Analytische Bestimmung von Niob,Tantal, Phosphor,Chlorid und 2,2-Dipyridyl in einigen Komplexverbindungen

Zusammenfassung Die analytische Bestimmung der Metalle, des Dipyridyls und der Chloride in Oxo-chloro-alkoxo-dipyridyl-Komplexverbindungen des Niobs und Tantals wurde beschrieben. Eine modifizierte Methode der Dipyridylanalyse, wie auch der Chloridbestimmung in Gegenwart von Dipyridyl wurde angegeben. Die radiometrische Metallbestimmung in Extraktionsverbindungen von Niob und Tantal mit Di-oktyl-methylenbis-phosphonsäure wurde dargelegt.

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Summary The analytical determination of metals, dipyridyl and chlorides in oxochloro-alkoxo-dipyridyl complex compounds of niobium and tantalum is described. A modified procedure of the dipyridyl analysis and also of the determination of chloride in the presence of dipyridyl is given. The radiometric determination of the metals in extraction compounds of niobium and tantalum with di-octyl-methylene-bis-phosphonic acid is discussed.

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Résumé On décrit le dosage des métaux, du dipyridyle et des chlorures dans les composés complexes oxo, chloro, alcoxo, dipyridyle, du niobium et du tantale. On indique une méthode modifiée pour le dosage de dipyridyle ainsi que pour la détermination des chlorures, en présence de dipyridyle. On décrit le dosage radiométrique des métaux dans les produits d'extraction du niobium et du tantale par l'acide di-octyl-méthylène-bis-phosphonique.

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Vorgetragen beim Symposium für analytische Chemie in Graz, 29. September bis 1. Oktober 1965.     

Kinetic determination of ultramicro amounts of copper

A new catalytic reaction is proposed and a kinetic method developed for the determination of ultramicro amounts of Cu(II) on the basis of its catalytic activity in oxidation of the 2-thiosemicarbazone of sodium 1,2-naphthoquinone-4-sulphonate by hydrogen peroxide in the presence of ascorbic acid. Under optimal conditions the sensitivity of the method is 0.25 ng/ml. The relative error is 4.8-18.2% for the concentration range 5-0.8 ng/ml. Most foreign ions do not change the rate of the catalysed reaction. Co(2+) and I(-) catalyse the reaction, Ni(2+) extensively inhibits it, and in the presence of EDTA only the uncatalysed reaction takes place.     

Eine kennzeichnende Eigenschaft der Zykel der Galileischen Ebene

Ohne Zusammenfassung     

Effect of the size of experimental channels of the lead slowing-down spectrometer SVZ-100 (Institute for Nuclear Research, Moscow) on the moderation constant

Lead slowing-down (LSD) spectrometers have a low energy resolution (about 30%), but their luminosity is 10³ to 10⁴ times higher than that of time-of-flight (TOF) spectrometers. A high luminosity of LSD spectrometers makes it possible to use them to measure neutron cross section for samples of mass about several micrograms. These features specify a niche for the application of LSD spectrometers in measuring neutron cross sections for elements hardly available in macroscopic amounts—in particular, for actinides. A mathematical simulation of the parameters of SVZ-100 LSD spectrometer of the Institute for Nuclear Research (INR, Moscow) is performed in the present study on the basis of the MCNPX code. It is found that the moderation constant, which is the main parameter of LSD spectrometers, is highly sensitive to the size and shape of detecting volumes in calculations and, hence, to the real size of experimental channels of the LSD spectrometer.     

New relationship of displacement signal at quadrant photodiode: Control signal analysis and simulation of a laser tracker

New relationship of displacement signal using opposite sectors on a quadrant photodiode is derived. Standard and new displacement signals are analyzed in details. Through MATLAB^® laser tracking simulation models, based on common and suggested approaches, detailed analysis is performed, and it is shown that better results for the new relationship signal processing are obtained. Within new relationship of displacement signal, the sensitivity of the system to the displacement of the spot increases and, hence, provides better accuracy in positioning up to 30%.     

Some optical specificity of ultrathin crystalline films

The changes of optical properties under boundary presence in molecular crystal nanofilm were theoretically investigated in this work. The dispersion law and states of excitons as well as their space distribution along boundary direction have been determined using adjusted Green's function method and also by combined analytical and numerical calculations. On the basis of real and imaginary part of relative permittivity, both absorption and refraction indices were determined, and the influences of boundary parameters on occurrence of a very selective and strictly discrete absorption were analyzed.     

Omega- and Omega+ production in central Pb + Pb collisions at 40 and 158A GeV

Results are presented on Omega production in central Pb+Pb collisions at 40 and 158A GeV beam energy. For the first time in heavy ion reactions, rapidity distributions and total yields were measured for the sum Omega(-) + Omega(+) at 40A GeV and for Omega(-) and Omega(+) separately at 158A GeV. The yields are strongly underpredicted by the string-hadronic UrQMD model but agree better with predictions from hadron gas models.     

Nonordered quantum logic and its YES-NO representation

It is shown that an orthomodular lattice is an ortholattice in which aunique operation of bi-implication corresponds to the equality relation and that the ordering relation in the binary formulation of quantum logic as well as the operation of implication (conditional) in quantum logic are completely irrelevant for their axiomatization. The soundness and completeness theorems for the corresponding algebraic unified quantum logic are proved. A proper semantics, i.e., a representation of quantum logic, is given by means of a new YES-NO relation which might enable a proof of the finite model property and the decidability of quantum logic. A statistical YES-NO physical interpretation of the quantum logical propositions is provided.