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121.
Jordi Bols Santiago Gubert Lluís Anglada Angel Prez Aurelio Sacristn Jos A. Ortiz 《Journal of heterocyclic chemistry》1994,31(6):1493-1496
The synthesis of the novel amino acid 6-(hydroxymethyl)-2-piperidinecarboxylic acid ( 1a ) and its ethyl ester 1b is reported. In the hydrogenation of 6-(hydroxymethyl)pyridine-2-carboxylates, hydrogenolysis of the alcohol group appeared as an unusual side reaction. Optimization of the reaction conditions allowed us to minimize hydrogenolysis and afforded pure 1 . 相似文献
122.
Aleman C Zanuy D Casanovas J Cativiela C Nussinov R 《The journal of physical chemistry. B》2006,110(42):21264-21271
We have used quantum mechanical calculations at the B3LYP/6-311G(d,p) level to determine the conformational preferences of the N-acetyl-N'-methylamide derivative of 1-aminocyclopentane-1-carboxylic acid in the gas phase, chloroform solution, and water solution. The backbone conformation of this dipeptide has been described through the dihedral angles varphi and psi, while the pseudorotational phase angle was used to define the conformation of the cyclopentane ring. Results indicate that the backbone flexibility of this amino acid is restricted by the cyclic nature of the side chain, the relative stability of the different conformations depending on the polarity of the environment. The potential energy of the pseudorotation was also studied as a function of the backbone conformation. Interestingly, the conformation of the cyclic side chain depends on the backbone arrangement. Furthermore, the number of pseudorotational states accessible at room temperature is high in all the investigated environments, especially in aqueous solution. Finally, a set of force-field parameters for classical molecular mechanics calculations was developed for the investigated amino acid. Molecular dynamics simulations in both chloroform and aqueous solutions were performed to demonstrate the reliability of such parameters. 相似文献
123.
Cavallini M Gomez-Segura J Albonetti C Ruiz-Molina D Veciana J Biscarini F 《The journal of physical chemistry. B》2006,110(24):11607-11610
We report a new patterning process which takes place as a result of demixing of a binary polymer/solute mixture. An efficient, sustainable approach for ordering nanosized rings of so-called single molecule magnets (SMMs) is thus provided. It exploits the self-organization process in which SMM patterned film evolves to a spatially correlated pattern of nanosized rings. At long time, the anisotropic patterning of the film drives the ring to coalesce, into parallel lines of nanometric width. 相似文献
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126.
Crowd synchrony and quorum sensing arise when a large number of dynamical elements communicate with each other via a common information pool. Previous evidence has shown that this type of coupling leads to synchronization, when coupling is instantaneous and the number of coupled elements is large enough. Here we consider a situation in which the transmission of information between the system components and the coupling pool is not instantaneous. To that end, we model a system of semiconductor lasers optically coupled to a central laser with a delay. Our results show that, even though the lasers are nonidentical due to their distinct optical frequencies, zero-lag synchronization arises. By changing a system parameter, we can switch between two different types of synchronization transition. The dependence of the transition with respect to the delay-coupling parameters is studied. 相似文献
127.
In this paper we study the difference between the 2-adic valuations of the cardinalities \( \# E( \mathbb {F}_{q^k} ) \) and \( \# E( \mathbb {F}_q ) \) of an elliptic curve E over \( \mathbb {F}_q \). We also deduce information about the structure of the 2-Sylow subgroup \( E[ 2^\infty ]( \mathbb {F}_{q^k} ) \) from the exponents of \( E[ 2^\infty ]( \mathbb {F}_q ) \). 相似文献
128.
Jordi Juan-Huguet 《Integral Equations and Operator Theory》2010,68(2):263-286
Let P be a linear partial differential operator with constant coefficients. For a weight function ω and an open subset Ω of
\mathbbRN{\mathbb{R}^N} , the class EP,{w}(W){\mathcal{E}_{P,\{\omega\}}(\Omega)} of Roumieu type involving the successive iterates of the operator P is considered. The completeness of this space is characterized in terms of the hypoellipticity of P. Results of Komatsu and Newberger-Zielezny are extended. Moreover, for weights ω satisfying a certain growth condition, this class coincides with a class of ultradifferentiable functions if and only if
P is elliptic. These results remain true in the Beurling case EP,(w)(W){\mathcal{E}_{P,(\omega)}(\Omega)}. 相似文献
129.
130.
De Witte PA Hernando J Neuteboom EE van Dijk EM Meskers SC Janssen RA van Hulst NF Nolte RJ García-Parajó MF Rowan AE 《The journal of physical chemistry. B》2006,110(15):7803-7812
The synthesis and characterization of perylenediimide polyisocyanides is reported. In addition to short oligomers, our synthetic approach results in the formation of extremely long, well-defined, and rigid perylenediimide polymers. Ordering and close-packing of the chromophores in these long polymers is guaranteed by attachment to a polyisocyanide backbone with amino acid side chains. Hydrogen bonding interactions between those groups stabilize and rigidify the helical polymer structure. The rodlike nature of the synthesized long perylenediimide pendant polyisocyanides as well as the helical arrangement of the chromophores is demonstrated by means of atomic force microscopy. Remarkably, polymer fibers up to 1 mum in length have been visualized, containing several thousands of perylenediimide molecules. Circular dichroism spectroscopy reveals the chiral organization of the chromophore units in the polymer, whereas absorption and emission measurements prove the occurrence of excited-state interactions between those moieties due to the close packing of the chromophore groups. However, an intricate optical behavior is encountered in bulk as a result of the coexistence of short oligomers and long polymers of perylenediimide, a situation subsequently uncovered by means of single-molecule experiments. Individual long helical perylenediimide polyisocyanides exhibit a typical red-shifted fluorescence spectrum, which, together with depolarized emission continuously decreasing in time, demonstrate that fluorescence arises from multiple excimer-like species in the polymer. Upon continuous irradiation of these long polymers, a fast decay in fluorescence lifetime is observed, a situation explained by photoinduced creation of quenching sites. Radical/ion formation by intramolecular electron transfer between close-by perylenediimide moieties is the most probable mechanism for this process. Appropriate control of the electron-transfer process might open the possibility of applying these polymers as perylenediimide-based supramolecular nanowires. 相似文献