F－L模型的状态方程与退禁闭相变图象

用温度场论方法计算了Ｆ－Ｌ模型在有限温度和密度下的状态方程，分析了压强对净重子数密度的等温线．结果表明，在平均场近似下，Ｆ－Ｌ模型所给出的退禁闭相变为一级相变．     

闪光灯泵浦的Nd:KGd(WO4)2激光器

报道了用闪光灯泵浦的掺钕的钨酸钆镓(Nd³⁺:KGd(WO₄)₂激光器.在重复频率1Hz,脉宽120μs的灯泵下,测量了不同透过率下激光输出能量,获得最大输出能量384mJ,斜率效率1.0%,外推阈值0.54J.在调Q运行时,Nd:KGW晶体的斜率效率为0.16%,最大输出能量46mJ.     

Poly[[diaqua(N,N‐dimethylformamide‐κO)manganese(II)]‐μ3‐sulfato]

In the title complex, [Mn(SO₄)(C₃H₇NO)(H₂O)₂]_n, each Mn^II ion has a distorted octahedral geometry formed by three O atoms of three different sulfate groups, one O atom of a dimethylformamide ligand and two water molecules. The sulfate groups act as tridentate bridging ligands connecting the Mn^II ions into a two‐dimensional layer structure which can be regraded as a 4.8² network.     

Aggregation Properties of an Amphiphilic Methanofullerene Derivative in THFH_2O Solvent Mixtures

Water-soluble fullerenes not only have a number of important applications in biological chemistry1, but also form ordered aggregate structures that can be utilized in materials science2. There are reports that some water-soluble fullerene derivatives can form ordered structures in water, such as vesicle, nanorod and nanoparticle2-5. However, relatively few reports on the aggregation process have been reported. Knowledge of factors that affect the cluster formation in solution is of consider…     

Syntheses,crystal structures and blue emission of three zinc(II) coordination polymers with a 4,4′‐dicarboxybiphenyl sulfone ligand

Three novel zinc complexes [Zn(dbsf)(H₂O)₂] ( 1 ), [Zn(dbsf)(2,2′‐bpy)(H₂O)]·(i‐C₃H₇OH) ( 2 ) and [Zn(dbsf)(DMF)] ( 3 ) (H₂dbsf = 4,4′‐dicarboxybiphenyl sulfone, 2,2′‐bpy = 2,2′‐bipyridine, i‐C₃H₇OH = iso‐propanol, DMF = N,N‐dimethylformamide) were first obtained and characterized by single crystal X‐ray crystallography. Although the results show that all the complexes 1–3 have one‐dimensional chains formed via coordination bonds, unique three‐dimensional supramolecular structures are formed due to different coordination modes and configuration of the dbsf^2? ligand, hydrogen bonds and π–π interactions. Iso‐propanol molecules are in open channels of 2 while larger empty channels are formed in 3 . As compared with emission band of the free H₂dbsf ligand, emission peaks of the complexes 1–3 are red‐shifted, and they show blue emission, which originates from enlarging conjugation upon coordination. Copyright © 2006 John Wiley & Sons, Ltd.     

Synthesis of optically active poly(N‐propargylsulfamides) with helical conformation

A novel chiral N‐propargylsulfamide monomer ( 1a ) and its enantiomer ( 1b ) were synthesized and polymerized with (nbd)Rh⁺B^?(C₆H₅)₄ as a catalyst providing poly(1) (poly( 1a ) and poly( 1b )) in high yields (≥99%). Poly(1) could take stable helices in less polar solvents (chloroform and THF), demonstrated by strong circular dichroism signals and UV–vis absorption peaks at about 415 nm and the large specific rotations; but in more polar solvents including DMF and DMSO, poly(1) failed to form helix. Quantitative evaluation with anisotropy factor showed that the helical screw sense had a relatively high thermal stability. These results together with the IR spectra measured in solvents showed that hydrogen bonding between the neighboring sulfamide groups is one of the main driving forces for poly(1) to adopt stable helices. In addition, copolymerization of monomer 1a and monomer 2 was conducted, the solubility of poly(1) was improved drastically. However, the copolymerization had adverse effects on the formation of stable helices in the copolymers. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 500–508, 2007     

Synthesis of grafted poly(p‐phenyleneethynylene) with energy donor–acceptor architecture via atom transfer radical polymerization: Towards nonaggregating and hole‐facilitating light‐emitting material

In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007     

化学位移各向导性对半整数自旋四极核的2D NMR章动的影响

考察了化学位移各向异性对半整数自旋四极核2D NMR章动的影响.用数值方法对2D NMR章动实验的演化期的Hamiltonian矩阵进行对角化,然后用帐篷法进行粉末平均,获得了自旋为I=3/2、5/2、7/2和9/2的四极核在不同化学位移各向异性下的2D NMR章动谱.实验结果与理论计算符合较好.     

布拉格方程在高聚物结构研究中的应用

本文将布拉格方程推广应用到高聚物的结构研究中，得到了经不同剂量辐照的聚乙烯单晶的长周期，并辅以示差扫描量热法研究了γ－射线辐照对聚乙烯单晶结构的影响．     

HPLC法测定阿奇霉素葡萄糖注射液中阿奇霉素的含量

利用高效液相色谱法，以VP-ODS型色谱柱，乙腈-异丙醇-水-氨水（60：25：15：0.1)为流动相，于210nm波长处测定了阿奇霉素葡萄糖注射液中阿奇霉素葡萄糖注射液中阿奇霉素的含量。阿奇霉素的浓度在0.75-1.75mg/mL线性关系良好，线性方程的A=881910.4c-16208.2，相关系数r=0.9999。阿奇霉素的平均回收率为99.59%，测定结果的相对标准偏差为1.31%。