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31.
Aji P. Mathew Gabriel Groeninckx G. H. Michler H. J. Radusch Sabu Thomas 《Journal of Polymer Science.Polymer Physics》2003,41(14):1680-1696
The effects of the blend ratio and initiating system on the viscoelastic properties of nanostructured natural rubber/polystyrene‐based interpenetrating polymer networks (IPNs) were investigated in the temperature range of ?80 to 150 °C. The studies were carried out at different frequencies (100, 50, 10, 1, and 0.1 Hz), and their effects on the damping and storage and loss moduli were analyzed. In all cases, tan δ and the storage and loss moduli showed two distinct transitions corresponding to natural rubber and polystyrene phases, which indicated that the system was not miscible on the molecular level. However, a slight inward shift was observed in the IPNs, with respect to the glass‐transition temperatures (Tg's) of the virgin polymers, showing a certain degree of miscibility or intermixing between the two phases. When the frequency increased from 0.1 to 100 Hz, the Tg values showed a positive shift in all cases. In a comparison of the three initiating systems (dicumyl peroxide, benzoyl peroxide, and azobisisobutyronitrile), the dicumyl peroxide system showed the highest modulus. The morphology of the IPNs was analyzed with transmission electron microscopy. The micrographs indicated that the system was nanostructured. An attempt was made to relate the viscoelastic behavior to the morphology of the IPNs. Various models, such as the series, parallel, Halpin–Tsai, Kerner, Coran, Takayanagi, and Davies models, were used to model the viscoelastic data. The area under the linear loss modulus curve was larger than that obtained by group contribution analysis; this showed that the damping was influenced by the phase morphology, dual‐phase continuity, and crosslinking of the phases. Finally, the homogeneity of the system was further evaluated with Cole–Cole analysis. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1680–1696, 2003 相似文献
32.
Juan A. Barceló Jonathan Bennett Alberto Ruiz 《Journal of Fourier Analysis and Applications》2003,9(6):541-562
We study the continuity properties of a projection derived from a recent characterization of Herglotz Wave Functions in the plane. Herglotz Wave Functions are the entire solutions of the Helmholtz equation which have L2-Far-Field-Pattern. The behavior of this projection is reminiscent of the Disc Multiplier Operator on both Lp and mixed Lp-normed spaces. In particular a Kakeya type set plays a central role in our analysis. As a consequence we answer a question posed by Alvarez, Folch-Gabayet and Pérez-Esteva. 相似文献
33.
Toluene adsorption reactions on the (1 1 0) surface of VSbO4 have been analyzed following the changes in the electronic structure of the hydrocarbon molecule and metal cation sites of the oxide using the Just Another Extended Hückel Molecular Orbital Program (JAEHMOP) code. The bonding character of these interactions has also been studied in the same theoretical framework. The calculations indicate that the exothermic hydrocarbon parallel interaction on Sb-V sites results in the weakening of one of the C-H bonds of the methyl fragment. This leads to a H-abstraction that involves the participation of a Sb-cation. Both methyl and phenyl fragments decrease their electronic population and so does the V-cation site. Most of these electrons are transferred to other V atoms in the bulk solid. As a result the LUMO of the toluene-oxide system fully populates. The analysis reveals that methyl-Sb bonding interactions mainly involve C2px and H1s orbitals with Sb5s orbital, while non-bonding phenyl-V interactions involve C2px orbitals with V3dx2−y2 orbital. This last interaction facilitates the desorption of the benzyl species after H-abstraction. 相似文献
34.
The determination of the enantiomeric purity of 2 or 3-substituted cyclanones, particularly cyclohexanones, is conveniently achieved by derivatisation into cyclic aminals with commercially available (R, R)-1,2-diphenylethylenediamine. The derivatisation procedure is directly done into the NMR tube, instantaneously, and 13C NMR allows an accurate measure of the ee. 相似文献
35.
D. Hugh Powell Andr E. Merbach Gabriel Gonzlez Ern Brücher Kroly Micskei M. Francesca Ottaviani Klaus Khler Alex Von Zelewsky Oleg Ya. Grinberg Yakob S. Lebedev 《Helvetica chimica acta》1993,76(5):2129-2146
EPR Spectra have been measured for aqueous solutions of a series of Gd3+ complexes at variable temperature and a range of magnetic fields; S-band (0.14 T), X-band (0.34 T), Q-band (1.2 T), and 2-mm-band (5.0 T). The major contribution to the observed line widths is magnetic-field-dependent and is interpreted as being due to the modulation of the zero-field splitting produced by distortion of the complexes from perfect symmetry. The transverse and longitudinal relaxation matrices for an 8S ion with such an interaction have been calculated using Redfield theory with vector-coupling methods, and diagonalised numerically to obtain relaxation rates and intensities for the degenerate transitions which contribute to the multiplet. The observed line width, which is inversely proportional to the magnetic field at low temperatures, is best described by the intensity-weighted mean transverse relaxation time for the four transitions with non-zero intensity. A least-squares fit of the data yields the square of the zero-field splitting tensor, Δ2, and a correlation time, τv, with activation energy, Ev. The physical significance of these parameters and the extent of validity of the theoretical approach are considered. The parameters are used to predict the magnetic-field dependence of the longitudinal and transverse electronic relaxation times, which are discussed in the context of their relevance to 1H-NMR relaxivity. 相似文献
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We give several equivalent characterisations of left (and hence, by duality, also of right) supported algebras. These characterisations are in terms of properties of the left and the right parts of the module category, or in terms of the classes L0 and R0 which consist respectively of the predecessors of the projective modules, and of the successors of the injective modules. 相似文献
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