Enhancement of the emission yield of silicon nanocrystals in silica due to surface passivation

The ability of surface passivation to enhance the photoluminescence (PL) emission of Si nanocrystals in SiO₂ has been investigated. Silicon precipitation in implanted samples takes place in a time scale of few minutes at 1100°C. For longer annealing at the same temperature, the PL intensity of the Si nanocrystals increases and eventually reaches saturation, while it correlates inversely with the amount of Si dangling bonds at the Si–SiO₂ interface (P_b centers), as measured by electron spin resonance. This combined behavior is independent on the silica matrix properties, implantation profiles and annealing atmosphere and duration. The observation that the light emission enhancement is directly related to the annealing of P_b centers is confirmed by treatment in forming gas. This mild hydrogenation at much lower temperature (450°C) leads to a complete passivation of the P_b defects, increasing at the same time the PL yield and the lifetime.     

Dog and tricks: some mathematics for students of graphics

This paper describes how parametric cubic splines and cubicBezier curves may be used in designing a two dimensional shape.A simple aerofoil shape is designed using both methods. Themathematics is described and the shape drawn using Excel. Theeffect of varying parameters is shown in both methods.     

Role of the microstructure on the transport properties of Y-doped zirconia and Gd-doped ceria

Transmission electron microscopy characterizations and XPS analyses have allowed us to show the influence of the microstructure and nanochemistry on the transport properties of Y₂O₃-(9 mol%)-stabilized zirconia (YSZ) and Gd₂O₃ (10 mol%)-doped ceria (GDC). The grain boundary electrical conductivity (σ_gb) and oxygen diffusion coefficient (D_o) of conventional YSZ ceramics increase with the grain size, while an opposite behavior was found for GDC samples. This difference was attributed to glassy precipitates present at YSZ grain boundaries. Furthermore, it was shown that kinetic demixing processes take place during cooling, at the end of sintering. This causes important changes in the cationic species distribution at interfaces and plays an important role on the transport properties of these two materials. Paper presented at the 9th EuroConference on Ionics, Ixia, Rhodes, Greece, Sept. 15 – 21, 2002.     

Comparing different hard-thermal-loop approaches to quark number susceptibilities

We compare our previously proposed hard-thermal-loop (HTL) resummed calculation of quark number susceptibilities using a self-consistent two-loop approximation to the quark density with a recent calculation of the same quantity at the one-loop level in a variant of HTL-screened perturbation theory. Besides pointing out conceptual problems with the latter approach, we show that it severely over-includes the leading-order interaction effects, while including none of the plasmon terms, which is the main reason for requiring improved resummation schemes. Received: 27 June 2002 / Revised version: 23 September 2002 / Published online: 31 January 2003     

Whispering-gallery modes in a barrel-shaped dielectric resonator

We experimentally study a new type of resonator, namely, a barrel-shaped dielectric resonator with whispering-gallery modes which is formed by the cutting dielectric hemisphere. Compared with a hemispherical dielectric resonator, the E type oscillation spectrum of such a resonator is rarefied with respect to the azimuthal index. Comparative analysis of the electromagnetic characteristics of the barrel-shaped dielectric resonator and half-disk dielectric resonators shows that the radiation losses of the mode energy from the spherical surface are smaller than those from the cylindrical surface. This fact stimulates the high values of the internal Q-factor of modes of the barrel-shaped dielectric resonator. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 48, No. 12, pp. 1041–1048, December 2005.     

On the computation of sound in free and wall-bounded domains

A new Dispersion-Relation-Preserving (DRP) scheme has been developed using the Lax-Wendroff methodology. Two collocated grids are placed in a staggered formation and a staggered DRP scheme is used to calculate the spatial differentiation of the propagation and convection terms. A staggered filtering scheme of a six points stencil is developed to complete the transformation from one grid to another. Existing DRP Runge-Kutta schemes are used for the time marching. Stability limits and accuracy issues are investigated using a simple 1D advection equation. The new method is then tested for monopole and quadrupole radiation, diffraction effects of an aperture in a wall, and convection effects of shear flow. All demonstrate the good accuracy and numerical stability of the new method.     

The Six and Eight-Vertex Models Revisited

Elliott Lieb's ice-type models opened up the whole field of solvable models in statistical mechanics. Here we discuss the “commuting transfer matrix” T,Qequations for these models, writing them in a more explicit and transparent notation that we believe offers new insights. The approach manifests the relationship between the six-vertex and chiral Potts models, and between the eight-vertex and Kashiwara–Miwa models.     

Investigation of charge effects on poling and stability for corona-poled polymer films

The optimal corona-poling temperature of polymer films was accurately determined by measuring the temperature dependence of the in situ second-harmonic (SH) intensity profile under the applied poling electric field. The in situ SH intensity profile was first measured by probing both the surface voltages and the poling currents induced by surface/space charges for the corona-poled polymer films. Moreover, charge effects on the stability of the chromophore orientation were first studied by using the thermally stimulated discharge-current technique. PACS 72.20.Jv; 42.65.Ky; 73.61.Ph; 81.40.Tv