全文获取类型
收费全文 | 268篇 |
免费 | 9篇 |
国内免费 | 3篇 |
专业分类
化学 | 218篇 |
晶体学 | 4篇 |
力学 | 4篇 |
数学 | 8篇 |
物理学 | 46篇 |
出版年
2023年 | 2篇 |
2022年 | 1篇 |
2021年 | 4篇 |
2018年 | 3篇 |
2017年 | 3篇 |
2016年 | 9篇 |
2015年 | 9篇 |
2014年 | 5篇 |
2013年 | 5篇 |
2012年 | 17篇 |
2011年 | 18篇 |
2010年 | 17篇 |
2009年 | 16篇 |
2008年 | 24篇 |
2007年 | 23篇 |
2006年 | 19篇 |
2005年 | 20篇 |
2004年 | 9篇 |
2003年 | 10篇 |
2002年 | 30篇 |
2001年 | 7篇 |
2000年 | 4篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 4篇 |
1995年 | 2篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1973年 | 2篇 |
1967年 | 1篇 |
排序方式: 共有280条查询结果,搜索用时 15 毫秒
101.
Evelin Jaehne Dirk Ferse Hans‐Juergen P. Adler K. Ramya I.K. Varma M. Wolter Nils Hebestreit Waldfried Plieth 《Macromolecular Symposia》2001,164(1):133-144
Polythiophene layers have been grafted onto silicon, iron, platinum and titanium for applications as organic semi‐conducting films on solid surfaces. In general, the adhesion between the polymer films and substrates is insufficient for technical and microelectronic applications. The use of adhesion promoters between substrate and polymer and enables the formation of a strongly bonded composite. The polymers were synthesized by chemical or electrochemical surface polymerization. 相似文献
102.
Andrij Pich Sven Richter Hans‐Juergen Adler Vitaly Datsyuk Stanislav Voronov 《Macromolecular Symposia》2001,164(1):11-24
In this work the emulsion polymerisation of styrene was carried out in presence of the inisurfs (reactive surfactants). The reaction kinetics was followed by dilatometric and calorimetric measurements. The influence of the inisurf concentration in reaction mixture as well as the reaction temperature on the particle properties were studied. Resulting particles were characterised with FFFF‐MALLS and PCS. Viscosity measurements indicate the formation of particle flocks in the solution at certain inisurf concentration in reaction mixture. 相似文献
103.
The adsorption and organisation process of reactive microgels has been investigated on technical aluminium. The aim was to replace the present chromating procedure on reactive metals like aluminium because this process was been considered as an ecological problem. By means of a two‐step emulsion polymerization with phosphate substituted monomer we have obtained polymeric nano‐particles with phosphate groups on the surface. The core is synthesized by copolymerization from styrene (St) and butyl acrylate (BuA). The results of several analytical methods like contact angle SEM or TEM measurements showed, that these microgels were able to adsorb spontaneously onto the substrate surface and subsequently a structured molecular order was formed. The properties of the adsorbed microgel layers were confirmed by industrial linked adhesion and corrosion tests. 相似文献
104.
Sherry Cox Ali Martin Mallery Hamill Nealy Pistole James Steeil Juergen Schumacher 《Biomedical chromatography : BMC》2014,28(8):1126-1130
A simple high‐performance liquid chromatography method for the determination of cefovecin in small volume plasma has been developed. Following solid‐phase extraction using Oasis HLB cartridges, samples were separated by reverse‐phase high‐performance liquid chromatography on an XBridge C8 (3.5 µm) 4.6 × 250 mm column and quantified using ultraviolet detection at 280 nm. The mobile phase was a mixture of 10 mm ammonium acetate (pH 3.5) and acetonitrile (89:11), with a flow rate of 0.85 mL/min. The standard curve ranged from 0.1 to 200 µg/mL. Intra‐ and Inter‐assay variability for cefovecin was <10%, and the average recovery was >90%. The lower limit of quantitation was 0.1 µg/mL. This method was successfully applied to the analysis of cefovecin samples at our institution. This is also the first fully validated method with an internal standard that does not use mass spectrometry. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
105.
106.
107.
Sivadinarayana C Choudhary TV Daemen LL Eckert J Goodman DW 《Journal of the American Chemical Society》2004,126(1):38-39
Inelastic neutron spectroscopy (INS) has been employed to identify surface species formed during the H2-O2 reaction on Au/TiO2 catalysts. Determination of the surface intermediates formed in this reaction is crucial to develop a mechanistic understanding for the direct vapor-phase propylene epoxidation reaction and synthesis of H2O2. Although the presence of intermediate hydroperoxo species (during these reactions) has been suggested in literature, it has never been demonstrated. Our studies provide direct evidence for the formation of surface hydroperoxo species during the H2-O2 reaction. 相似文献
108.
An analytical method has been developed for the determination of five naturally occurring estrogens (estradiol, estriol, estrone, genistein, daidzein), one synthetic hormone (ethynylestradiol) and three xenoestrogens (4-nonylphenol (NP), 4-tert-octylphenol (4-tert-OP), bisphenol A (BPA)) in coastal marine waters. The procedure includes a solid-phase extraction of approx. fifty litres of water samples on the solid-phase copolymer Oasis HLB followed by a clean-up on silica. Twenty-five percent aliquots were used for the analytical determination of the analytes using high performance liquid chromatography coupled with electrospray-ionisation tandem mass spectrometry (HPLC-ESI-MS/MS). Calculated extraction recoveries between 52 (4-tert-octylphenol) and 91% (nonylphenol) were obtained for the method developed. Matrix interferences occurring during electrospray ionisation were quantified by spiking the extracts prior to the measurements. Method detection limits ranged from 0.02 (estrone) to 1 ng L(-1) (estriol). The method was applied to determine environmental estrogens in coastal waters of the Baltic Sea. The analyses showed the presence of five compounds at levels between 0.10 (estrone) and 17 ng L(-1) (ethynylestradiol). 相似文献
109.
Ben Bader Juergen Gay Stephan Gruendemann Judith Guenther Martina Schaefer Tilman Spellig Thomas M. Zollner Ludwig Zorn 《Tetrahedron letters》2007,48(34):5984-5986
For in-depth characterization as a putative pan-selectin antagonist 3H-labeled Efomycine M was synthesized starting from the natural product derived from Elaiophyline. 相似文献
110.
The growth of nanocrystalline MoO3 islands on Au(111) using physical vapor deposition of Mo has been studied by scanning tunneling microscopy and low energy electron diffraction. The growth conditions affect the shape and distribution of the MoO3 nanostructures, providing a means of preparing materials with different percentages of edge sites that may have different chemical and physical properties than atoms in the interior of the nanostructures. MoO3 islands were prepared by physical vapor deposition of Mo and subsequent oxidation by NO2 exposure at temperatures between 450 K and 600 K. They exhibit a crystalline structure with a c(4 x 2) periodicity relative to unreconstructed Au(111). While the atomic-scale structure is identical to that of MoO3 islands prepared by chemical vapor deposition, we demonstrate that the distribution of MoO3 islands on the Au(111) surface reflects the distribution of Mo clusters prior to oxidation although the growth of MoO3 involves long-range mass transport via volatile MoO3 precursor species. The island morphology is kinetically controlled at 450 K, whereas an equilibrium shape is approached at higher preparation temperatures or after prolonged annealing at the elevated temperature. Mo deposition at or above 525 K leads to the formation of a Mo-Au surface alloy as indicated by the observation of embedded MoO3 islands after oxidation by NO2. Au vacancy islands, formed when Mo and Au dealloy to produce vacancies, are observed for these growth conditions. 相似文献