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991.
One-pot catalytic synthesis of butyrolactones from alkynols under mild conditions is described here. The methodology involves the use of the K2[Ni(CN)4]/NaBH4 system in presence of KCN and water. According to the experimental evidences, a possible mechanism pathway is suggested, which involves the nickel-catalyzed reductive cyanation of alkynol, followed by nitrile hydration, reduction of double bond and lactonization. 相似文献
992.
We extend the Gustavsson–Peetre method to the context of N ‐tuples of Banach spaces. We give estimates for the norm of the interpolated operator. The method is applied to tuples of weighted L p ‐spaces and to tuples of Orlicz spaces identifying the outcoming spaces in both cases. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
993.
This work defines a new class of hybrid systems called state-based switched (SBS) systems that have numerous important engineering applications. The characterizing feature of these systems is that the discrete-event dynamics are associated with the continuous-time state making a specific function be equal to zero. The choice of this function is application specific and for the closed-loop SBS systems defined in this paper it is related to the execution of a desired set of tasks from a pre-specified mission plan. For this broad class of SBS systems, the paper presents a unified analysis and controller synthesis methodology based on Lyapunov theory. Depending on the details of the mission plan, the closed-loop hybrid system will be divided into two subclasses: sequential and non-sequential. The controller design procedure for both subclasses consists of the same two steps: finding a control law and finding a stabilizing switching rule. For static state and output feedback of sequential hybrid systems, the paper proposes a new hybrid sequential sliding-mode controller. It is proven that the control mission can be accomplished for sequential hybrid systems under static state and output feedback using this new controller. A similar framework is investigated for the more complex class of nonsequential hybrid systems and a systematic procedure for designing the switching rule is presented for some specific instances of these systems. 相似文献
994.
Arvids Stashans Cesar Zambrano Alfredo Sanchez Luis Miguel Procel 《International journal of quantum chemistry》2002,87(3):145-151
We investigate the structural and electronic properties of pure and Zr‐doped PbTiO3 crystals. The nature of atomic relaxation around the Zr impurity is studied through quantum‐chemical simulations based on the Hartree–Fock theory and a periodic large unit cell model adopted within the so‐called intermediate neglect of differential overlap approximation. The most stable defect configurations are predicted for different impurity concentrations. The results obtained are compared with those from other theoretical studies and a number of experimental measurements carried out on this technologically important perovskite‐type crystal. © 2001 John Wiley & Sons, Inc. Int J Quantum Chem, 2001 相似文献
995.
Among the most frequent protein binding sites served by Mg(II), we identify those which have higher affinity towards Al(III). We also estimate the free energies of metal exchange for all these binding sites taking into account solvent effects explicitly. The obtained results show that thermodynamically favored Mg(II)/Al(III) exchange reactions take place at a number of these metal binding sites, which could possibly be related to some dysfunctions of Mg(II)-dependent biological processes. Additionally, they shed light on the molecular basis of the toxicity of Al(III) in living organisms. 相似文献
996.
A generalization of the Poisson–Boltzmann equation solution has been obtained as a function of a single parameter that is only temperature and concentration dependent. This new solution improves the analytical expressions for the surface charge density/surface potential relationship stated by other authors and shows excellent agreement with the exact numerical values obtained by Loeb, Overbeek and Wiersema [The Electrical Double Layer Around a Spherical Colloidal Particle, MIT Press, Cambridge, MA, 1961]. 相似文献
997.
F. Raiola B. Burchard Zs. Fülöp Gy. Gyürky S. Zeng J. Cruz A. Di Leva B. Limata M. Fonseca H. Luis M. Aliotta H. W. Becker C. Broggini A. D'Onofrio L. Gialanella G. Imbriani A. P. Jesus M. Junker J. P. Ribeiro V. Roca C. Rolfs M. Romano E. Somorjai F. Strieder F. Terrasi 《The European Physical Journal A - Hadrons and Nuclei》2006,27(1):79-82
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We study the relationship between data compression and prediction in single-layer neural networks of limited complexity. Quantifying the intuitive notion of Occam's razor using Rissanen's minimum complexity framework, we investigate the model-selection criterion advocated by this principle. While we find that the criterion works well for large sample sizes (as it must for consistency), the behavior for finite sample sizes is rather complex, depending intricately on the relationship between the complexity of the hypothesis space and the target space. We also show that the limited networks studied perform efficient data compression, even in the error full regime. 相似文献