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71.
Mechanically hard amorphous carbon nitride films were formed by applying a combination of radio frequency (RF) bias voltage to the substrate and the chemical vapor deposition process using the decomposition reaction of BrCN with the microwave discharge flow of Ar. Cooling water was circulated inside the substrate stage. The maximum hardness was (17 ± 1) GPa for the film prepared under the negative RF bias voltage, −VRF, of 30 V. This hardness was nearly twice that of the film prepared without cooling, suggesting that substrate cooling was effective for suppressing the relaxation of the internal stress of the film due to the temperature rise during the application of the RF bias voltage. Under the continuous operation of the RF bias voltage, films cannot be formed for −VRF > 40 V because of the sputtering by the bombardment of energetic Ar+. Then, the RF bias voltage was applied with a pulsed operation. By using this operation films were prepared in the range of −VRF = 40-100 V. The hardness, (36 ± 10) GPa, was obtained for the film obtained under the conditions of −VRF = 100 V, the pulse period of 1000 s, and the pulse-on time of 800 s. The observed hardness scattered largely for the different observation points within this film; a single observation point in that film showed the maximum hardness of 46 GPa. According to the IR spectra of the films, the three-dimensional C-N network structure was developed. 相似文献
72.
Semi-free As2S3 flakes undergo visible-scale anisotropic deformations when exposed to linearly-polarized bandgap illumination. We investigate the behavior and also those in amorphous Se, GeS2, AgAsS2, and crystalline As2S3. These results suggest that the deformation occurs through photo-induced birefringence, photo-induced fluidity, and optical force. 相似文献
73.
A. Saitoh 《Journal of Raman spectroscopy : JRS》2007,38(5):537-542
Raman scattering from BiI3 and SbI3 crystals has been studied at hydrostatic pressures up to 2 GPa. The wavenumbers monotonically increased with pressure for all modes in BiI3. Although both crystals belong to the same space group, the pressure coefficients of SbI3 were significantly different from those of BiI3. At pressure P0 = 0.92 ± 0.01 GPa, the pressure coefficients of all modes changed. Above P0, all modes in SbI3 had positive pressure coefficients as they have in BiI3. By comparing this unusual behavior of the Raman lines in SbI3 around P0 with the results in BiI3 and comparing the two lattice structures, we suggest that the type of bonding of SbI3 changes to become more ionic and hence more similar to the bonding of BiI3. This change in structure is supported by changes in the bandwidth of the self‐trapped exciton (STE) luminescence and the slope of the absorption edge photon energy versus pressure. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
74.
75.
Ca2+-doping effects were studied on the N-type ferrimagnet of NdVO3. The chemical pressures by Ca2+-doping induced lowering of ferrimagnetic transition temperature Tc and compensation temperature θc, resulting in the phase transition from N- to P-type ferrimagnetic phase. In the N-phase, spontaneous magnetization Msp becomes zero at finite temperature θc and in the P-phase, Msp is positive in whole temperature range. It was revealed that NdVO3 and Ca0.1Nd0.9VO3 located in the N-phase and Ca0.2Nd0.8VO3 in the P-phase. This N→P transition by the chemical pressure was discussed by the intra- and inter-sublattice exchange integrals estimated from the molecular field approximation. 相似文献
76.
S. Hagimura T. Saitoh Y. Yagihara 《Annals of the Institute of Statistical Mathematics》1988,40(3):419-438
Cement plant process is full of internal noise sources and feedback loops. Therefore, statistical approach is required to understand its dynamic characteristics. Time series analysis has been applied to some important subprocesses of a cement plant process. These are the vertical mill process, calcining process and clinker cooling process. Based on the AR models of these, a set of optimum controllers have been designed by modern control theory. Successful results of application are reported in this paper. A method of determining optimal production level is also discussed. 相似文献
77.
Nickel(II), copper(II) and zinc(II) ions are extracted from an aqueous solution into carbon tetrachloride as their diethyldithiocarbamate (DDC) chelates. The extract, after removal of the solvent, is treated with meso-tetraphenylporphine (TPP) in benzyl alcohol at 140°C for 60 min. Quantitative conversion of the DDC chelate to the TPP chelate is obtained over the range 0.25–4.5 μg of each metal by use of 3 μgmol of TPP. The reaction mixture is analysed by reversed-phase high-performance liquid chromatography with spectrophotometric detection at 412 nm. Simultaneous determination of Cu and Zn in NBS bovine liver is possible by this procedure. 相似文献
78.
Transmission loss of holey fiber is found to depend on its structure, and to be caused by Rayleigh scattering at glass surface. Under this loss dependence, most promising is optical wiring application, for which fiber designs to realize bend-insensitivity and single-modedness are presented. 相似文献
79.
80.
Nobuo Kitada Tsuyoshi Saitoh Yuma Ikeda Satoshi Iwano Rika Obata Haruki Niwa Takashi Hirano Atsushi Miyawaki Koji Suzuki Shigeru Nishiyama Shojiro A. Maki 《Tetrahedron letters》2018,59(12):1087-1090
The synthesis and bioluminescence of allyl-substituted luciferin derivatives as substrates for firefly luciferase are reported. The allylation of luciferins induced bathochromic shift (15–40?nm) of the bioluminescence emission. Upon combination with other chemical modifications for bioluminescence wavelength tuning, novel red emitting luciferin analogues were obtained with emission maxima at 685 and 690?nm. 相似文献