全文获取类型
收费全文 | 6087篇 |
免费 | 267篇 |
国内免费 | 24篇 |
专业分类
化学 | 3980篇 |
晶体学 | 35篇 |
力学 | 153篇 |
数学 | 1129篇 |
物理学 | 1081篇 |
出版年
2023年 | 51篇 |
2022年 | 103篇 |
2021年 | 118篇 |
2020年 | 104篇 |
2019年 | 127篇 |
2018年 | 108篇 |
2017年 | 121篇 |
2016年 | 246篇 |
2015年 | 172篇 |
2014年 | 236篇 |
2013年 | 399篇 |
2012年 | 451篇 |
2011年 | 497篇 |
2010年 | 285篇 |
2009年 | 299篇 |
2008年 | 384篇 |
2007年 | 348篇 |
2006年 | 298篇 |
2005年 | 300篇 |
2004年 | 253篇 |
2003年 | 203篇 |
2002年 | 176篇 |
2001年 | 61篇 |
2000年 | 66篇 |
1999年 | 50篇 |
1998年 | 53篇 |
1997年 | 52篇 |
1996年 | 51篇 |
1995年 | 27篇 |
1994年 | 37篇 |
1993年 | 40篇 |
1992年 | 39篇 |
1991年 | 31篇 |
1990年 | 38篇 |
1989年 | 30篇 |
1988年 | 33篇 |
1987年 | 24篇 |
1986年 | 30篇 |
1985年 | 34篇 |
1984年 | 49篇 |
1983年 | 24篇 |
1982年 | 24篇 |
1981年 | 30篇 |
1980年 | 27篇 |
1979年 | 24篇 |
1978年 | 25篇 |
1977年 | 28篇 |
1976年 | 15篇 |
1975年 | 18篇 |
1974年 | 20篇 |
排序方式: 共有6378条查询结果,搜索用时 15 毫秒
991.
This paper presents an application of the recently proposed symmetry operation measures to the determination of the effective symmetry point group of coordination polyhedra in inorganic solids. Several structure types based on octahedra are found to present distinct distortion patterns each, not strictly attached to the crystallographic site symmetry. These include the (NH4)2[CuCl4], CdI2 (brucite), FeS2 (pyrite), TiO2 (rutile), CaCl2, GdFeO3, PbTiO3,LiNbO3, BiI3, CrCl3, Al2O3, and NiWO4 structures. It is shown that a similar analysis can be applied to the Bailar and tetragonal Jahn-Teller distortions of molecular transition metal complexes, as well as to solids based on tetrahedra, such as the ZnCl2, FeS, BeCl2, SiS2, and KFeS2 structure types. 相似文献
992.
Coronado E Galán-Mascarós JR Martí-Gastaldo C Ribera A Palacios E Castro M Burriel R 《Inorganic chemistry》2008,47(19):9103-9110
Layered double hydroxides containing paramagnetic Ni (II) and diamagnetic/paramagnetic Al (III)/Fe (III) ions have been prepared and characterized. Ni 2Al(OH) 6(NO 3). nH 2O ( 1), Ni 2Fe(OH) 6(NO 3). nH 2O ( 2), Ni 2Fe(OH) 6(C 6H 8O 4) 0.5. nH 2O ( 3), and Ni 2Fe(OH) 6(C 10H 16O 4) 0.5. nH 2O ( 4) were prepared by coprecipitation at controlled pH as polycrystalline materials with the typical brucite-like structure, with alternating layers of hydroxide and the corresponding anions, which determine the interlayer separation. Magnetic studies show the appearance of spontaneous magnetization between 2 and 15 K for these compounds. Interestingly, the onset temperature for spontaneous magnetization follows a direct relationship with interlayer separation, since this is the only magnetic difference between compounds 2, 3, and 4. Magnetic and calorimetric data indicate that long-range magnetic ordering is not occurring in any of these materials, but rather a freezing of the magnetic system in 3D due to the magnetic disorder and competing intra- and interlayer interactions. Thus, these hydrotalcite-like magnetic materials can be regarded as spin glasses. 相似文献
993.
Santacruz-Juárez E Cruz-Huerta J Hernández-Ahuactzi IF Reyes-Martínez R Tlahuext H Morales-Rojas H Höpfl H 《Inorganic chemistry》2008,47(21):9804-9812
The potassium bis-dithiocarbamate (bis-dtc) salts of 1,3-bis(benzylaminomethyl)benzene (1,3-Bn-ambdtc), 1,3-bis(iso-butylaminomethyl)benzene (1,3-(i)Bu-ambdtc), 1,4-bis(benzylaminomethyl)benzene (1,4-Bn-ambdtc), and 1,4-bis(iso-butylaminomethyl)benzene (1,4-(i)Bu-ambdtc) were reacted with three different diorganotin dichlorides (R2SnCl2 with R = Me, (n)Bu, and Ph) in 1:1 stoichiometric ratios to give the corresponding diorganotin bis-dithiocarbamates. Additionally, the dimethyltin bis-dithiocarbamate of 1,1'-bis(benzylaminomethyl)ferrocene (1,1'-Bn-amfdtc) was prepared. The resulting complexes have been characterized as far as possible by elemental analysis, FAB(+) mass spectrometry, IR and NMR ((1)H, (13)C, and (119)Sn) spectroscopy, and single-crystal X-ray diffraction, showing that the tin complexes are dinuclear 24- and 26-membered macrocyclic species of composition [{R2Sn(bis-dtc)}2]. As shown by (119)Sn NMR spectroscopy, the tin centers are hexa-coordinated in all cases; however, two different coordination environments are possible, as detected by single-crystal X-ray diffraction. In the dimethyltin derivatives of 1,3-Bn-ambdtc, 1,3-(i)Bu-ambdtc, 1,4-Bn-ambdtc, and 1,1'-Bn-amfdtc and the di-n-butyltin derivative of 1,3-(i)Bu-ambdtc, the metal atoms are embedded in skewed-trapezoidal-bipyramidal coordination polyhedra with asymmetrically coordinating trans-oriented dtc groups. In contrast, in the diphenyltin derivative 1,3-(i)Bu-ambdtc, the metal centers have distorted octahedral coordination with symmetrically coordinating cis-oriented dtc functions. Thus, for the complexes derived from 1,3-Bn/(i)Bu-ambdtc, two different macrocyclic structures were observed. In the dimethyl- and di-n-butyltin derivatives, the bridging bis-dtc ligands adopt U-shaped conformations, while in the case of the diphenyltin derivative, the conformation is L-shaped. Furthermore, two different macrocyclic ring conformations can occur, which differ in the spatial orientation of the substituents attached to the nitrogen atoms (Bn or (i)Bu). The dimethyltin derivatives of 1,4-Bn-ambdtc and 1,1'-Bn-amfdtc have cavities, in which aromatic rings are accommodated in the solid state. 相似文献
994.
995.
A hierarchical transition state search algorithm is developed and its implementation in the density functional theory program deMon2k is described. This search algorithm combines the double ended saddle interpolation method with local uphill trust region optimization. A new formalism for the incorporation of the distance constrain in the saddle interpolation method is derived. The similarities between the constrained optimizations in the local trust region method and the saddle interpolation are highlighted. The saddle interpolation and local uphill trust region optimizations are validated on a test set of 28 representative reactions. The hierarchical transition state search algorithm is applied to an intramolecular Diels-Alder reaction with several internal rotors, which makes automatic transition state search rather challenging. The obtained reaction mechanism is discussed in the context of the experimentally observed product distribution. 相似文献
996.
Density functional theory (DFT) of freezing is used to study the isotropic–nematic, isotropic–smectic A and nematic–smectic A phase transitions in a system of large, semi-flexible conjugated oligomers parameterised within Gay–Berne (GB) potential. The pair correlation functions of the isotropic fluid, used as structural inputs in the DFT, are calculated by solving the Percus–Yevick integral equation theory. Large number of spherical harmonic coefficients of each orientation-dependent functions has been considered to ensure the numerical accuracy at different densities and temperatures for the system of these model GB ellipsoids having large aspect ratio (length-to-breadth ratio). We found that the system of GB ellipsoids parameterised for conjugated oligomers shows stable isotropic, nematic and smectic A phases. At low temperatures, on increasing the density, isotropic fluid makes a direct transition to smectic A phase. Nematic phase get stabilised in between the isotropic and smectic A phases on increasing the temperature. Using the transition parameter obtained through the DFT, we have plotted the temperature–density and pressure–temperature phase diagrams which are found to be qualitatively similar to the one obtained in simulations for the systems with low aspect ratio GB particles. 相似文献
997.
998.
A Computational and Experimental Approach Linking Disorder,High‐Pressure Behavior,and Mechanical Properties in UiO Frameworks
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Claire L. Hobday Ross J. Marshall Colin F. Murphie Jorge Sotelo Tom Richards Dr. David R. Allan Prof. Tina Düren Dr. François‐Xavier Coudert Dr. Ross S. Forgan Dr. Carole A. Morrison Dr. Stephen A. Moggach Dr. Thomas D. Bennett 《Angewandte Chemie (International ed. in English)》2016,55(7):2401-2405
Whilst many metal–organic frameworks possess the chemical stability needed to be used as functional materials, they often lack the physical strength required for industrial applications. Herein, we have investigated the mechanical properties of two UiO‐topology Zr‐MOFs, the planar UiO‐67 ([Zr6O4(OH)4(bpdc)6], bpdc: 4,4′‐biphenyl dicarboxylate) and UiO‐abdc ([Zr6O4(OH)4(abdc)6], abdc: 4,4′‐azobenzene dicarboxylate) by single‐crystal nanoindentation, high‐pressure X‐ray diffraction, density functional theory calculations, and first‐principles molecular dynamics. On increasing pressure, both UiO‐67 and UiO‐abdc were found to be incompressible when filled with methanol molecules within a diamond anvil cell. Stabilization in both cases is attributed to dynamical linker disorder. The diazo‐linker of UiO‐abdc possesses local site disorder, which, in conjunction with its longer nature, also decreases the capacity of the framework to compress and stabilizes it against direct compression, compared to UiO‐67, characterized by a large elastic modulus. The use of non‐linear linkers in the synthesis of UiO‐MOFs therefore creates MOFs that have more rigid mechanical properties over a larger pressure range. 相似文献
999.
Infinite Polyiodide Chains in the Pyrroloperylene–Iodine Complex: Insights into the Starch–Iodine and Perylene–Iodine Complexes
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Sheri Madhu Hayden A. Evans Dr. Vicky V. T. Doan‐Nguyen Dr. John G. Labram Dr. Guang Wu Prof. Dr. Michael L. Chabinyc Prof. Dr. Ram Seshadri Prof. Dr. Fred Wudl 《Angewandte Chemie (International ed. in English)》2016,55(28):8032-8035
We report the preparation and X‐ray crystallographic characterization of the first crystalline homoatomic polymer chain, which is part of a semiconducting pyrroloperylene–iodine complex. The crystal structure contains infinite polyiodide I∞δ?. Interestingly, the structure of iodine within the insoluble, blue starch–iodine complex has long remained elusive, but has been speculated as having infinite chains of iodine. Close similarities in the low‐wavenumber Raman spectra of the title compound and starch–iodine point to such infinite polyiodide chains in the latter as well. 相似文献
1000.
Cost‐Effective,High‐Performance Porous‐Organic‐Polymer Conductors Functionalized with Sulfonic Acid Groups by Direct Postsynthetic Substitution
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dong Won Kang Kwang Soo Lim Kyung Jin Lee Jong Hyeon Lee Dr. Woo Ram Lee Jeong Hwa Song Kyu Hyun Yeom Dr. Jin Young Kim Prof. Chang Seop Hong 《Angewandte Chemie (International ed. in English)》2016,55(52):16123-16126
We demonstrate the facile microwave‐assisted synthesis of a porous organic framework 1 and the sulfonated solid ( 1S ) through postsubstitution. Remarkably, the conductivity of 1S showed an approximately 300‐fold enhancement at 30 °C as compared to that of 1 , and reached 7.72×10?2 S cm?1 at 80 °C and 90 % relative humidity. The superprotonic conductivity exceeds that observed for any conductive porous organic polymer reported to date. This material, which is cost‐effective and scalable for mass production, also revealed long‐term performance over more than 3 months without conductivity decay. 相似文献