Design and validation of a single sphere multi-detector neutron spectrometer based on LiF: Mg,Cu,P thermoluminescent dosemeters

This communication describes a new neutron spectrometer consisting of pairs of ⁷Li and ⁶Li based thermoluminescent dosemeters (MCP-6, MCP-7) located at selected positions within a single moderating polyethylene sphere. The spatial arrangement of the dosemeters has been designed using the MCNPX Monte Carlo code to calculate the response matrix in order to obtain a nearly isotropic response for neutrons in the energy range up to 20 MeV. A partial validation of the calculated response matrix has been performed with the calibrated ²⁴¹Am–Be neutron source at the INFN–LNF Laboratory, using the shadow cone technique.     

Swarm approach based on gravity for optimizing energy savings in grid systems

Execution time optimization is one of the most important objectives to accomplish for experiments launched on grid environments. However, the computing community is becoming more conscious about energy savings, seeking their optimization. In this work, both execution time and energy consumption are optimized through two swarm and multi-objective algorithms based on both physics and biology fields. On the one hand, multi-objective gravitational search algorithm (MOGSA) is inspired by the gravity forces between the planet masses. On the other hand, Multi-Objective Firefly Algorithm is based on the light attraction between the fireflies. These swarm algorithms are compared with the standard multi-objective algorithm non-dominated sorting genetic algorithm II to study their efficiency as multi-objective algorithms. Moreover, the best algorithm proposed, MOGSA, is compared with MOHEFT (a multi-objective version of one of the most-used algorithms in workflow scheduling, HEFT), and also with two real grid schedulers: Workload Management System and deadline budget constraint. Results show the superior performance of MOGSA regarding the others.     

Weighted inequalities for some integral operators with rough kernels

In this paper we study integral operators with kernels $$K(x,y) = k_1 (x - A_1 y) \cdots k_m \left( {x - A_m y} \right),$$ $k_i \left( x \right) = {{\Omega _i \left( x \right)} \mathord{\left/ {\vphantom {{\Omega _i \left( x \right)} {\left| x \right|}}} \right. \kern-0em} {\left| x \right|}}^{{n \mathord{\left/ {\vphantom {n {q_i }}} \right. \kern-0em} {q_i }}}$ where Ω _i : ? ⁿ → ? are homogeneous functions of degree zero, satisfying a size and a Dini condition, A _i are certain invertible matrices, and n/q ₁ +…+n/q _m = n?α, 0 ≤ α < n. We obtain the appropriate weighted L ^p -L ^q estimate, the weighted BMO and weak type estimates for certain weights in A(p, q). We also give a Coifman type estimate for these operators.     

Conorm and Essential Conorm in C*-Algebras

Let A be a unital C^*-algebra with non-zero socle (soc(A)). We introduce the essential conorm of an element a in A (denoted by γ _e (a)), as the conorm of the element π(a), where π denotes the canonical projection of A onto . It is established that for every von Neumann regular element , γ _e (a) = max . We characterize the continuity points of the conorm and essential conorm for extremally rich C^*-algebras. Some formulae for the distance from zero to the generalized spectrum and Atkinson spectrum are also obtained. Authors partially supported by I+D MEC projects no. MTM2005-02541 and MTM2007-65959, and Junta de Andalucía grants FQM0199 and FQM1215.     

Closed-form BER analysis of variable weight MPPM coding under gamma-gamma scintillation for atmospheric optical communications

In this paper, the performance of the variable weight multiple pulse-position modulation (MPPM) coding technique in an atmospheric optical communication environment under gamma-gamma optical scintillation is analyzed, proposing a closed-form expression for the average bit error rate (BER). This study is based on a hyperexponential fitting of the conditional BER in absence of turbulence fluctuations, leading to closed-form expressions that characterize the behavior of this nonlinear coding scheme. Finally, conditional and average BER expressions proposed here are corroborated with Monte Carlo simulations results.     

An unexpected Pummerer rearrangement in the synthetic route to ethyl (2′-hydroxy-4′,5′-methylenedioxyphenyl)acetate: An alternative approach to 2,3-dimethylthio benzofurans

The synthesis of ethyl (2′-hydroxy-4′,5′-methylendioxophenyl)acetate, a fragment of the antihyperglycemic natural coumarin subcoriacin, is reported. We found an expeditious route to the title compound in five steps. Final metal catalyzed acid ethanolysis of the vinylic 1,1-methylthio methylsulfoxide derivative afforded the required aryl acetic ester, but in the absence of metal catalyst, an unexpected Pummerer rearrangement produced the 2,3-dimethylthiofuran derivative as the major product. This last result provides an alternative entry to 2,3-dimethlythiobenzofurans.     

On the Structure and Formation of Self-Assembled Lattices of Gold Nanoparticles

The structure and ordering of nanoparticles of gold functionalized with n-alkyl thiol molecules are studied both experimentally and theoretically. Samples where produced using n=6 to n=16 alkyl thiol molecules. High Resolution Electron Microscopy coupled with image processing was used to study the gold particle structure. The details of the particle structure are discussed. We found that when the gold surface is saturated with thiol molecules there is some tendency to produce molecules with a disulphide structure. We also show that ordered arrays of particles can be produced using Langmuir-Blodgett techniques. The crystal structure of the films produced is studied and found to be 3D hcp. We also report that thiol covered gold particles with a size of 5 nm present a rounded shape suggesting that thiol molecules might induce an isotropic surface energy. It is found in the theoretical calculations that a strong bond between gold and sulphur is required to stabilize the complex metal-n-alkyl thiol. It is predicted that otherwise a heavily distorted nanocore will be formed. This is contrary to the observed structure of the particles.     

Solubility and preferential solvation of acetaminophen in methanol + water mixtures at 298.15 K

The equilibrium solubility of acetaminophen in methanol + water binary mixtures at 298.15 K was determined and correlated with the Jouyban–Acree model. Preferential solvation parameters by methanol (δx_1,3) were derived from their thermodynamic solution properties by means of the inverse Kirkwood–Buff integrals method. δx_1,3 values are negative in water-rich mixtures but positive in compositions from 0.32 in mole fraction of methanol to pure methanol. It is conjecturable that in the former case, the hydrophobic hydration around non-polar groups plays a relevant role in the solvation. The higher solvation by methanol in mixtures of similar cosolvent compositions and methanol-rich mixtures could be explained in terms of the higher basic behavior of this cosolvent.     

Synthesis and electrochemical reaction with lithium of mesoporous iron oxalate nanoribbons

Mesoporous FeC 2O 4 was prepared by dehydration of bulk monoclinic- and micellar orthorhombic FeC 2O 4.2H 2O precursors at 200 degrees C. The micellar material shows nanoribbon shaped particles, which are preserved after dehydration. These solids are used as high-capacity lithium storage materials with improved rate performance. The mesoporous nanoribbons exhibit higher capacities close to 700 mA h/g after 50 cycles at 2C (C = 1 Li h (-1) mol (-1)) rate between 0 and 2 V.