全文获取类型
收费全文 | 3445篇 |
免费 | 136篇 |
国内免费 | 24篇 |
专业分类
化学 | 2173篇 |
晶体学 | 13篇 |
力学 | 91篇 |
数学 | 774篇 |
物理学 | 554篇 |
出版年
2023年 | 35篇 |
2022年 | 80篇 |
2021年 | 90篇 |
2020年 | 63篇 |
2019年 | 85篇 |
2018年 | 64篇 |
2017年 | 67篇 |
2016年 | 139篇 |
2015年 | 105篇 |
2014年 | 121篇 |
2013年 | 199篇 |
2012年 | 250篇 |
2011年 | 286篇 |
2010年 | 158篇 |
2009年 | 173篇 |
2008年 | 232篇 |
2007年 | 222篇 |
2006年 | 201篇 |
2005年 | 162篇 |
2004年 | 159篇 |
2003年 | 100篇 |
2002年 | 95篇 |
2001年 | 40篇 |
2000年 | 42篇 |
1999年 | 29篇 |
1998年 | 27篇 |
1997年 | 24篇 |
1996年 | 32篇 |
1995年 | 15篇 |
1994年 | 19篇 |
1993年 | 16篇 |
1992年 | 27篇 |
1991年 | 14篇 |
1990年 | 28篇 |
1989年 | 13篇 |
1988年 | 12篇 |
1987年 | 11篇 |
1986年 | 16篇 |
1985年 | 21篇 |
1984年 | 23篇 |
1983年 | 10篇 |
1982年 | 7篇 |
1981年 | 14篇 |
1980年 | 8篇 |
1979年 | 9篇 |
1978年 | 6篇 |
1974年 | 8篇 |
1973年 | 5篇 |
1971年 | 6篇 |
1963年 | 5篇 |
排序方式: 共有3605条查询结果,搜索用时 15 毫秒
151.
Hoyos-Montilla Ary A. Puertas F. Tobón Jorge I. 《Journal of Thermal Analysis and Calorimetry》2018,131(3):2395-2410
Journal of Thermal Analysis and Calorimetry - The objective of this research is to know, through the flow of heat released, the effect of the addition of calcium hydroxide and the temperature on... 相似文献
152.
Jorge Castellanos-Soriano Allen T. Ekubo Mark R. J. Elsegood Nuria Lastra-Calvo Aman Mantry Arturo Martinez-Insua-Rodriguez 《Phosphorus, sulfur, and silicon and the related elements》2017,192(5):570-575
New tetraalkylaminophosphonium chlorides were readily prepared by four-fold condensation of commercially available [P(CH2OH)4]Cl with a range of fifteen aryl based primary amines, in EtOH, at ambient temperature. All compounds have been characterized by FT–IR spectroscopy and elemental analysis. Solution 31P{1H} NMR studies of these chloride salts reveal their instability with respect to various PIII/PV species. The structures of three examples have been determined by single crystal X-ray diffraction and confirm the pseudotetrahedral arrangement around the PV center. Extensive N–H···Cl hydrogen bonding is observed. 相似文献
153.
154.
155.
José Maria Esbrí Anna Bernaus Marta ávila David Kocman Eva M. García‐Noguero Beatriz Guerrero Xavier Gaona Rodrigo álvarez Gustavo Perez‐Gonzalez Manuel Valiente Pablo Higueras Milena Horvat Jorge Loredo 《Journal of synchrotron radiation》2010,17(2):179-186
The mobility, bioavailability and toxicity of mercury in the environment strongly depend on the chemical species in which it is present in soil, sediments, water or air. In mining districts, differences in mobility and bioavailability of mercury mainly arise from the different type of mineralization and ore processing. In this work, synchrotron‐based X‐ray absorption near‐edge spectroscopy (XANES) has been taken advantage of to study the speciation of mercury in geological samples from three of the largest European mercury mining districts: Almadén (Spain), Idria (Slovenia) and Asturias (Spain). XANES has been complemented with a single extraction protocol for the determination of Hg mobility. Ore, calcines, dump material, soil, sediment and suspended particles from the three sites have been considered in the study. In the three sites, rather insoluble sulfide compounds (cinnabar and metacinnabar) were found to predominate. Minor amounts of more soluble mercury compounds (chlorides and sulfates) were also identified in some samples. Single extraction procedures have put forward a strong dependence of the mobility with the concentration of chlorides and sulfates. Differences in efficiency of roasting furnaces from the three sites have been found. 相似文献
156.
157.
Antonio Alivert Jorge Bujons Juan-Julio Bonet 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-4):205-207
Abstract The treatment of 2-acetylthiophene with phosphorus pentachloride led, besides other products reported in previous studies, to 2-(2-thienyl)-2-chloroethenephosphonic acid in 16% yield. This compound was transformed, in the course of purification attempts, into 2-(2-thienyl)-2-oxoethanephosphonic acid. Full spectroscopic data for both compounds are provided. 相似文献
158.
Fernando R. Díaz Jorge L. Torres M. Angélica Del Valle Jorge H. Vélez J. Christian BernÈde Gastón A. East 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(10):1101-1108
Poly(3,5‐dichloroaniline) was prepared by chemical oxidation in the presence of various sulfonic acids as doping agent, using potassium permanganate as oxidant. 1‐Naphtalene sulfonic acid, 2‐naphatalene sulphonic acid, 1,5‐naphtalene disulfonic acid, and p‐toluenesulfonic acid were the acids of choice. Infrared and UV‐Vis spectroscopy, utilized to characterize the polymers, revealed that the compounds exist in the emeraldine (conductive) oxidation state. The level of doping, conductivity, and morphology were determined as well. The presence of a sulfonic acid produces a morphological change, from granular to microtubule structures, which is responsible for the strong increase in the conductivity of the polymer. 相似文献
159.
Jorge A. Martínez-Ramírez Juliane Strien Juliane Sanft Gita Mall Grit Walther Frank T. Peters 《Analytical and bioanalytical chemistry》2013,405(26):8443-8450
Cadavers can be colonized by a wide variety of bacteria and fungi. Some of these microbes could change the concentration or the metabolic pattern of drugs present in postmortem samples. The purpose of this study was to identify fungi from human postmortem material and to further assess their potential role in the metabolism of drugs. Aliquots of 252 postmortem samples (heart blood, liver, kidney, and lung) taken from 105 moderately to severely decomposed bodies were streaked on Sabouraud agar for isolation of fungal species. One part of the samples was worked up immediately after autopsy (group I). The second part had previously been stored at ?20 °C for at least 1 year (group II). Identification of the isolates was achieved morphologically by microscopy and molecularly by polymerase chain reaction amplification and sequencing of markers allowing species identification of the respective genera. Depending on the genus, different gene fragments were used: calmodulin for Aspergillus, β-tubulin for Penicillium, translation elongation factor 1α for Fusarium, and the internal transcribed spacer region of the ribosomal DNA for all remaining genera. A total of 156 fungal strains were isolated from 62 % of the postmortem materials. By using these primers, 98 % of the isolates could be identified to the species level. The most common genera were Candida (60.0 %—six species), Penicillium (10.3 %—two species), Rhodotorula (7.1 %—one species), Mucor (6.4 %—four species), Aspergillus (3.2 %—four species), Trichosporon (3.2 %—one species), and Geotrichum (3.2 %—one species). Group I samples contained 53 % more fungal species than stored samples suggesting some fungi did not survive the freezing process. The isolated fungi might be characteristic for decomposed bodies. The proposed methodology proved to be appropriate for the identification of fungi in this type of material. 相似文献
160.
Jorge Pisonero Nerea Bordel Claudia Gonzalez de Vega Beatriz Fernández Rosario Pereiro Alfredo Sanz-Medel 《Analytical and bioanalytical chemistry》2013,405(17):5655-5662
The combination of radiofrequency pulsed glow discharge (RF-PGD) analytical plasmas with time-of-flight mass spectrometry (TOFMS) has promoted the applicability of this ion source to direct analysis of innovative materials. In this sense, this emerging technique enables multi-elemental depth profiling with high depth resolution and sensitivity, and simultaneous production of elemental, structural, and molecular information. The analytical potential and trends of this technique are critically presented, including comparison with other complementary and well-established techniques (e.g. SIMS, GD–OES, etc.). An overview of recent applications of RF-PGD–TOFMS is given, including analysis of nano-structured materials, coated-glasses, photovoltaic materials, and polymer coatings 相似文献