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51.
The interaction of SO2 with oxygen-sputtered Au(1 1 1) (θoxygen 0.35 ML) was studied by monitoring the oxygen and sulfur coverages as a function of SO2 exposure. The morphology of the sputtered Au is relatively smooth on a long length scale, but rough on a finer scale with islands averaging 15 nm. The rough surface is not stable to scanning with the STM. Two reaction regimes were observed: oxygen depletion followed by sulfur deposition. An enhanced, transient sulfur deposition rate is observed at the oxygen depletion point. This effect is specifically pronounced if the Au surface is continuously exposed to SO2. The enhanced reactivity towards S deposition seems to be linked to the presence of highly reactive, under-coordinated Au atoms. Adsorbed oxygen appears to stabilize, but also to block these sites. In absence of the stabilization effect of adsorbed oxygen, i.e. at the oxygen depletion point, the enhanced reactivity decays on a timescale of a few minutes. These observations shed a new light on the catalytic reactivity of highly dispersed gold nanoparticles. 相似文献
52.
The electrophoretic mobility of silica nanospheres was shown to be a function of separation conditions such as pH and phosphate concentration of a carrier electrolyte. The separation selectivity can be controlled by the separation conditions and optimised depending on the sample composition. The effects of pH and phosphate concentration of buffer solutions on the nanosphere electrophoretic mobility are explained using the Overbeek-Booth electrokinetic theory taking into account both electrophoretic retardation and the relaxation effect. 相似文献
53.
The electron transfer from an H-terminated diamond (100)-2 x 1 surface to a neutral or acidic water adlayer has been theoretically investigated, using quantum mechanical DFT calculations under periodic boundary conditions. A surface conductivity of p-type was found to be induced by the acidic environment. An electron transfer of 1.8 electrons per surface unit cell was observed to take place from the upper part of the diamond valence band to the lowest unoccupied molecular level of the aqueous adlayer that contains one H(3)O(+) ion. The result is a hole delocalized over the whole diamond model slab. Also, a pronounced weakening of the H(3)O(+) bonds by the interaction with the diamond surface is observed. 相似文献
54.
A bioassay-directed chemical analysis (BDCA) scheme has been developed which combines a yeast screen for estrogenic activity with LC–MS detection after liquid–liquid extraction and fractionation by size exclusion chromatography. Focusing on sewage-treatment plant (STP) effluents, the approach aims at characterizing the substances responsible for estrogenic effects in aquatic systems. Initial results show a strong response of STP effluent extracts in the yeast screen. Estrone, bisphenol A, and nonylphenol have been identified as substances being partly responsible for observed estrogenic activity. However, confirmation experiments with synthetic samples revealed that the estrogenic effect potentials of the samples could not be completely assigned to specific compounds. Further improvement of the limits of detection of the analytical scheme is needed to enable identification and quantification of potent estrogenic compounds at low concentrations. 相似文献
55.
Synthesis and Characterization of Far‐Red/NIR‐Fluorescent BODIPY Dyes,Solid‐State Fluorescence,and Application as Fluorescent Tags Attached to Carbon Nano‐onions 下载免费PDF全文
Dr. Juergen Bartelmess Dr. Michele Baldrighi Dr. Valentina Nardone Dr. Emilio Parisini David Buck Prof. Dr. Luis Echegoyen Prof. Dr. Silvia Giordani 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(27):9727-9732
A series of π‐extended distyryl‐substituted boron dipyrromethene (BODIPY) derivatives with intense far‐red/near‐infrared (NIR) fluorescence was synthesized and characterized, with a view to enhance the dye’s performance for fluorescence labeling. An enhanced brightness was achieved by the introduction of two methyl substituents in the meso positions on the phenyl group of the BODIPY molecule; these substituents resulted in increased structural rigidity. Solid‐state fluorescence was observed for one of the distyryl‐substituted BODIPY derivatives. The introduction of a terminal bromo substituent allows for the subsequent immobilization of the BODIPY fluorophore on the surface of carbon nano‐onions (CNOs), which leads to potential imaging agents for biological and biomedical applications. The far‐red/NIR‐fluorescent CNO nanoparticles were characterized by absorption, fluorescence, and Raman spectroscopies, as well as by thermogravimetric analysis, dynamic light scattering, high‐resolution transmission electron microscopy, and confocal microscopy. 相似文献
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Juergen Linke Peter Neumeyer Matthias Waechter Joachim Peinke 《Experiments in fluids》2007,42(5):811-814
We report on a surprising phenomenon in a turbulent jet setup which uses a cone-shaped nozzle with an excentric inlet. Inside
the nozzle a slowly mixing, rotating cylinder surface was observed. The speed of mixing on this cylinder surface is reduced
by approximately a factor of 8 compared to the remaining flow field of the nozzle. The phenomenon seems to be independent
of the Reynolds number and the pressure distribution inside the nozzle. 相似文献
59.
Stefan Lautenschlaeger Sebastian Eisermann Michael N. Hofmann Udo Roemer Melanie Pinnisch Andreas Laufer Bruno K. Meyer Holger von Wenckstern Alexander Lajn Florian Schmidt Marius Grundmann Juergen Blaesing Alois Krost 《Journal of Crystal Growth》2010,312(14):2078-2082
We report on the growth of non-polar a-plane ZnO by CVD on r-plane-sapphire-wafers, a-plane GaN-templates and a-plane ZnO single-crystal substrates. Only the homoepitaxial growth approach leads to a Frank–van-der–Merwe growth mode, as shown by atomic force microscopy. The X-ray-diffraction spectra of the homoepitaxial thin films mirror the excellent crystalline quality of the ZnO substrate. The morphological and the structural quality of the homoepitaxial films is comparable to the best results for the growth on c-plane ZnO-substrates. The impurity incorporation, especially of group III elements, seems to be reduced when growing on the non-polar a-plane surface compared to the c-plane films as demonstrated by secondary ion mass spectrometry (SIMS). Optical properties have been investigated using low temperature photoluminescence measurements. We employed capacitance–voltage measurements (C–V) to measure the background carrier density and its profile from substrate/film interface throughout the film to the surface. In thermal admittance spectroscopy (TAS) specific traps could be distinguished, and their thermal activation energies and capture cross sections could be determined. 相似文献
60.
Thomas Ortlepp Olaf Mielke Juergen Kunert Hannes Toepfer 《Physica C: Superconductivity and its Applications》2010,470(21):1955-1958
We implemented small superconducting loops containing a frozen single flux quantum in single flux quantum (SFQ) electronics. Such an element acts as a π-phaseshifter which is the missing complementary circuit element in SFQ electronics and can significantly improve the circuit reliability and robustness. We designed a four bit ripple counter including toggle flip-flops (TFF) with these π-phaseshifters. We analyzed the circuit stability by means of bit error rate (BER) measurements versus bias supply. The measured operation range of the counter in standard SFQ technique was ±14% and could be improved to ±24% for the new version utilizing π-phaseshifters. These results are a clear proof for a more robust circuit realization achieved without any additional power consumption. Furthermore, it supports the reduction of present power consumption in SFQ circuits by using smaller switching energy as well as the development of more complex circuits because of a reduced sensitivity against technological parameter spread. 相似文献