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61.
Olaf Morgenstern Peter Richter Juha Rouvinen Pentti J. Mlknen Pirjo Vainiotalo Kari Hnninen Markku Ahlgrn Jouko Vepslinen 《Journal of heterocyclic chemistry》1991,28(4):1091-1097
The reaction of 3- and 4-aminoacetophenone with thiophosgene in a chloroform-water-calcium carbonate mixture at room temperature results in good yields of the related, known isothiocyanates. At first, however, we failed in all our attempts to produce 2-isothiocyanatoacetophenones with this reaction. Closer inspection of the reaction showed, that the product distribution depends upon the concentration of hydrogen ions pro-ducted and on the reaction time. When the reaction was followed with thin-layer chromatography, it was observed that the isothiocyanates formed first. In the further course of the reaction, they were converted to the 4-methylene-2-oxo-3,1-benzothiazines by the action of protons. The final products of the reaction were the 4-(3,1-benzothiazin-4-yl)-methylene-3,1-benzothiazines, formed from the monomer in a dimerization process. Depending upon the time the protons were removed from the reaction mixture, different products could be isolated. 相似文献
62.
T. Piippanen Jouko Jaatinen Aarni Pirjetä Jouni Tummavuori 《Analytical and bioanalytical chemistry》1997,358(7-8):771-774
A new approach for the determination of cobalt, copper, iron, nickel and zinc in cemented tungsten carbides with cobalt as a binder by flame atomic absorption spectrophotometry (FAAS) is reported. Real samples were dissolved in phosphoric, hydrochloric and nitric acid. PTFE bomb or alternatively small amounts of HF were used for the enhancement of the recovery of the elements investigated. Synthetic samples were used for interference studies. Multiple linear regression was applied for the control of matrix effects and it proved to be very effective in the search for interfering elements. Using simple acid based standards, all investigated elements could be determined sequentially in a complex matrix by using an appropriate method of calculation. The method described has been succesfully applied to real type commercial samples. Results were compared with those obtained by inductively coupled plasma atomic emission spectrometry (ICP-AES) and X-ray fluorescence spectrometry (XRF), being in good agreement with each other and having relative standard deviations better than 5%. 相似文献
63.
A Comparative Study of Pyrolysis Liquids by Slow Pyrolysis of Industrial Hemp Leaves,Hurds and Roots
Ayobami Salami Jorma Heikkinen Laura Tomppo Marko Hyttinen Timo Keklinen Janne Jnis Jouko Vepslinen Reijo Lappalainen 《Molecules (Basel, Switzerland)》2021,26(11)
This study assessed the pyrolysis liquids obtained by slow pyrolysis of industrial hemp leaves, hurds, and roots. The liquids recovered between a pyrolysis temperature of 275–350 °C, at two condensation temperatures 130 °C and 70 °C, were analyzed. Aqueous and bio-oil pyrolysis liquids were produced and analyzed by proton nuclear magnetic resonance (NMR), gas chromatography–mass spectrometry (GC-MS), and atmospheric pressure photoionization Fourier transform ion cyclotron resonance mass spectrometry (APPI FT-ICR MS). NMR revealed quantitative concentrations of the most abundant compounds in the aqueous fractions and compound groups in the oily fractions. In the aqueous fractions, the concentration range of acetic acid was 50–241 gL−1, methanol 2–30 gL−1, propanoic acid 5–20 gL−1, and 1-hydroxybutan-2-one 2 gL−1. GC-MS was used to compare the compositions of the volatile compounds and APPI FT-ICR MS was utilized to determine the most abundant higher molecular weight compounds. The different obtained pyrolysis liquids (aqueous and oily) had various volatile and nonvolatile compounds such as acetic acid, 2,6-dimethoxyphenol, 2-methoxyphenol, and cannabidiol. This study provides a detailed understanding of the chemical composition of pyrolysis liquids from different parts of the industrial hemp plant and assesses their possible economic potential. 相似文献
64.
Jouko Mickelsson 《Communications in Mathematical Physics》1990,127(2):285-294
We show that the anomalous finite gauge transformations can be realized as linear operators acting on sections of the bundle of fermionic Fock spaces parametrized by vector potentials, and more generally, by splittings of the fermionic one-particle space into a pair of complementary subspaces. On the Lie algebra level we show that the construction leads to the standard formula for the relevant commutator anomalies. 相似文献
65.
66.
The high sensitivity of differential pulse anodic stripping voltammetry (d.p.a.s.v.) is based on discrimination against the charging current by using short current-sampling periods near the end of the applied pulses. In this paper, the capacitive current is eliminated by using a symmetric double-step waveform superimposed on the voltage ramp. The areas under the adjacent current peaks are subtracted from each other which effectively cancels the contribution of the double-layer charging current but preserves the changes in the faradaic current. By using a mercury thin-film electrode the base line is reasonably flat down to nanomolar levels of Cd, Cu and Pb with a deposition time of 3–5 min. Compared with d.p.a.s.v., the proposed method has the advantages of a higher scan rate and simple electronic circuitry. 相似文献
67.
Gábor Benk? Jani Kallioinen Jouko E I Korppi-Tommola Arkady P Yartsev Villy Sundstr?m 《Journal of the American Chemical Society》2002,124(3):489-493
Electron injection from the transition metal complex Ru(dcbpy)(2)(NCS)(2) (dcbpy = 4,4'-dicarboxy-2,2'-bipyridine) into a titanium dioxide nanocrystalline film occurs on the femto- and picosecond time scales. Here we show that the dominating part of the electron transfer proceeds extremely rapidly from the initially populated, vibronically nonthermalized, singlet excited state, prior to electronic and nuclear relaxation of the molecule. The results are especially relevant to the understanding and design of molecular-based photovoltaic devices and artificial photosynthetic assemblies. 相似文献
68.
Kumpulainen H Järvinen T Saari R Lehtonen M Vepsäläinen J 《The Journal of organic chemistry》2005,70(22):9056-9058
[reaction: see text] A versatile, efficient, and simple method for the preparation of various 1-chloroethyl phosphates and phosphoramidates is described. The protected chlorophosphates or phosphoramidates are synthesized to the vinyl derivative under mild conditions, followed by conversion to the chloroethylidene phosphate or phosphoramidate by dry HCl gas, resulting in good to excellent yields. 1-Chloroethyl phosphates and phosphoramidates are excellent building blocks for the synthesis of novel ethylidene-linked phosphate prodrugs. 相似文献
69.
Kaarina?Kek?l?inenEmail author Mirja?Illikainen Jouko?Niinim?ki 《Cellulose (London, England)》2012,19(3):879-889
The modification of bleached never-dried cellulose fibers was studied under controlled compression and shearing conditions.
Fibers were further treated in a high-intensity mixing device in low-consistency to determine if the fiber structure was weakened
in the in-pad attrition. The difference between the development of the softwood and hardwood fibers was examined. The fiber
properties were analyzed using a fiber morphology analyzer, fractional fiber analysis and an electron microscope. The results
indicate that the shearing under the controlled compression at high consistency modified the softwood and hardwood fibers
already at low-energy consumptions. The fiber length and width decreased, and the formation of curls and kinks was pronounced.
However, the intensive mixing after in-pad attrition revealed that the fiber structure was not weakened under compression
and shear forces; conversely, the fiber cell wall was more resistant for the intensive mixing. When comparing the results
for hardwood and softwood fibers, the softwood fibers were more modified during in-pad attrition, whereas the fiber wall strengthening
was more significant in the hardwood fibers. 相似文献
70.
The thermal properties of two conventional polyester-based toners and a chemically prepared styrene/acrylate toner with different thermal histories were studied by scanning probe microscopy (SPM) and differential scanning calorimetry (DSC). The thermal transition temperatures detected by SPM agreed with the results of the DSC measurements. The validity of SPM for detecting thermal transitions was further confirmed by studying two amorphous reference polymers with different glass transition points (Tg) and three crystalline reference polymers with different melting points (Tm). When the toner sample was heated by the SPM probe above the glass transition temperature of the toner powder (Tprobe > Tg), changes occurred in the surface topography and roughness causing different levels of local sintering of the particles. A set of roughness parameters calculated from the SPM image data were used to quantify the most essential features of toner surfaces. Environmental scanning electron microscopy (ESEM) was used to study the penetration depth of heat dissipated by the SPM probe. The probe-annealing was compared with oven-annealing in order to establish the effect of thermal history on the thermal properties of the materials. 相似文献