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11.
ABSTRACT The theory of calculus of variations is a mathematical tool which is widely used in different scientific areas in particular in physics and chemistry. This theory is strongly related with optimisation. In fact the former seeks to optimise an integral related with some physical magnitude over some space to an extremum by varying a function of the coordinates. On the other hand, reaction paths and potential energy surfaces, in particular their stationary points, are the basis of many chemical theories, in particular reactions rate theories. We present a review where it is gathered together the variational nature of many types of reaction paths: steepest descent, Newton trajectories, artificial force induced reaction (AFIR) paths, gradient extremals, and gentlest ascent dynamics (GAD) curves. The variational basis permits to select the best optimisation technique in order to locate important theoretical objects on a potential energy surface. 相似文献
12.
A critical review of known results about the permanence conditions for the null character of the solutions to the (vacuum) Maxwell equations, is presented. Concomitants of the electromagnetic field and the metric tensor are constructed, which give the principal directions of the field in covariant form. The known permanence conditions are generalized in order to includeall the (local) null fields; the above concomitants allow these conditions to be explicitly formulated in terms of the electromagnetic field.Supported in part by Conselleria de Cultura, Educació i Ciència de la Generalitat Valenciana. 相似文献
13.
We consider static spherically symmetric Lovelock black holes and generalize the dimensionally continued black holes in such a way that they asymptotically for large $r$ go over to the d-dimensional Schwarzschild black hole in dS/AdS spacetime. This means that the master algebraic polynomial is not degenerate but instead its derivative is degenerate. This family of solutions contains an interesting class of pure Lovelock black holes which are the $N$ th order Lovelock $\Lambda $ -vacuum solutions having the remarkable property that their thermodynamical parameters have the universal character in terms of the event horizon radius. This is in fact a characterizing property of pure Lovelock theories. We also demonstrate the universality of the asymptotic Einstein limit for the Lovelock black holes in general. 相似文献
14.
Imaging the Magnetic Reversal of Isolated and Organized Molecular‐Based Nanoparticles using Magnetic Force Microscopy 下载免费PDF全文
Elena Pinilla‐Cienfuegos Samuel Mañas‐Valero Josep Canet‐Ferrer Laure Catala Talal Mallah Alicia Forment‐Aliaga Eugenio Coronado 《Particle & Particle Systems Characterization》2015,32(6):693-700
In the race towards miniaturization in nanoelectronics, magnetic nanoparticles (MNPs) have emerged as potential candidates for their integration in ultrahigh‐density recording media. Molecular‐based materials open the possibility to design new tailor‐made MNPs with variable composition and sizes, which benefit from the intrinsic properties of these materials. Before their implementation in real devices is reached, a precise organization on surfaces and a reliable characterization and manipulation of their individual magnetic behavior are required. In this paper, it is demonstrated how molecular‐based MNPs are accurately organized on surfaces and how the magnetic properties of the individual MNPs are detected and tuned by means of low‐temperature magnetic force microscopy (LT‐MFM) with variable magnetic field. The magnetization reversal on isolated and organized MNPs is investigated; in addition, the temperature dependence of their magnetic response is evaluated. 相似文献
15.
Design and performance of BOREAS,the beamline for resonant X‐ray absorption and scattering experiments at the ALBA synchrotron light source 下载免费PDF全文
Alessandro Barla Josep Nicolás Daniele Cocco Secundino Manuel Valvidares Javier Herrero-Martín Pierluigi Gargiani Jairo Moldes Claude Ruget Eric Pellegrin Salvador Ferrer 《Journal of synchrotron radiation》2016,23(6):1507-1517
The optical design of the BOREAS beamline operating at the ALBA synchrotron radiation facility is described. BOREAS is dedicated to resonant X‐ray absorption and scattering experiments using soft X‐rays, in an unusually extended photon energy range from 80 to above 4000 eV, and with full polarization control. Its optical scheme includes a fixed‐included‐angle, variable‐line‐spacing grating monochromator and a pair of refocusing mirrors, equipped with benders, in a Kirkpatrick–Baez arrangement. It is equipped with two end‐stations, one for X‐ray magnetic circular dichroism and the other for resonant magnetic scattering. The commissioning results show that the expected beamline performance is achieved both in terms of energy resolution and of photon flux at the sample position. 相似文献
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Camarero J Sort J Hoffmann A García-Martín JM Dieny B Miranda R Nogués J 《Physical review letters》2005,95(5):057204
The magnetization reversal in exchange-biased ferromagnetic-antiferromagnetic (FM-AFM) bilayers is investigated. Different reversal pathways on each branch of the hysteresis loop, i.e., asymmetry, are obtained both experimentally and theoretically when the magnetic field is applied at certain angles from the anisotropy direction. The range of angles and the magnitude of this asymmetry are determined by the ratio between the FM anisotropy and the interfacial FM-AFM exchange anisotropy. The occurrence of asymmetry is linked with the appearance of irreversibility, i.e., finite coercivity, as well as with the maximum of exchange bias, increasing for larger anisotropy ratios. Our results indicate that asymmetric hysteresis loops are intrinsic to exchange-biased systems and the competition between anisotropies determines the asymmetric behavior of the magnetization reversal. 相似文献
19.
In this work we have performed a detailed analysis, using signal processing tools, to study time series of data (temperature proxy) extracted from the GRIP ice-core records and we relate it with the evolution of atmospheric CO2 within the last glacial period. Our method is based in considering the warm periods known as Dansgaard–Oeschger (D/O) events and posterior returns to the cold stage as a climatic cycle. After the warming phase, D/O events relax to the initial cold state in three different ways, what gives rise to three classes of cycles. Also, the Younger/Dryas–Bolling/Allerod (Y/D–B/A) cycle corresponds to one of the classes obtained. We have found that all cycles start with identical warming phases which seem completely unrelated to variations in CO2 concentration. We discuss on the consequences for global climatology of such steady pattern of cycles. 相似文献
20.
Option pricing and perfect hedging on correlated stocks 总被引:2,自引:0,他引:2
We develop a theory for option pricing with perfect hedging in an inefficient market model where the underlying price variations are autocorrelated over a time τ0. This is accomplished by assuming that the underlying noise in the system is derived by an Ornstein-Uhlenbeck, rather than from a Wiener process. With a modified portfolio consisting in calls, secondary calls and bonds we achieve a riskless strategy which results in a closed and exact expression for the European call price which is always lower than Black-Scholes price. We obtain the same price and a modified delta hedging if we start from an effective one-dimensional market model. We compare these strategies and study the sensitivity of the call price to several parameters where the correlation effects are also observed. 相似文献