Analysis and design of photobioreactors for microalgae production I: method and parameters for radiation field simulation

Having capabilities for the simulation of the radiation field in suspensions of microalgae constitutes a great asset for the analysis, optimization and scaling-up of photobioreactors. In this study, a combined experimental and computational procedure is presented, specifically devised for the assessment of the coefficients of absorption and scattering, needed for the simulation of such fields. The experimental procedure consists in measuring the radiant energy transmitted through samples of suspensions of microalgae of different biomass concentrations, as well as the forward and backward scattered light. At a microscopic level, suspensions of microalgae are complex heterogeneous media and due to this complexity, in this study they are modeled as a pseudocontinuum, with centers of absorption and scattering randomly distributed throughout its volume. This model was tested on suspensions of two algal species of dissimilar cell shapes: Chlorella sp. and Scenedesmus quadricauda. The Monte Carlo simulation algorithm developed in this study, when used as a supporting subroutine of a main optimization program based on a genetic algorithm, permits the assessment of the physical parameters of the radiation field model. The Monte Carlo algorithm simulates the experiments, reproducing the events that photons can undergo while they propagate through culture samples or at its physical boundaries.     

<Emphasis Type="Italic">p</Emphasis>-groups having few almost-rational irreducible characters

We prove that a 2-group has exactly five rational irreducible characters if and only if it is dihedral, semidihedral or generalized quaternion. For an arbitrary prime p, we say that an irreducible character χ of a p-group G is “almost rational” if ℚ(χ) is contained in the cyclotomic field ℚ _p , and we write ar(G) to denote the number of almost-rational irreducible characters of G. For noncyclic p-groups, the two smallest possible values for ar(G) are p ² and p ² + p − 1, and we study p-groups G for which ar(G) is one of these two numbers. If ar(G) = p ² + p − 1, we say that G is “exceptional”. We show that for exceptional groups, |G: G′| = p ², and so the assertion about 2-groups with which we began follows from this. We show also that for each prime p, there are exceptional p-groups of arbitrarily large order, and for p ≥ 5, there is a pro-p-group with the property that all of its finite homomorphic images of order at least p ³ are exceptional.     

A logic‐mathematical point of view of the truth: Reality,perception, and language

In this article, the authors propose a theory of the truth value of propositions from a logic‐mathematical point of view. The work that the authors present is an attempt to address this question from an epistemological, linguistic, and logical‐mathematical point of view. What is it to exist and how do we define existence? The main objective of this work is an approach to the first of these questions. We leave a more thorough treatment of the problem of existence for future works. © 2014 Wiley Periodicals, Inc. Complexity 20: 58–67, 2015     

Micellisation of triblock copolymers of ethylene oxide and 1,2-butylene oxide: effect of B-block length

We have used pyrene fluorescence spectroscopy and isothermal titration calorimetry (ITC) to investigate the effect of hydrophobic-block length on values of the critical micelle concentration (cmc) for aqueous solutions of triblock poly(butylene oxide)-poly(ethylene oxide)-poly(butylene oxide) block copolymers (B(n)E(m)B(n), where m and n denote the respective block lengths) with hydrophobic block lengths in the range n=12-21. Combined with results from previous work on B(n)E(m)B(n) copolymers with shorter B blocks, plots of log(10)(cmc) (cmc in molar units and reduced to a common E-block length) against total number of B units (n(t)=n for diblock or n(t)=2n for triblock copolymers) display transitions in the slopes of the two plots, which indicate changes in the micellisation equilibrium. These occur at values of n(t)which can be assigned to the onset and completion of collapse of the hydrophobic B blocks, an effect not previously observed for reverse triblock copolymers. The results are compared with related data for diblock E(m)B(n) copolymers.     

One-dimensional magnetic nanowires obtained by protein fibril biotemplating

Magnetic nanowires were obtained through the in situ synthesis of magnetic material by Fe-controlled nanoprecipitation in the presence of two different protein (human serum albumin (HSA) and lysozyme (Lys)) fibrils as biotemplating agents. The structural characteristics of the biotemplates were transferred to the hybrid magnetic wires. They exhibited excellent magnetic properties as a consequence of the 1D assembly and fusion of magnetite nanoparticles as ascertained by SQUID magnetometry. Prompted by these findings, we also checked their potential applicability as MRI contrast agents. The magnetic wires exhibited large r(2)* relaxivities and sufficient contrast resolution even in the presence of an extremely small amount of Fe in the magnetic hybrids, which would potentially enable their use as T(2) contrast imaging agents.     

Could marine aerosol contribute to deteriorate building materials from interior areas of lighthouses? An answer from the analytical chemistry point of view

In this work, a multianalytical methodology based on a combination of spectroscopic techniques such as Raman spectroscopy and micro energy dispersive X‐ray fluorescence spectroscopy, and soluble salt analysis by means of ion chromatography followed by a correlation analysis of these data was applied, in order to identify the nature of the deterioration compounds present in different building materials located on inner rooms from the ground floor of the Igueldo lighthouse (San Sebastian, Basque Country, North of Spain), and in order to prove if marine aerosol could contribute to cause deterioration processes in this kind of materials. The main deterioration compounds identified were sulfate and nitrate salts. Taking into consideration the positioning of some materials, a gypsum plaster covering them could be the sulfate source responsible of the crystallisation process of a wide variety of sulfate salts. Nevertheless, in some areas were no gypsum plaster remains are present, ammonium sulfate crystallisations were identified. The presence of this kind of sulfate could suggest a possible sulfate input coming from the migration of ammonium sulfate (among other sulfate salts) carried on marine aerosol, which can be deposited on the facade of the lighthouse and migrate to its inner areas. The possible source of nitrates that could cause the crystallisation of a wide variety of nitrate salts identified in this work could be the infiltration of ammonium nitrates coming from seagull droppings from outdoor to indoor areas. Copyright © 2013 John Wiley & Sons, Ltd.     

Myth,language, and complex ideologies

Ideologies use for their conservation and propagation persuasive methods of communication: rhetoric. Rhetoric is analyzed from the semiotic and logical‐mathematical points of view. The following hypotheses are established: (1) language L is a self‐explanatory system, mediated by a successive series of systems of cultural conventions, (2) connotative significances of an ideological advertising rhetoric must be known, and (3) the notion of ideological information is a neutral notion that does not imply the valuation of ideology or its conditions of veracity or falsification. Rhetorical figures like metonymy, metaphor, parable analogy, and allegory are defined as relations. Metaphor and parable are order relations. Operations of metonymic and metaphoric substitution are defined and several theorems derived from these operations have been deduced. © 2014 Wiley Periodicals, Inc. Complexity 20: 63–81, 2014     

Manipulating Charge-Transfer States in BODIPYs: A Model Strategy to Rapidly Develop Photodynamic Theragnostic Agents

On the basis of a family of BINOL (1,1′-bi-2-naphthol)-based O-BODIPY (dioxyboron dipyrromethene) dyes, it is demonstrated that chemical manipulation of the chromophoric push–pull character, by playing with the electron-donating capability of the BINOL moiety (BINOL versus 3,3'-dibromoBINOL) and with the electron-acceptor ability of the BODIPY core (alkyl substitution degree), is a workable strategy to finely balance fluorescence (singlet-state emitting action) versus the capability to photogenerate cytotoxic reactive oxygen species (triplet-state photosensitizing action). It is also shown that the promotion of a suitable charge-transfer character in the involved chromophore upon excitation enhances the probability of an intersystem crossing phenomenon, which is required to populate the triple state enabling singlet oxygen production. The reported strategy opens up new perspectives for rapid development of smarter agents for photodynamic theragnosis, including heavy-atom-free agents, from a selected organic fluorophore precursor.     

Second order mobility analysis of mechanisms using closure equations

This paper presents a general method for the second order local mobility analysis of kinematical chains using closure equations. As it is known, one can obtain the mobility of a mechanism as the nullspace of its Jacobian Matrix. But in the event of a singular configuration, not all of the linear combinations of these vectors represent finite movements. This phenomena leads to branching, kinematotropy and other kinds of particular behavior of mechanisms. The exposed algorithm allows one to obtain the restrictions that appear in these cases, thus providing a better understanding of the behavior of the mechanism. The solution of these restrictions gives information about not only the real number of second order finite motions, but also the vectors defining the branches of finite movements, if any. Although the algorithm itself is applicable with other kind of methods for the definition of the Jacobian Matrix, the use of closure equations leads to simplicity. One of the advantages of the presented method is that it takes advantage of the work performed to solve the velocity and acceleration analysis. This reduces the amount of operations needed to perform the analysis The paper presents some examples of application, including complex mechanisms in singular configurations and a kinematotropic mechanism.     

Kinetic Model of Photoautotrophic Growth of Chlorella sp. Microalga,Isolated from the Setúbal Lagoon

In this work, a kinetic expression relating light availability in the culture medium with the rate of microalgal growth is obtained. This expression, which is valid for low illumination conditions, was derived from the reactions that take part in the light‐dependent stage of photosynthesis. The kinetic expression obtained is a function of the biomass concentration in the culture, as well as of the local volumetric rate of absorption of photons, and only includes two adjustable parameters. To determine the value of these parameters and to test the validity of the hypotheses made, autotrophic cultures of the Chlorella sp. strain were carried out in a modified BBM medium at three CO₂ concentrations in the gas stream, namely 0.034%, 0.34% and 3.4%. Moreover, the local volumetric rate of photon absorption was predicted based on a physical model of the interaction of the radiant energy with the suspended biomass, together with a Monte Carlo simulation algorithm. The proposed intrinsic expression of the biomass growth rate, together with the Monte Carlo radiation field simulator, are key to scale up photobioreactors when operating under low irradiation conditions, independently of the configuration of the reactor and of its light source.