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101.
Wang Z 《Magnetic resonance imaging》2011,29(9):1288-1303
Constrained independent component analysis (CICA) eliminates the order ambiguity of standard ICA by incorporating prior information into the learning process to sort the components intrinsically. However, the original CICA (OCICA) and its variants depend on a learning rate, which is not easy to be tuned for various applications. To solve this problem, two learning-rate-free CICA algorithms were derived in this paper using the fixed-point learning concept. A complete stability analysis was provided for the proposed methods, which also made a correction to the stability analysis given to OCICA. Variations for adding constraints either to the components or to the associated time courses were derived too. Using synthetic data, the proposed methods yielded a better stability and a better source separation quality in terms of higher signal-to-noise-ratio and smaller performance index than OCICA. For the artificially generated brain activations, the new CICAs demonstrated a better sensitivity/specificity performance than standard univariate general linear model (GLM) and standard ICA. Original CICA showed a similar sensitivity/specificity gain but failed to converge for several times. Using functional magnetic resonance imaging (fMRI) data acquired with a well-characterized sensorimotor task, the proposed CICAs yielded better sensitivity than OCICA, standard ICA and GLM in all the target functional regions in terms of either higher t values or larger suprathreshold cluster extensions using the same significance threshold. In addition, they were more stable than OCICA and standard ICA for analyzing the sensorimotor fMRI data. 相似文献
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103.
Injectable hydrogels for nonsteroidal anti‐inflammatory drugs’ (NSAIDs) delivery to minimize the side effects of NSAIDs and achieve long‐term sustained release at the targeted site of synovial joint are attractive for osteoarthritis therapy, but how to improve its mechanical strength remains a challenge. In this work, a kind of 1D natural clay mineral material, attapulgite (ATP), is introduced to a classical cyclodextrin pseudopolyrotaxane (PPR) system to form a reinforced supramolecular hydrogel for sustained release of diclofenac sodium (DS) due to its rigid, rod‐like morphology, and unique structure, which has great potential in tissue regeneration, repair, and engineering. Investigation on the interior morphology and rheological property of the obtained hydrogel points out that the ATP distributed in PPR hydrogel plays a role similar to the “reinforcement in concrete” and exhibits a positive effect on improving the mechanical properties of PPR hydrogel by regulating their interior morphology from a randomly distributed style to the well‐ordered porous frame structure. The hybrid hydrogels demonstrate good shear‐thinning and thixotropic properties, excellent biocompability, and sustained release behavior both in vitro and in vivo. Furthermore, preliminary in vivo treatment in an acute inflammatory rat model reveals that the ATP hybrid hydrogels present sustained anti‐inflammatory effect. 相似文献
104.
105.
Ming Ze Wu Zhi Long Ma Jian Yun Shi Xiu Juan Shi 《Journal of Coordination Chemistry》2019,72(22-24):3495-3501
AbstractSolvothermal reaction of a multidentate ligand (tetrakis[4-(1-triazolyl)phenyl]-methane (ttpm)), with Cd(NO3)2 afforded a cationic Cd(II) coordination polymer {[Cd(ttpm)·DMSO]·2NO3}n. Single-crystal X-ray diffraction analyses showed that ttpm belonged to the tetragonal space group I41/a, and 1 was a 2-D (4,4) network. 1-D channels along the c direction exist in the 3D stacking map to accommodate the charge-balancing NO3? anions. N2 adsorption/desorption experiments showed the framework had a BET surface area of 11.36?m2·g?1. Compared with luminescence of ttpm, 1 showed red-shifted luminescence spectra with higher intensity from the more rigid arrangement of the π systems. 相似文献
106.
Chun-Sen Liu E. Carolina Sañudo Li-Fen Yan Ze Chang Jun-Jie Wang Tong-Liang Hu 《Transition Metal Chemistry》2009,34(1):51-60
Abstract To explore the influence of the anthracene ring skeleton, with a large conjugated π-system, on the structures and properties
of its complexes, two MnII complexes with anthracene-9-carboxylate ligand were synthesized and structurally characterized: {[Mn(L)2(H2O)2](H2O)}∞ (1) and [Mn2(L)4(phen)2(μ-H2O)](CH3OH) (2) (L = anthracene-9-carboxylate and phen = 1,10-phenanthroline). Complex (1) has a one-dimensional (1D) chain structure that is further assembled to form a two-dimensional (2D) sheet, and then an overall
three-dimensional (3D) network by π···π stacking and/or C–H···π interactions. Complex (2) makes a dinuclear structure by incorporating the chelating phen ligand, which is further interlinked via inter-molecular
π···π stacking and C–H···π interactions to generate a higher-dimensional supramolecular network along the different crystallographic
directions. The results reveal that the bulky anthracene ring skeleton in L, by virtue of intra- and/or inter-molecular π···π
stacking and C–H···π interactions, plays an important role in the formation of complexes (1) and (2). The magnetic properties of (1) and (2) were further investigated. As expected, the very long inter-metallic separations result in weak magnetic coupling, with
the corresponding coupling constant values of J = −10 cm−1 for (1) and J = −2.46 cm−1 for (2).
Graphical abstract The constructions of two new MnII complexes comprising 1D chain (1) and dinuclear subunit (2) structures have been successfully achieved by using a bulky anthracene-9-carboxylic acid (HL), together with incorporating
the chelating 1,10-phenanthroline as a co-ligand for (2). The result reveals that the bulky anthracene ring skeleton of HL, by virtue of intra- and/or inter-molecular π···π stacking
and C–H···π interactions, plays an important role in the formation of the supramolecular architectures of (1) and (2). Moreover, magnetic properties of the complexes have been investigated.
相似文献
107.
YIN Miao CHENG Ze SHEN Lei-Lei 《理论物理通讯》2008,50(9):661-663
We investigate the generation of entanglement of coherent excitonic states in coupled quantum dots placed in a cavity by meaning of the state preparation fidelity [Nature (London) 404 (2002) 256; Phys. Rev. A 65 (2002) 012107; J. Uffink, Phys. Rev. Lett. 88 (2002) 230406.] The effect of the number of excitons and the coherent intensity |α| of the cavity field on the entanglement is also studied. 相似文献
108.
Assume an additional congruent condition on the coefficients. We prove that the pair 5 of linear equations ∑j=1^5 αλjpj = bλ (λ= 1, 2) has solutions in primes pj satisfying pj 〈〈 (|b1|+|b2|+1) maxλ,j |αλj|^2318+ε. This improves the exponent 79680 without assuming the additional condition of the second author's. 相似文献
109.
Cheng Xin Kong De-Sheng Wang Ze Feng Yuan-Yuan Li Wen-Juan 《Journal of Solid State Electrochemistry》2017,21(5):1467-1475
Journal of Solid State Electrochemistry - The TiO2/solution interfacial junction is of scientific and practical importance in the field of photoelectrochemical water splitting. Illumination of this... 相似文献
110.