采用热处理方法提高MEH-PPV单层聚合物有机发光二极管发光性能的研究

对以MEH－PPV为发光层的单层聚合物有机发光二极管（OLED）器件在最佳条件下进行真空热处理，并用金相显微镜观察施加电压后器件的阴极表面形貌。发现处理后的器件阴极表面的气泡及黑斑明显减少。器件的发光性能显著提高。与未经处理的器件相比，最大相对发光强度提高了一个数量级、启亮电压降低了2．0V，半寿命提高了12．7倍。初步分析表明热处理方法提高器件发光性能的主要原因在于有效地减少了器件在工作过程中由于焦耳热产生的某些气体，从而减少阴极表面气泡及黑斑的出现，另一方面，热处理方法也增强了有机发光层与阴极接触界面的结合力，提高电子注入水平。     

Clement-Desormes实验之不足

通过分析实验数据发现，Clement-Desormes的测量结果接近理论值存在某种巧合，该实验所用的测量原理并不能充分解释其实验现象。     

The Millimeter-Wave Spectrum of 2,3-Dihydrofuran

The millimeter-wave spectrum of 2,3-dihydrofuran in the ground and five ring-puckering excited states has been measured in the frequency range 100–250 GHz. The ground and first ring-puckering excited states have been fitted to a two-state Hamiltonian including Coriolis coupling interaction. The determined energy difference of 18.684(7) cm⁻¹between these states and theaandbtype coupling parameters are consistent with the ring-puckering potential function and the previously observed dependence of the centrifugal distortion constants Δ_JK, Δ_K, and δ_K. A small ring-puckering dependence of the quartic centrifugal distortion constants Δ_Jand δ_Jhas been also observed. This dependence is well accounted for in terms of the ring-puckering potential function and the vibrational dependence of the rotational constants.     

Pure phase correlation with improved discrimination capability

Pure phase correlation with improved discrimination capability is proposed. The improvement is achieved by designing a region of support based on the discrimination capability (DC). We propose four approaches for designing this region; some of them consider the input scene in the design, while others are input scene invariant. The performances of these approaches are compared by numerical simulation. The DC is improved significantly for the multi-object scenes even when using an input scene invariant region of support design.     

两种亚波长金属波片的透射特性对比

综合等效介质理论和表面等离子激元(SPP)Bloch模型,对比分析了两种新的亚波长光栅结构:二维矩形金属光栅和二维椭圆柱金属光栅。利用时域有限差分(FDTD)算法,对比分析了两种结构的透射率及其相位延迟与入射光波长及偏振角变化的关系,尤其两种结构实现λ/4波片功能所对应的透射特性。仿真结果表明,当入射光偏振角为75°时,两种结构均可实现λ/4波片功能,此时二维矩形和椭圆柱金属光栅的透射率分别为0.77和0.67,表明二维矩形金属光栅比椭圆柱光栅具有更好的透射效果。对应550～800nm的入射波长,两种光栅在各自允许的入射偏振角范围内均表现了较为平坦的宽带透射特性。     

鲁米诺-铁氰化钾化学发光体系测定氧氟沙星

基于氧氟沙星对鲁米诺-铁氰化钾化学发光体系具有较强的增敏作用,建立了一种测定氧氟沙星的新方法。该法简便、快速、灵敏度高,化学发光强度的变化值与氧氟沙星的浓度在6.84×10^-9—2.28×10^-5mol/L范围内呈线性关系,检出限（S/N=3）达4.56×10^-10mol/L。方法成功用于胶囊中氧氟沙星含量的测定,结果令人满意。     

轴对称折叠组合多通道板条型CO2激光器

基于轴对称折叠组合腔CO2激光器和多通道板条型CO2激光器的特点,提出了轴对称折叠组合多通道板条型CO2激光器模型。通过对模型建立、参数设定、腔特性分析、数值模拟等方面的研究,得到输出光强的近场分布规律。通过分析可知其具有共面输出、多光束并和、光束分布高度对称、近场光能强并分布集中等特点。对CO2激光器的研究有一定的参考价值。     

Changes in surface morphology and work function caused by corrosion in aluminum alloys

Corrosion behavior of a material is complicated and can affect strongly its surface physical and chemical properties. In this study, the effect of corrosion on surface morphology and electron work function (EWF) of various Al alloys was comparatively investigated using a scanning electron microscopy and a scanning Kelvin probe. The experimental results showed that the change in EWF with corrosion time was not linear, but firstly increased and then decreased. The theoretical treatments demonstrated that such a change in EWF did not only depend on the surface roughness, but also correlate with oxide layers formed at the surfaces of Al alloys. The present results can also be used to reasonably explain the correlation between surface roughness and EWF reported previously.     

一体化核磁共振谱仪控制台的软件系统设计

提出了一体化核磁共振谱仪控制台的软件系统设计方案,主要包括2部分,一部分是安装在谱仪控制台上的嵌入式Linux操作系统及实时控制软件,另外一部分是PC机上的界面控制软件. 2部分软件之间利用socket网络接口进行数据交互, 采用TCP/IP通信协议,这样既能保证数据传输的可靠性又可以达到较高的数据传输速率. 通过网络通信,该谱仪控制台还可以接受远程操控和系统升级. 该文具体阐述了该软件系统的设计思路和设计方法,对设计的软件系统进行了实验测试,并对实验结果进行了讨论.     

HPLC测定人工蛹虫草培养基中的虫草素

建立蛹虫草培养基中虫草素的含量测定方法.采用反相高效液相色谱法,以十八烷基键合相硅胶为固定相,0.01mol/L的磷酸二氢钾溶液(pH=6.0)-乙腈(93∶7,V/V)为流动相,检测波长260nm,流速1.0mL/min进行分析.结果 虫草素在2.0-40.0μg·mL-1范围内线性良好(r=0.9999);平均加标回收率分别为96.8％、98.1％和100.9％,RSD分别为3.33％,2.88％和1.60％(n=3);方法精密度RSD为0.29％(n=5).该法分析时间短,结果准确,重现性好,适合人工蛹虫草培养基中的虫草素的含量测定.