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61.
B. Pignataro L. Chi S. Gao B. Anczykowski C. Niemeyer M. Adler H. Fuchs 《Applied Physics A: Materials Science & Processing》2002,74(3):447-452
Self-assembled oligomeric nanostructures consisting of bisbiotinylated DNA fragments connected by the protein streptavidin
(STV) are studied by dynamic scanning force microscopy (SFM) operating in air. A comparison of the images taken in repulsive
and attractive regimes is systematically made on DNA and STV structures. Stable and reproducible SFM images are obtained in
the attractive regime by using a special feedback circuit, called Q-control. On the other hand, when SFM is operating in the
repulsive regime, deformation of the structures that reduce the resolution and the image quality are clearly observable. The
heights of both DNA and STV have been measured as a function of the tip/molecule interaction forces. This study offers the
possibility to suggest a different mechanical behavior of DNA with respect to STV.
Received: 24 July 2001 / Accepted: 3 December 2001 / Published online: 4 March 2002 相似文献
62.
本文通过对大量的黄酮类化合物13C NMR图谱的分析和研究,总结了不同类型的黄酮类化合物的13C NMR图谱特征及化学位移规律.对影响黄酮类化合物结构骨架上不同位置碳原子化学位移的因素进行了分析,建立了用于黄酮类天然产物13C NMR图谱智能解析的知识库. 相似文献
63.
高智民 《纯粹数学与应用数学》1994,10(2):1-5
本文证明了:若X是K-半分层空间,f是闭映射,则f(X)是K-半分层空间,这一结果推广改进了Lutzer与高国士的有关结果。 相似文献
64.
Observation of spontaneous pattern with six-fold symmetry in disk-shaped ZnO complex microstructures
L.W. Yang Y.J. Gao X.L. Wu Y.M. Yang G.S. Huang Z.Y. Zhang P.K. Chu 《Applied Physics A: Materials Science & Processing》2007,89(1):173-176
Using a simple vapor phase transport technique, we have fabricated unique complex disk-shaped ZnO microstructures comprising
a small disk coaxially grown on a large one and observed spatially perfect six-fold symmetric patterns. The observed results
can be explained based on the spontaneous nanoindentation (NI) effect under the geometric constraints and the explanation
can be extended to fathom the growth mechanism of other highly symmetrical ZnO nanostructures. Our results indicate that NI
not only can elucidate the mechanical properties of surfaces and thin films but also is an effective approach to fabricate
ordered nanostructures with high precision on the location of the building blocks.
PACS 81.16.Rf; 81.07.-b; 81.05.Dz 相似文献
65.
Sang Kyu Lee Min Ju Cho Jung‐Il Jin Dong Hoon Choi 《Journal of polymer science. Part A, Polymer chemistry》2007,45(3):531-542
New photocrosslinkable maleimide copolymers have been synthesized by the attachment of a tricyanopyrrolidene‐based chromophore. The 2‐(3‐cyano‐4‐(2‐{4‐[hexyl‐(6‐hydroxy‐hexyl)‐amino]‐phenyl}‐vinyl)‐5‐oxo‐1‐{4‐[4‐(3‐oxo‐3‐phenyl‐propenyl)‐ phenoxy]‐butyl}‐1,5‐dihydro‐pyrrol‐2‐ylidene)‐malononitrile chromophore exhibits nonlinear optical activity and contains a chalcone moiety that is sensitive to UV light (λ = 330–360 nm) for crosslink formation. The maleimide monomers have also been functionalized with chalcone moieties. The resultant copolymers exhibit great processability, and one of them shows a maximum electrooptic coefficient of 90 pm/V at 1300 nm. We could control the thermal stability of the electrooptic coefficient with the newly synthesized photoreactive copolymers successfully. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 531–542, 2007 相似文献
66.
Ju Yeon Woo Eun Hee Kim Tae Hoon Yoon Jae Chang Kim Byung Kyu Kim 《Liquid crystals》2007,34(9):1115-1120
Chiral dopants were added to the formulation of holographic polymer-dispersed liquid crystals and the effects studied in terms of grating formation dynamics, morphology, diffraction efficiency, contrast ratio and electro-optical properties of the films. A gradual increase of real-time diffraction efficiency, decrease of droplet size and increase of diffraction efficiency of the composite film were obtained with the addition and increasing content of chiral dopant, due to the increased viscosity of the liquid crystal (LC) doped with the chiral dopant leading to decreased droplet coalescence. The contrast ratio decreased with increasing content of chiral dopant due to the difficult orientation of LC molecules caused by the formation of a helical structure. Addition of a small amount of the chiral dopant increased the driving voltage slightly, whereas the decay time is decreased significantly as a result of the high twisting of the helical structure. 相似文献
67.
Backstepping design is proposed for synchronization of Genesio chaotic system. Firstly, the control problem for the chaos synchronization of nominal Genesio systems without unknown parameters is considered. Next, an adaptive backstepping control law is derived to make the error signals between drive Genesio system and response Genesio system with an uncertain parameter asymptotically synchronized. Finally, the approach is extended to the synchronization problem for the system with three unknown parameters. The stability analysis in this article is proved by using a well-known Lyapunov stability theorem. Note that the approach provided here needs only a single controller to realize the synchronization. Two numerical simulations are presented to show the effectiveness of the proposed chaos synchronization scheme. 相似文献
68.
W. Gao M. Li R. Klie E.I. Altman 《Journal of Electron Spectroscopy and Related Phenomena》2006,150(2-3):136-149
Oxide catalysts are frequently used to convert toxic species to environmentally benign molecules, and to prevent the formation of toxic species in the first place. In this paper, growth and characterization of model oxide systems employed in both approaches is discussed. An example of the former approach is the selective catalytic reduction (SCR) of NO emitted from power plants by NH3, which employs tungsten and vanadium oxides supported on the anatase polymorph of TiO2. To model SCR catalysts, epitaxial titanium, vanadium and tungsten oxide films were grown using molecular beam epitaxy and magnetron sputtering. Two different anatase orientations were grown on LaAlO3 substrates and their interactions with vanadia were characterized. On LaAlO3 (0 0 1), anatase exposed a (4 × 1) reconstructed (0 0 1) surface. Vanadia lifted the reconstruction and at 1 ML a (1 × 1) surface with mostly V5+ was observed. Continued V2O5 growth led to loss of order, but at high temperatures epitaxial VO2 could be grown; vanadia behaved similarly on anatase films on LaAlO3 (1 1 0). Results suggested that the monolayer is pseudomorphic with O adsorption oxidizing the surface V to 5+, since the anatase structure cannot accommodate more bulk oxygen, only a monolayer can be pseudomorphic and have only V5+. Thus the vanadia monolayer has unique structural and chemical properties that can help explain why vanadia monolayers on TiO2 are much more active than bulk V2O5. For WO3, a series of added row reconstructions were observed as the epitaxial films were reduced. The effect of these structures on surface chemistry was characterized by studying 1-propanol adsorption. The results indicated that the structure of the WO3 surface did not alter its catalytic function but had a strong effect on reaction kinetics. As an example of a system where catalysts prevent the formation of toxic species, the reactivity of oxidized Pd surfaces used in CH4 catalytic combustion were studied. An ordered PdO-like monolayer was found to be less reactive towards CO than adsorbed O on Pd. On the other hand, the PdO layer favored a lower activation energy C3H6 oxidation pathway. The results indicated that Pd oxidation reduces the sticking coefficient of reactive species but once molecules adsorb, the oxide surface can reduce the activation energy for subsequent reaction. 相似文献
69.
70.
O.E. Petrova N.B. Tarasova A.Ju. Alyabyev M.N. Davydova N.L. Loseva 《Thermochimica Acta》2006,445(1):67-69
Calorimetric results indicate that nitrocellulose (NC)-induced changes in the metabolism of Desulfovibrio desulfuricans 1388 are caused by both chemical (nitrate) and physical (biofilm formation) factors. Nitrate added to lactate-based culture medium with nitrocellulose competed for the electron flux from lactate and suppressed the bacterial sulfidogenesis and growth. The presence of an insoluble compound (carbon backbone of the polymer) induced the creation of a biofilm-like structure with its own metabolism. 相似文献