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101.
Perišić-Janjić Nada U. Djaković-Sekulić Tatjana Lj. Jevrić Lidija R. Jovanović Bratislav Ž. 《平面色谱法杂志一现代薄层色谱法》2005,18(3):212-216
JPC – Journal of Planar Chromatography – Modern TLC - Quantitative structure-retention relationships (QSRR) have been used to study the chromatographic behavior of some s-triazines.... 相似文献
102.
Negative ion MALDI‐TOF MS,ISD and PSD of neutral underivatized oligosaccharides without anionic dopant strategies,using 2,5‐DHAP as a matrix
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Oligosaccharides represent complex class of analytes for mass spectrometric analysis due to the high variety of structural isomers concerning glycosidic linkages and possible branching. A systematic study of the negative ion mode matrix‐assisted laser desorption/ionization (MALDI) mass spectrometry of various neutral oligosaccharides under selection of an appropriate matrix, like 2,5‐dihydroxyacetophenone (2,5‐DHAP) is reported here, without commonly used anion dopant strategies. Nevertheless, we were able to generate relevant in‐source decay (ISD) cross‐ring fragment ions, typically obtained in the negative ion mode. Data observed indicate that the intrinsic property of the terminal non‐reduced aldose is crucial for this behavior. A systematic study of the post source decay (PSD) of molecular, pseudomolecular and ISD cross‐ring cleavage precursor ions is reported here. A direct comparison of the positive and negative ion mode MALDI MS1 and PSD behavior of neutral oligosaccharides could also be performed under the use of the same matrix preparation, because 2,5‐DHAP is fully compatible with positive ion mode acquisition. We found that PSD spectra of deprotonated neutral oligosaccharides obtained in the negative ion mode are richer, because they contained both glycosidic and cross‐ring fragment ions. However, we also found that cross‐ring fragment ions are readily produced in the positive ion mode when potassiated precursor ions were selected. In addition, we show evidence that non‐anionic dopants and specific instrumental parameters can also significantly influence the ISD fragmentation. Taken together, our results should increase our understanding of oligosaccharide behavior in the negative ion mode as well as increase our knowledge regarding many aspects of in‐source MALDI chemistry. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
103.
Milica Kosović Snežana Jovanović Goran A. Bogdanović Gerald Giester Željko Jaćimović Živadin D. Bugarčić 《Journal of Coordination Chemistry》2016,69(19):2819-2831
Substitution reactions of [Pt(terpy)Cl]+ (terpy = 2,2′;6′,2′′-terpyridine), [Pt(bpma)Cl]+ (bpma = bis(2-pyridylmethyl)amine), [Pt(dien)Cl]+ (dien = diethylenetriamine or 1,5-diamino-3-azapentane) and [Pt(tpdm)Cl]+ (tpdm = tripyridinedimethane) with nitrogen donor heterocyclic molecules, such as 3-amino-4-iodo-pyrazole (pzI), 5-amino-4-bromo-3-methyl-pyrazole (pzBr) and imidazole (Im), were studied in aqueous 0.10 M NaClO4 in the presence of 10 mM NaCl using variable-temperature UV–vis spectrophotometry. The second-order rate constants k2 indicate decrease in reactivity in the order [Pt(terpy)Cl]+ > [Pt(bpma)Cl]+ > [Pt(tpdm)Cl]+ > [Pt(dien)Cl]+. The most reactive nucleophile among the heterocyclic compounds is imidazole, while pzI shows slightly higher reactivity than pzBr. Activation parameters were also determined and the negative values for entropies of activation, ΔS≠, support an associative mode of substitution for all substitution processes. Crystal structure of [Pt(bpma)(pzBr)]Cl2·2H2O was determined by single-crystal X-ray analysis. The coordination geometry of the complex is distorted square-planar while the bond distance Pt–N2(pzBr) is longer than the other three Pt–N distances. 相似文献
104.
Vukadin M. Leovac Ljiljana S. Jovanović Vladimir Divjaković Andrej Pevec Ivan Leban Thomas Armbruster 《Polyhedron》2007
This paper describes the synthesis of the first Ni(II) complexes with pyridoxal semicarbazone (PLSC), viz. Ni(PLSC)Cl2 · 3.5H2O (1), [Ni(PLSC)(H2O)3](NO3)2 (2), Ni(PLSC)(NCS)2 · 4H2O (3), [Ni(PLSC-2H)NH3] · 1.5H2O (4), as well as two new complexes with pyridoxal thiosemicarbazone (PLTSC), [Ni(PLTSC-H)py]NO3 (5) and [Ni(PLTSC-H)NCS] (6). Complexes 1–3 are paramagnetic and have most probably an octahedral structure, for complex 2 this was proved by X-ray diffraction analysis. In contrast, complexes 4–6 are diamagnetic and have a square-planar structure, and in the case of complex 5 this was also confirmed by X-ray structural analysis. In all cases the Schiff bases are coordinated as tridentate ligands with an ONX (X = O, PLSC; X = S, PLTSC) set of donor atoms. With the complexes involving the neutral form of PLSC and the monoanionic form of PLTSC, the PL moiety is in the form of a zwitterion. In addition to the above-mentioned techniques, all the complexes were characterized by measuring their molar conductivities, UV–Vis and partial IR spectra. 相似文献
105.
Snežana Jovanović Jovana Bogojeski Marijana Petković 《Journal of Coordination Chemistry》2015,68(17-18):3148-3163
Substitution reactions of the dinuclear Pt(II) complexes, [{Pt(en)Cl}2(μ-pz)]2+ (1), [{Pt(dach)Cl}2(μ-pz)]2+ (2) and [{Pt(dach)Cl}2(μ-4,4?-bipy)]2+ (3), and corresponding aqua analogs with selected biologically important ligands, viz. 1,2,4-triazole, L-histidine (L-His) and guanosine-5?-monophosphate (5?-GMP) were studied under pseudo-first-order conditions as a function of concentration and temperature using UV–vis spectrophotometry. The reactions of the chloride complexes were followed in aqueous 25 mmol L?1 Hepes buffer in the presence of 40 mmol L?1 NaCl at pH 7.2, whereas the reactions of the aqua complexes were studied at pH 2.5. Two consecutive reaction steps, which both depend on the nucleophile concentration, were observed in all cases. The second-order rate constants for both reaction steps indicate a decrease in the order 1 > 2 > 3 for all complexes. Also, the pKa values of all three aqua complexes were determined. The order of the reactivity of the studied ligands is 1,2,4-triazole > L-His > 5?-GMP. 1H NMR spectroscopy and HPLC were used to follow the substitution of chloride in the dichloride 1, 2, and 3 complexes by guanosine-5?-monophosphate (5?-GMP). This study shows that the inert and bridging ligands have an important influence on the reactivity of the studied complexes. 相似文献
106.
107.
Željka Jovanović Aleksandra Radosavljević Milorad Šiljegović Nataša Bibić Vesna Mišković-Stanković Zorica Kačarević-Popović 《Radiation Physics and Chemistry》2012,81(11):1720-1728
Silver nanoparticles (AgNPs) were synthesized in situ by γ-irradiation using poly(N-vinyl-2-pyrrolidone) (PVP) as a capping agent. The concentration, molecular weight and the structure (crosslinked and interpenetrated network) of PVP were varied, in order to determine the influence of the capping agent in the radiolytic synthesis of the Ag/PVP nanosystems. Transmission electron microscopy (TEM) showed that AgNPs obtained from the solutions containing higher PVP concentration and higher molecular weight were spherical in shape, with narrow size distribution and a diameter of~6 nm, while slightly larger rod-shaped silver agglomerates, with bimodal nanoparticle size distribution and diameters of ~10 nm and ~20 nm were obtained from the solutions containing lower PVP concentration and lower molecular weight. Strong plasmon coupling and extending of plasmon resonance was observed by UV–vis spectroscopy, as a result of formation of nanorod-like agglomerates. Crosslinked and interpenetrated network did not affect the structure of synthesized AgNPs. Ag/PVP nanocomposite, in the form of thin film, was obtained by solvent evaporation from Ag/PVP colloid solution with 10 wt% of PVP, and characterized by FTIR spectroscopy. The interactions in Ag/PVP nanocomposite are shown to be the result of the coordination bonding between AgNPs and nitrogen from pyrrolidone ring of PVP. The optical properties of investigated Ag/PVP nanosystems, as measured by the values of optical band gap, Eg, are mainly the consequence of the interparticle distance as a result of the concentration and the structure of surrounding PVP macromolecules. 相似文献
108.
S. Stevanovi? D. Tripkovi? J. Rogan K. Popovi? J. Lovi? A. Tripkovi? V. M. Jovanovi? 《Journal of Solid State Electrochemistry》2012,16(10):3147-3157
High surface area carbon-supported Pt, PtRh, and PtSn catalysts were synthesized by microwave-assisted polyol procedure and tested for ethanol oxidation in perchloric acid. The catalysts were characterized by thermogravimetric analysis (TGA), X-ray diffraction (XRD), scanning tunnelling microscopy (STM), TEM, and EDX techniques. STM analysis of unsupported catalysts shows that small particles (~2?nm) with a narrow size distribution are obtained. TEM and XRD examinations of supported catalysts revealed an increase in particle size upon deposition on carbon support (diameter?~?3?nm). The diffraction peaks of the bimetallic catalysts in X-ray diffraction patterns are slightly shifted to lower (PtSn/C) or higher (PtRh/C) 2θ values with respect to the corresponding peaks at Pt/C catalyst as a consequence of alloy formation. Oxidation of ethanol is significantly improved at PtSn/C with the onset potential shifted for?~?150?mV to more negative values and the increase of activity for approximately three times in comparison to Pt/C catalyst. This is the lowest onset potential found for ethanol oxidation at PtSn catalysts with a similar composition. Chronoamperometric measurements confirmed that PtSn/C is notably less poisoned than Pt/C catalyst. PtRh/C catalyst exhibited mild enhancement of overall electrochemical reaction in comparison to Pt/C. 相似文献
109.
Jelena S. ?or?evi? Ana M. Kalijadis Ksenija R. Kumri? Zoran M. Jovanovi? Zoran V. Lau?evi? Tatjana M. Trti?-Petrovi? 《Central European Journal of Chemistry》2012,10(4):1271-1279
In this study the application of home-made unmodified (GC) and bulk modified boron doped glassy carbon (GCB) electrodes for the voltammetric determination of the linuron was investigated. The electrodes were synthesized with a moderate temperature treatment (1000°C). Obtained results were compared with the electrochemical determination of the linuron using a commercial glassy carbon electrode (GC-Metrohm). The peak potential (E p ) of linuron oxidation in 0.1 mol dm−3 H2SO4 as electrolyte was similar for all applied electrodes: 1.31, 1.34 and 1.28 V for GCB, GC and GC-Metrohm electrodes, respectively. Potential of linuron oxidation and current density depend on the pH of supporting electrolyte. Applying GCB and GC-Metrohm electrodes the most intensive electrochemical response for linuron was obtained in strongly acidic solution (0.1 mol dm−3 H2SO4). Applying the boron doped glassy carbon electrode the broadest linear range (0.005–0.1 μmol cm−3) for the linuron determination was obtained. The results of voltammetric determination of the linuron in spiked water samples showed good correlation between added and found amounts of linuron and also are in good agreement with the results obtained by HPLC-UV method. This appears to be the first application of a boron doped glassy carbon electrode for voltammetric determination of the environmental important compounds. 相似文献
110.
Dj. Jovanović B. Nikolić T. Radić D.M. Djokić R. Gajić 《Photonics and Nanostructures》2012,10(4):657-666
We theoretically investigated the symmetry properties of the modes in two-dimensional square lattice photonic crystals in order to study phenomena that would enable new frontiers in the applications of photonic crystals. Using group theory, symmetry analysis of the photonic crystals bands has been done. Particular attention was given to the search for the uncoupled B modes that cannot be excited by the external plane wave because they are symmetry forbidden. The existence of the uncoupled modes enabled to define new physics phenomena: uncoupled photonic band gaps. For the frequency ranges inside the uncoupled photonic band gaps, zero transmission is obtained. Therefore, there are two different types of photonic gaps in the photonic crystals: photonic band gaps and uncoupled photonic band gaps. The appearance of uncoupled photonic band gaps in photonic crystals could at least improve the application of the existing photonic materials and structures or even enable the usage of new ones for devices like waveguides, filters, and lasers. 相似文献