paper reports the development of a simple electroanalytical method for imazethapyr (IMT) determination in rice samples based on molecularly imprinted polymer and functionalized carbon black paste electrode (MIP-fCBPE). Carbon black (CB) was functionalized by the insertion of oxygenated functional groups upon acid treatment with HNO3 and H2SO4. The functionalized carbon black (fCB) presented higher performance for IMT determination than the CB without functionalization. The insertion of molecularly imprinted polyvinylimidazole (MIP-VN) in the fCBPE promoted a significant increase in the cathodic peak current even at low proportions (7.5 % w/w) due to the specific binding sites for IMT recognition. For IMT determination, DPV parameters were optimized by the Doehlert matrix applying 0.1 V for 60 s as pre-treatment in acetate buffer solution (pH 3.0) as supporting electrolyte. The proposed method showed low limit of detection (0.03 μmol L−1), a wide linear range (0.10–70.00 μmol L−1), and good precision in terms of repeatability of intraday measures (RSD%=3.6). The method was applied in rice samples after microwave-assisted extraction of IMT and the accuracy of the method was evaluated by addition/recovery assays (96.3–105.7 %), being statistically attested using HPLC-DAD as reference technique. 相似文献