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61.
Andrew J. Parker Malcolm J. Joyce Colin Boxall 《Journal of Radioanalytical and Nuclear Chemistry》2014,300(2):769-777
A phantom for the evaluation of electrokinetic remediation of radioactive species from water saturated concrete is described. The phantom has been designed to be a general analogue for environments where structural concrete is saturated by radioactive aqueous solutions and where electrokinetic remediation may be deployed. It is also a specific analogue for the walls of storage ponds for legacy spend nuclear fuel pins where the pond water comprises a large volume of hazardous active waste that may penetrate the pond wall. The fabricated phantom was evaluated using a fixed electrical potential to monitor the rate of cationic transport of K+ through concrete samples of different thickness (20 and 35 mm respectively). Results of the evaluation show K+ diffusion coefficients of 5.20 × 10?13 and 7.61 × 10?13 m2 s?1 for the 20 mm and 35 mm samples, consistent with those seen in literature for the transport of caesium through concrete of similar thickness. The phantom offers a means of experimental validation of computational electrokinetic models as well as providing a basis to test the effects of electrode material on ionic transport rates, to interrogate the effects of pH on all components of the system, and as a basis for instruction, education and training in nuclear decommissioning and waste treatment. 相似文献
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Joyce Cristale Izabela Oliveira Santos Enelton Fagnani 《Journal of separation science》2020,43(4):748-755
Organophosphate esters used as flame retardants and plasticizers are ubiquitous contaminants in surface waters. Many studies indicate that these compounds are neurotoxicants, endocrine disruptors, and may affect reproduction and development of aquatic organisms. Thus, analytical methods that allow accurate quantification of these contaminants at environmentally relevant concentrations are desirable for risk assessment studies. In this study, a method based on solid phase extraction and gas chromatography coupled to mass spectrometry was developed for determination of organophosphate esters in river water extracts. Multivariate optimization was used to determine the best conditions for injection of larger volumes of sample in a Programmable Temperature Vaporization inlet. Furthermore, the matrix effect on the instrumental response was evaluated and compensated by association of extraction‐blank‐matched calibration and isotopically labeled focus standards. The method quantification limits ranged from 0.009 to 0.11 µg/L, staying below the predicted non‐effect concentration for the aquatic compartment for all analytes, which is a requisite for using in risk assessment studies. The method was applied to freshwater samples collected in rivers from the Sao Paulo State, Brazil, and eight out of the ten target organophosphate esters were quantified, being tris(2‐chloroisopropyl) phosphate and tris(phenyl) phosphate the most frequently detected compounds. 相似文献
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Dynamic states of cancer cells moving under shear flow in an antibody-functionalized microchannel are investigated experimentally and theoretically. The cell motion is analyzed with the aid of a simplified physical model featuring a receptor-coated rigid sphere moving above a solid surface with immobilized ligands. The motion of the sphere is described by the Langevin equation accounting for the hydrodynamic loadings, gravitational force, receptor-ligand bindings, and thermal fluctuations; the receptor-ligand bonds are modeled as linear springs. Depending on the applied shear flow rate, three dynamic states of cell motion have been identified: (i) free motion, (ii) rolling adhesion, and (iii) firm adhesion. Of particular interest is the fraction of captured circulating tumor cells, defined as the capture ratio, via specific receptor-ligand bonds. The cell capture ratio decreases with increasing shear flow rate with a characteristic rate. Based on both experimental and theoretical results, the characteristic flow rate increases monotonically with increasing either cell-receptor or surface-ligand density within certain ranges. Utilizing it as a scaling parameter, flow-rate dependent capture ratios for various cell-surface combinations collapse onto a single curve described by an exponential formula. 相似文献
66.
A method for the amidation of aldehydes with PhI=NTs/PhI=NNs as the nitrogen source and an inexpensive iron(II) chloride + pyridine as the in situ formed precatalyst under mild conditions at room temperature or microwave assisted conditions is described. The reaction was operationally straightforward and accomplished in moderate to excellent product yields (20-99%) and with complete chemoselectivity with the new C-N bond forming only at the formylic C-H bond in substrates containing other reactive functional groups. By utilizing microwave irradiation, comparable product yields and short reaction times of 1 h could be accomplished. The mechanism is suggested to involve insertion of a putative iron-nitrene/imido group to the formylic C-H bond of the substrate via a H-atom abstraction/radical rebound pathway mediated by the precatalyst [Fe(py)(4)Cl(2)] generated in situ from reaction of FeCl(2) with pyridine. 相似文献
67.
Stephen L. Howard Joyce E. Newberry Rosario C. Sausa Andrzej W. Miziolek 《Journal of the American Society for Mass Spectrometry》1993,4(2):152-158
A recently developed research apparatus for characterization of low-pressure premixed flames has been developed and was used to characterize the C2H4/N2O/Ar flame at 20 torr. This instrument incorporates several diagnostic techniques in one apparatus so that individual techniques can be quantitatively compared and the usable detection range (both in terms of resolution and species detection) expanded. Results discussed in this report include mass analysis by triple quadrupole mass spectrometer and temperature measurement by thermocouple. Concentration profiles in the one-dimensional flame include CO, N2, and C2H4, at nominal m/z 28 as well as CO2 and N2O at m/z 44. 相似文献
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A. Ray R. Sriravindrarajah J.-P. Guerbois P. S. Thomas S. Border H. N. Ray J. Haggman P. Joyce 《Journal of Thermal Analysis and Calorimetry》2007,88(1):279-283
The use of supplementary cementitious materials (SCM) is a well established practice worldwide in the manufacture of Portland cement (PC)-based construction materials. While utilisation of industrial by-products has been successful, the potential of mining wastes is yet to receive adequate attention in the context of construction materials. In an expanded form perlite, which is a naturally occurring, hydrated volcanic siliceous glass, is an ideal material as a lightweight aggregate for use in a wide range of construction materials including concrete. The mining and processing of the grades of perlite required for the production of lightweight aggregate results in the creation of a fine grained waste which currently has no economic value. This paper reports preliminary data on the utilisation of waste perlite fines as a SCM in calcium silicate-based construction material and discusses the potential of this mining waste to reduce the environmental impact of the production of conventional cement-based construction materials. 相似文献