首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   238篇
  免费   10篇
  国内免费   7篇
化学   163篇
晶体学   1篇
力学   13篇
数学   41篇
物理学   37篇
  2023年   1篇
  2022年   1篇
  2021年   5篇
  2020年   10篇
  2019年   6篇
  2018年   8篇
  2017年   6篇
  2016年   10篇
  2015年   5篇
  2014年   11篇
  2013年   24篇
  2012年   32篇
  2011年   23篇
  2010年   12篇
  2009年   11篇
  2008年   9篇
  2007年   10篇
  2006年   8篇
  2005年   9篇
  2004年   12篇
  2003年   10篇
  2002年   3篇
  2001年   4篇
  2000年   2篇
  1999年   1篇
  1998年   3篇
  1997年   1篇
  1996年   4篇
  1994年   3篇
  1993年   1篇
  1992年   1篇
  1987年   1篇
  1985年   2篇
  1984年   1篇
  1982年   1篇
  1980年   1篇
  1979年   1篇
  1972年   1篇
  1929年   1篇
排序方式: 共有255条查询结果,搜索用时 15 毫秒
181.
182.
Silver nanoclusters embedded in two transparent fluorinated polyimides, 4,4'-hexafluoroisopropylidene diphthalic anhydride – 2,3,5,6-tetramethyl paraphenylene diamine (6FDA-DAD) and 3,3',4,4' – biphenyltetracarboxylic acid dianhydride – 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane (BPDA-3F), have been produced by surface modification with KOH aqueous solution followed by K-assisted Ag doping and thermal reduction in hydrogen atmosphere. The reaction rate of the nucleophilic hydrolysis in KOH, studied by Fourier transform infrared spectroscopy (FT-IR) and Rutherford backscattering spectrometry (RBS), depends on the polyimide chemical structure. After ion-exchange in AgNO3 solution and subsequent annealing, the polyimide structure recovery was monitored by FT-IR whereas the characteristic surface plasmon absorption band of silver nanoparticles was evidenced by optical absorption measurements. The structure of silver nanoclusters as related to size and size distribution in the different polyimide matrices was thoroughly investigated by Transmission electron microscopy (TEM) and X-ray diffraction (XRD). The collected data evidenced a uniform distribution of Ag clusters of nanometric size after thermal treatment at 300 C in both polyimides. For the same ion-exchange treatment parameters and annealing temperature, XRD analyses evidenced the presence of crystallites with similar sizes.  相似文献   
183.
184.
185.
In this paper we study the spectral counting function for the weightedp-laplacian in one dimension. First, we prove that all the eigenvalues can be obtained by a minimax characterization and then we show the existence of a Weyl-type leading term. Finally we find estimates for the remainder term. The first author is supported by Universidad de Buenos Aires grant TX48, by ANPCyT PICT No. 03-05009. The second author is supported by CONICET and Universidad de San Andres.  相似文献   
186.
187.
Brown humic acids (BHAs) constitute the most polar and soluble fraction of humic acids. Their colloidal character and their high number of functional surface groups justify their higher reactivity as against metallic cations with respect to other humic fractions (i.e., gray humic acids and humins). The aim of this work is to study the retention mechanisms of Cu(II), Ni(II), and Co(II) on a BHA by means of a proper combination of physical and chemical techniques: sorption isotherms, mathematical modeling of these isotherms, molecular modeling, FTIR, and N2 (77 K) and CO2 (273 K) adsorption. Electrostatic retention for the three cations is an important mechanism at very low concentrations. Its magnitude is higher than that of the specific retention in the initial stages of the retention but it decreases progressively with respect to the former as the initial metal concentration increases. The BHA surface area varies with the amount of retained metal. When the initial amount of added metal is low (n0 < 80 mmol kg(-1)), the cations form 2:1 complexes, which are energetically favored due to the chelate effect. To obtain this coordination, the BHA slightly modifies its conformation by decreasing its area. When the initial amount of added metal is sufficiently high to occupy most of the surface functional groups (n0 > 1280 mmol kg(-1)), the cations are heterogeneously retained over the whole surface, thus preventing the available groups at low n0 from giving place to the 2:1 complexes due to the fact that they are already occupied.  相似文献   
188.
Stable cyclotriphosphazenes 5 and 6, with three and four carbon radical centers, have been prepared by condensation of (4-hydroxy-2,6-dichlorophenyl)bis(2,4,6-trichlorophenyl)methyl radical (4) with tetrachloro-2,2'-dioxybiphenylcyclotriphosphazene (7). EPR studies of both polyradicals in fluid solution suggest an electronic communication through the PN multiple bonds of the cycle. EPR spectral results in frozen solutions and magnetic susceptibility measurements in the solid are consistent with very weak electron-electron dipolar interactions. Reductive cyclic voltammetry shows a single three-electron redox couple for triradical 5 and a single four-electron redox couple for tetraradical 6. Both polyradicals 5 and 6 have been chemically oxidized to a stable trication 5(3+) and a tetracation 6(4+), respectively, by electron-transfer reactions.  相似文献   
189.
The ephedrine derivative, (H2ceph), yields [Cu(Hceph)2], showing a CH...Cu(II) agostic interaction; while in the analogous compound [Cu(Hcpse)2], with pseudoephedrine (H2cpse), that interaction is absent, despite the fact that these two diasteromers differ only in the orientation of the methyl and phenyl groups: erythro in H2ceph and threo in H2cpse. The X-ray crystal structure of [Cu(Hceph)2], indicates a Cu...HC length of 2.454 A and the theoretical study reveals the formation of a Cu...HC bond since the associated electronic density shows both a bond critical point and a bond ring critical point.  相似文献   
190.
A new method to test the antioxidant activity of polyphenols by electron transfer reactions to a stable organic free radical, tris(2,4,6-trichloro-3,5-dinitrophenyl)methyl radical (HNTTM), is reported. Therefore, the activity of the natural flavanols, (-)-epicatechin, and two synthetic derivatives, 4beta-(S-cysteinyl)epicatechin and 4beta-(2-aminoethylthio)epicatechin, can be differentiated by their capacity to transfer hydrogen atoms to 2,2-diphenyl-1-picrylhydrazyl radical (DPPH) and to transfer electrons to HNTTM. [structure: see text]  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号