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991.
992.
R. Resel M. Oehzelt O. Lengyel T.U. Schülli G. Hlawacek C. Teichert G. Koller 《Surface science》2006,600(19):4645-4649
A para-sexiphenyl monolayer of near up-right standing molecules (nominal thickness of 30 Å) is investigated in-situ by X-ray diffraction using synchrotron radiation and ex-situ by atomic force microscopy. A terrace like morphology is observed, the step height between the terraces is approximately one molecular length. The monolayer terraces, larger than 20 μm in size, are extended along the [0 0 1] direction of the TiO2(1 1 0) substrate i.e. along the Ti-O rows of the reconstructed substrate surface. The structure of the monolayer and its epitaxial relationship to the substrate is determined by grazing incidence X-ray diffraction. Extremely sharp diffraction peaks reveal high crystalline order within the monolayer, which was found to have the bulk structure of sexiphenyl. The monolayer terraces are epitaxially oriented with the (0 0 1) plane parallel to the substrate surface (out-of-plane order). Four epitaxial relationships are observed. This in-plane alignment is determined by the arrangement of the terminal phenyl rings of the sexiphenyl molecules parallel to the oxygen rows of the substrate. 相似文献
993.
Janine C. Swarbrick 《Applied Surface Science》2006,252(15):5622-5626
We have used the established technique of electrospray in developing a portable vacuum electrospray system which can deposit, in vacuo, dissolved molecules onto a sample which may then be analysed by UHV techniques. As an initial test of the system we have analysed silicon samples with an electrosprayed layer of poly(ethylene) oxide (PEO) using atomic force microscopy (AFM). The polymer forms different structures depending on the voltage applied to the emitter, and solution composition. The system is part of our ongoing effort to deposit other materials such as nanoparticles, and large dye molecules for developing molecular dye sensitised solar cells. 相似文献
994.
M.A.C. Potenza M.D. Alaimo D. Pescini D. Magatti F. Ferri M. Giglio 《Optics and Lasers in Engineering》2006,44(7):722
We show that the time evolution of near-field scattering speckles, originated by a fluid suspension of particles, provides information about the velocity field in the fluid. This information can be extracted from a statistical analysis of speckle fields taken at different times, either by measuring their cross-correlation function or by recovering the power spectrum corresponding to the difference between the two speckle fields. Experimental data are in accordance to the expected behaviors. The results are independent of the scatterer's size, allowing one to exploit the technique also with sub-wavelength tracking particles. 相似文献
995.
996.
A domain partitioning algorithm for minimizing or maximizing a Lipschitz continuous function is enhanced to yield two new, more efficient algorithms. The use of interval arithmetic in the case of rational functions and the estimates of Lipschitz constants valid in subsets of the domain in the case of others and the addition of local optimization have resulted in an algorithm which, in tests on standard functions, performs well. 相似文献
997.
Despite its capability of high spatial resolution, simulation of turbulent flows with traditional Lagrangian (front tracking) scheme is often discouraged by numerical instability caused by clustering of marker nodes and topological changes of fronts. Contour advection surgery (CAS), being a robust front tracking scheme, can limit the growth of front complexity during simulation without jeopardizing accuracy or efficiency. This allows it to open up an advantage over traditional front-tracking schemes. It has already been demonstrated that CAS, with incorporation of the reaction sheet model, can accurately simulate the propagation and advection of a turbulent premixed V-shaped flame. In this study, it is further tested with 10 values of vortex circulation. A range of upstream turbulence levels of 1.8–19.8% was obtained. Results indicate that upstream turbulence increase the average flame length, flame zone area and the overall burning rate. Flame surface density Σ was also estimated. Maximum values of Σ obtained lie in the range 0.1–1.4 mm−1. Skewness towards the burnt region was observed in all profiles of Σ. Similar to results from laboratory experiments, it was found that Σ values decreases with upstream turbulence. From this study, the ability of CAS to cope with intense turbulence is demonstrated and a better quantitative understanding on the scheme has also been acquired. 相似文献
998.
Due to the discovery of Au as a catalyst for low temperature CO oxidation, the adsorption of CO on Au surfaces has attracted a lot of attention recently. On stepped and rough single crystal surfaces as well as on deposited particles two characteristic desorption states above 100 K have been observed via TPD. We have studied Au deposits on graphite in order to elucidate the nature of these desorption peaks in more detail. For this purpose, Au was deposited at 100 K and 300 K on HOPG as a weakly interacting support. In analogy to other supports, we obtain two desorption states (∼140 K and ∼170 K) whose relative intensities depend strongly on the deposition temperature with the high temperature peak being much more pronounced for the 100 K deposits. After annealing to 600 K, both states drastically lose intensity. XP spectra, on the other hand, show virtually no decrease of the Au 4f intensity as would be expected for desorption or significant changes of the particle morphologies. We conclude that both desorption peaks are defect-related and connected with under-coordinated Au atoms that are lost for the most part upon annealing. These sites could be located at the perimeter of dendritic islands or on small, defect-rich particles in addition to larger particles not adsorbing CO at 100 K. Preliminary STM results are in favour of the second interpretation. 相似文献
999.
Differential algebraic equations with after-effect 总被引:4,自引:0,他引:4
C. T. H. Baker C. A. H. Paul H. Tian 《Journal of Computational and Applied Mathematics》2002,140(1-2):63-80
In this paper, we are concerned with the solution of delay differential algebraic equations. These are differential algebraic equations with after-effect, or constrained delay differential equations. The general semi-explicit form of the problem consists of a set of delay differential equations combined with a set of constraints that may involve retarded arguments. Even simply stated problems of this type can give rise to difficult analytical and numerical problems. The more tractable examples can be shown to be equivalent to systems of delay or neutral delay differential equations. Our purpose is to highlight some of the complexities and obstacles that can arise when solving these problems, and to indicate problems that require further research. 相似文献
1000.
J A Bennell C N Potts J D Whitehead 《The Journal of the Operational Research Society》2002,53(10):1109-1117
In the min-max loop layout problem, machines are to be arranged around a loop of conveyor belt. The ordering of the machines dictates the number of circuits of the conveyor belt required to manufacture each of several products. The goal is to find an ordering of the machines that minimises the maximum number of circuits required for the manufacture of any of the products. Since the problem is strongly NP-hard, the study of heuristic methods is of interest. This paper proposes iterated descent and tabu search algorithms, and a randomised insertion algorithm. Results of extensive computational tests show that all of our algorithms outperform a previously known algorithm that applies a greedy heuristic to the solution of a linear programming relaxation. The best quality solutions are obtained with iterated descent. This adds further evidence to the belief that iterated descent can produce high quality solutions to a variety of combinatorial optimisation problems. Moreover, unlike some other local search algorithms, iterated descent does not require much tuning in order to be competitive. 相似文献