Anisotropic Local Hardy Spaces

In this paper we introduce and study the anisotropic local Hardy spaces h_A^p(\mathbbRⁿ)h_{A}^{p}(\mathbb{R}^{n}) 0<p≤1, associated with the expansive matrix A. We obtain an atomic characterization of the distributions in h_A^p(\mathbbRⁿ)h_{A}^{p}(\mathbb{R}^{n}). Also we describe the dual spaces of our local Hardy anisotropic spaces as anisotropic Campanato type spaces.     

Microcalorimetric study of the effect of calcium hydroxide and temperature on the alkaline activation of coal fly ash

Journal of Thermal Analysis and Calorimetry - The objective of this research is to know, through the flow of heat released, the effect of the addition of calcium hydroxide and the temperature on...     

Characterizing the influence of reinforcing resin on the structure and the mechanical response of filled isoprene rubber

In the present study, a specific type of reinforcing resin behavior is investigated using various mechanical approaches as well as microscopic techniques such as transmission electron microscopy and atomic force microscopy. Based on these observations, it could be concluded that the reinforcing resin introduces a synergistic effect with carbon black in order to strengthen the system. This is implied since the percolation threshold is significantly reduced and the morphology of the filler aggregates changes toward higher compactness, i.e., an increase of volume-to-size ratio with the addition of resin.     

On-Surface Synthesis and Characterization of Acene-Based Nanoribbons Incorporating Four-Membered Rings

A bottom up method for the synthesis of unique tetracene-based nanoribbons, which incorporate cyclobutadiene moieties as linkers between the acene segments, is reported. These structures were achieved through the formal [2+2] cycloaddition reaction of ortho-functionalized tetracene precursor monomers. The formation mechanism and the electronic and magnetic properties of these nanoribbons were comprehensively studied by means of a multitechnique approach. Ultra-high vacuum scanning tunneling microscopy showed the occurrence of metal-coordinated nanostructures at room temperature and their evolution into nanoribbons through formal [2+2] cycloaddition at 475 K. Frequency-shift non-contact atomic force microscopy images clearly proved the presence of bridging cyclobutadiene moieties upon covalent coupling of activated tetracene molecules. Insight into the electronic and vibrational properties of the so-formed ribbons was obtained by scanning tunneling microscopy, Raman spectroscopy, and theoretical calculations. Magnetic properties were addressed from a computational point of view, allowing us to propose promising candidates to magnetic acene-based ribbons incorporating four-membered rings. The reported findings will increase the understanding and availability of new graphene-based nanoribbons with high potential in future spintronics.     

Directing Group-Promoted Inert C−O Bond Activation Using Versatile Boronic Acid as a Coupling Agent

A simple Ni(cod)₂ and carbene mediated strategy facilitates the efficient catalytic cross-coupling of methoxyarenes with a variety of organoboron reagents. Directing groups facilitate the activation of inert C−O bonds in under-utilized aryl methyl ethers enabling their adaptation for C−C cross-coupling reactions as less toxic surrogates to the ubiquitous haloarenes. The method reported enables C−C cross-coupling with readily available and economical arylboronic acid reagents, which is unprecedented, and compares well with other organoboron reagents with similarly high reactivity. Extension to directing group assisted chemo-selective C−O bond cleavage, and further application towards the synthesis of novel bifunctionalized biaryls is reported. Key to the success of this protocol is the use of directing groups proximal to the reaction center to facilitate the activation of the inert C−OMe bond.     

Antibacterial activity of agave fructans against salmonella typhimurium

Abstract

The objective of this study was to evaluate the antimicrobial effect of Agave fructans against the Salmonella Typhimurium in “in vitro” experiments. The result of the antimicrobial activity was 263.89?±?0, 414.95?±?12.83, 494.54?±?13.88, 522.29?±?0, 580.41?±?14.92?AU for 10, 20, 30, 40 and 50% of Agave fructans (AF) respectively. In addition, there is a significant effect on the growth of the bacteria with all the percentages of AF evaluated (p?<?0.001, R2?=?0.859) with respect to the control. The growth rate of Salmonella with 25% AF was statistically significant compared to the control (?0.7353?±?0.586, 0.0079?±?0.002?D.O./h, respectively; p?>?0.01). Agave fructans could be an alternative to prevent the infections caused by Salmonella.     

Orthonormal tetrad transport. II. Physical identification of the normals and curvatures of a time-like curve

A flat space-time time-like curve is considered from the point of view of an instantaneous comoving inertial observer. In the context of the ‘vierbein’ formalism a projection operator is introduced, able to project 3-vectors, belonging to the 3-space of the comoving observer, out of space-time 4-vectors. The motion of an accelerated particle relative to the comoving inertial frame is briefly reviewed by means of the projection technique, and the three space-like components of the Frenet-Serret tetrad are thus projected, and their motion relative to the comoving observer neatly stated. Finally, the physical identification of the normals and the curvatures obtains in terms of three-dimensional kinematics as seen by the instantaneous comoving observer.     

A biased random-key genetic algorithm with forward-backward improvement for the resource constrained project scheduling problem

This paper presents a biased random-key genetic algorithm for the resource constrained project scheduling problem. The chromosome representation of the problem is based on random keys. Active schedules are constructed using a priority-rule heuristic in which the priorities of the activities are defined by the genetic algorithm. A forward-backward improvement procedure is applied to all solutions. The chromosomes supplied by the genetic algorithm are adjusted to reflect the solutions obtained by the improvement procedure. The heuristic is tested on a set of standard problems taken from the literature and compared with other approaches. The computational results validate the effectiveness of the proposed algorithm.     

Transcendental values of class group <Emphasis Type="Italic">L</Emphasis>-functions

Let K be an algebraic number field and f a complex-valued function on the ideal class group of K. Then, f extends in a natural way to the set of all non-zero ideals of the ring of integers of K and we can consider the Dirichlet series \({L(s,f) =\sum_{{\mathfrak a}} f({\mathfrak a}){\bf N}({\mathfrak a})^{-s}}\) which converges for \({{\mathfrak R}(s) >1 }\). After extending this function to \({{\mathfrak R}(s)=1}\), and in the case that f does not contain the trivial character, we study the special value L(1, f) when f is algebraic valued and K is an imaginary quadratic field. Applying Kronecker’s limit formula and Baker’s theory of linear forms in logarithms, we derive a variety of results related to the transcendence of this special value.