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101.
Väisänen A Suontamo R Silvonen J Rintala J 《Analytical and bioanalytical chemistry》2002,373(1-2):93-97
An extraction method was developed for the determination of toxic elements in contaminated soil samples by inductively coupled plasma atomic emission spectrometry (ICP-AES). The determination of arsenic, cadmium, lead, and silver in ultrasound-assisted extracts of SRM 2710 and SRM 2711 by ICP-AES was carried out with high accuracy and precision (RSD<3.7%). The certified concentrations of the SRMs were obtained for arsenic, cadmium, lead, and silver by using an ultrasound-assisted extraction method with a digestion solution of (1+1)-diluted aqua regia. The determination of copper in SRMs by the ultrasound-assisted extraction method and analysis by ICP-AES failed to obtain the certified concentrations at the 95% level of confidence using (+/-2 s) as confidence limits of the mean. However, the same results were observed with the use of the microwave digestion method and reflux, which is the ISO 11466 standard method. The analysis of the SRMs showed that the ultrasound-assisted extraction method is highly comparable with the other methods used for such purposes. The major advantages of the ultrasound-assisted extraction method compared to the microwave and reflux methods are the high treatment rate (50 samples simultaneously in nine minutes) and low reagent usage, the main benefit of which are the low chloride and nitrate concentrations in the extracts. 相似文献
102.
R. Silvonen J. J. Lindberg C. Seppälä M. Ervasti C. Hauta-Aho 《Journal of Thermal Analysis and Calorimetry》1982,25(1):101-108
The hydrogen-bond properties (WBI index), water retention and water release from the protein-water systems gluten-water, soya protein- water and casein-water, have been investigated using differential scanning calorimetry in the temperature range 223–423 K. The proteins were characterized by their isoelectric point, contents of carboxyl groups and sulfur-containing groups, and readiness of undergo chloromethylation. It was concluded that the marked difference in water-release behaviour is chiefly explained by conformational differences and charge effects.
Zusammenfassung Wasserstoffbrückenbindugseigenschaften (WBI-Index), Wasserretention und Wasserabgabe von Protein-Masser-Systemen — Gluten-Wasser, Sojaprotein-Wasser und Casein-Wasser — wurden im Temperaturbereich von 233–423 K mit einem Scanning-Kalorimeter untersucht. Die Proteine wurden durch ihren isoelektrischen Punkt, den Gehalt an Carbonylgruppen und Schwefel enthaltenden Gruppen und durch ihre Reaktivität in der Chlormethylierung charakterisiert. Es wurde gefolgert, dass der ausgesprochene Unterschied im Wasserabgabeverhalten in erster Linie auf strukturelle Unterschiede und Ladungseffekte zurückzuführen ist.
223–423 K , , — , — — . , , . , .相似文献
103.
Structure-activity relationships of 23 P450 2A5 and 2A6 inhibitors were analysed using the CoMFA [1] and GOLPE/GRID with smart region definition (SRD) [2]. The predictive power of the resulting models was validated using five compounds not belonging to the model set. All models have high internal and external predictive power and resulting 3D-QSAR models are supporting each other. Both Sybyl and GOLPE highlight properties near lactone moiety to be important for 2A5 and 2A6 inhibition. Another important feature for pIC50 was the size of the substituent in the 7-positon of coumarin. The models suggest that the 2A5 binding site is larger that that of 2A6 due to larger steric regions in the CoMFA coefficient maps and corresponding GOLPE maps. In addition, the maps reveal that 2A6 disfavours negative charge near the lactone moiety of coumarin. 相似文献
104.
Abstract A simple method of deformational correction for the N.M.R. spectral parameters of molecules dissolved in liquid crystals is described. The method is applicable to the different isotopically substituted derivatives of the molecules belonging to the cubic point groups. Its validity is verified for the dipolar and quadrupolar couplings observed in the molecules CH4, CD4 and CH3D dissolved in the liquid crystals Merck Phase IV, Merck ZLI 1167 and their mixtures. 相似文献
105.
106.
Carboxymethyl cellulose (CMC, DS 0.58) was treated in solutions of sodium hydroxide (0.001–1 M) at 95 °C. The treated (1–12 h) CMC samples were purified by dialysis and analyzed by UV spectroscopy and by UV resonance Raman spectroscopy (UVRRS) with excitation at 244 nm. A UV absorption maximum at 265 nm and a UVRR signal at 1650 cm−1 were indicative of formation of -conjugated aldehyde end groups in CMC through -elimination. Another strong UVRR band at 1610 cm−1 gave evidence on conversion of some of the -conjugated aldehyde end groups to alkali stable aromatic structures. 相似文献
107.
Xenon porometry is a method in which porous material is immersed in a medium and the properties of the material are studied by means of 129Xe nuclear magnetic resonance (NMR) of xenon gas dissolved in the medium. For instance, the chemical shift of a particular signal (referred to as signal D) arising from xenon inside small pockets formed in the pores during the freezing of the confined medium is highly sensitive to the pore size. In the present study, we show that when naphthalene is used as the medium the pore size distribution of the material can be determined by measuring a single one-dimensional spectrum near room temperature and converting the chemical shift scale of signal D to the pore radius scale by using an experimentally determined correlation. A model has been developed that explains the curious behavior of the chemical shift of signal D as a function of pore radius. The other signals of the spectra measured at different temperatures have also been identified, and the influence of xenon pressure on the spectra has been studied. For comparison, 129Xe NMR spectra of pure xenon gas adsorbed to porous materials have been measured and analyzed. 相似文献
108.
Tuomela Jukka; Arponen Teijo; Normi Villesamuli 《IMA Journal of Numerical Analysis》2006,26(4):811-846
** Email: jukka.tuomela{at}joensuu.fi*** Corresponding author. Email: arponen{at}maths.warwick.ac.uk**** Email: villesamuli.normi{at}joensuu.fi We analyse some RungeKutta type methods for computing1D integral manifolds, i.e. solutions to ordin-ary differentialequations and differential-algebraic equations. We show thatwe can compute the solutions which respect all the constraintsof the problem reliably and reasonably quickly. Moreover, weshow that the so-called impasse points are regular points inour approach and hence require no special attention. 相似文献
109.
Refractive index change of liquids was detected using a temperature compensated prism cavity together with a diffractive optical element fabricated by electron beam lithography. Small changes of refractive index could be detected from image data of the sensor. 相似文献
110.
Paloniemi H Aäritalo T Laiho T Liuke H Kocharova N Haapakka K Terzi F Seeber R Lukkari J 《The journal of physical chemistry. B》2005,109(18):8634-8642
HiPco single-wall carbon nanotubes (SWNTs) have been noncovalently modified with ionic pyrene and naphthalene derivatives to prepare water-soluble SWNT polyelectrolytes (SWNT-PEs), which are analogous to polyanions and polycations. The modified nanotubes have been characterized with UV-vis-NIR, fluorescence, Raman and X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). The nanotube-adsorbate interactions consist of pi-pi stacking interactions between the aromatic core of the adsorbate and the nanotube surface and specific contributions because of the substituents. The interaction between nanotubes and adsorbates also involves charge transfer from adsorbates to SWNTs, and with naphthalene sulfonates the role of a free amino group was important. The ionic surface charge density of the modified SWNTs is constant and probably controlled by electrostatic repulsion between like charges. The linear ionic charge density of the modified SWNTs is similar to that of common highly charged polyelectrolytes. 相似文献