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991.
Nassif N Cense B Park BH Yun SH Chen TC Bouma BE Tearney GJ de Boer JF 《Optics letters》2004,29(5):480-482
An ultrahigh-speed spectral domain optical coherence tomography (SD-OCT) system is presented that achieves acquisition rates of 29,300 depth profiles/s. The sensitivity of SD-OCT and time domain OCT (TD-OCT) are experimentally compared, demonstrating a 21.7-dB improvement of SD-OCT over TD-OCT. In vivo images of the human retina are presented, demonstrating the ability to acquire high-quality structural images with an axial resolution of 6 microm at ultrahigh speed and with an ocular exposure level of less than 600 microW. 相似文献
992.
The photochemical behavior of 2-halo-N-pyridinylbenzamide (1-4 in Chart 1) was studied. The photoreaction of 2-chloro-N-pyridinylbenzamides 1a, 2a, 3a, and 4 afforded photocyclized products, benzo[c]naphthyridinones (6-9 and 16), in high yield, whereas the bromo analogues 1b, 2b, and 3b produced extensively photoreduced products, N-pyridinylbenzamides (1c, 10, and 11), with minor photocyclized product. Since the photocyclization reaction of 2-chloro-N-pyridinylbenzamide is retarded by the presence of oxygen and sensitized by the presence of a triplet sensitizer, acetone or acetophenone, a triplet state of the chloro analogue is involved in the reaction. Since several radical intermediates, particularly n-complexes of chlorine radical, are identified in the laser flash photolysis of 2-chloro-N-pyridinylbenzamide, an intramolecular cyclization mechanism of phenyl radical assisted with n-complexation of chlorine radical for the cyclization reaction is proposed: the triplet state (78 kcal/mol) of the chloro analogue (1a), which is populated by the excitation of 1a undergoes a homolytic cleavage of the C-Cl bond to give phenyl and chlorine radicals; while chlorine radical holds the neighbor pyridinyl ring with its n-complexation, the intramolecular arylation of the phenyl radical with the pyridinyl ring proceeds to produce a conjugated 2,3-dihydropyridinyl radical and then the conjugated radical aromatizes to afford a cyclized product, benzo[c]naphthyridinone by ejecting a hydrogen. The photoreduction product can be formed by hydrogen atom abstraction of the phenyl sigma radical from the environment. 相似文献
993.
A synthetic strategy for the preparation of cyclic peptide mimetics based on SET-promoted photocyclization processes 总被引:2,自引:0,他引:2
Yoon UC Jin YX Oh SW Park CH Park JH Campana CF Cai X Duesler EN Mariano PS 《Journal of the American Chemical Society》2003,125(35):10664-10671
A novel method for the synthesis of cyclic peptide analogues has been developed. The general approach relies on the use of SET-promoted photocyclization reactions of peptides that contain N-terminal phthalimides as light absorbing electron acceptor moieties and C-terminal alpha-amidosilane or alpha-amidocarboxylate centers. Prototypical substrates are prepared by coupling preformed peptides with the acid chloride of N-phthalimidoglycine. Irradiation of these substrates results in the generation of cyclic peptide analogues in modest to good yields. The chemical efficiencies of these processes are not significantly affected by (1) the lengths of the peptide chains separating the phthalimide and alpha-amidosilane or alpha-amidocarboxylate centers and (2) the nature of the penultimate cation radical alpha-heterolytic fragmentation process (i.e., desilylation vs decarboxylation). An evaluation of the effects of N-alkyl substitution on the amide residues in the peptide chain showed that N-alkyl substitution does not have a major impact on the efficiencies of the photocyclization reactions but that it profoundly increases the stability of the cyclic peptide. 相似文献
994.
James L. Park 《Foundations of Physics》1970,1(1):23-33
The concept of quantum transition is critically examined from the perspective of the modern quantum theory of measurement. Historically rooted in the famous quantum jump of the Old Quantum Theory, the transition idea survives today in experimental jargon due to (1) the notion of uncontrollable disturbance of a system by measurement operations and (2) the wave-packet reduction hypothesis in several forms. Explicit counterexamples to both (1) and (2) are presented in terms of quantum measurement theory. It is concluded that the idea of transition, or quantum jump, can no longer be rationally comprehended within the framework of contemporary physical theory. 相似文献
995.
Kim GN Kim EJ Son D Bacala A Imlay R Kirk P McNeil RR Metcalf W Cheng CP Mao ZP Yan Y Xu YT Zhu YC Abashian A Gotow K Kajino F Low E Naito F Piilonen L Childers R Darden C Lusin S Rosenfeld C Wilson S Frautschi M Kagan H Kass R Trahern CG Ko W Lander RL Maeshima K Malchow RL Higashi JR Kurihara Y Maki A Nozaki T Omori T Perez P Sagawa H Sakai Y Sugimoto Y Takaiwa Y Terada S Tsuchiya K Poling R Green J Park IH Sakamoto S Sannes F Schnetzer S Stone R Trentalange S Zimmerman D Miyano K Miyata H 《Physical review letters》1988,61(8):911-914
996.
Muramatsu H Richichi SJ Severini H Skubic P Dytman SA Mueller JA Nam S Savinov V Chen S Hinson JW Lee J Miller DH Pavlunin V Shibata EI Shipsey IP Cronin-Hennessy D Lyon AL Park CS Park W Thorndike EH Coan TE Gao YS Liu F Maravin Y Narsky I Stroynowski R Artuso M Boulahouache C Bukin K Dambasuren E Khroustalev K Mountain R Nandakumar R Skwarnicki T Stone S Wang JC Mahmood AH Csorna SE Danko I Bonvicini G Cinabro D Dubrovin M McGee S Bornheim A Lipeles E Pappas SP Shapiro A Sun WM Weinstein AJ 《Physical review letters》2002,89(25):251802
In e(+)e(-) collisions using the CLEO detector, we have studied the decay of the D0 to the final state K(0)(S)pi(+)pi(-) with the initial flavor of the D0 tagged by the decay D(*+)-->D0pi(+). We use the Dalitz technique to measure the resonant substructure in this final state and clearly observe ten different contributions by fitting for their amplitudes and relative phases. We observe a K(*)(892)(+)pi(-) component which arises from doubly Cabibbo suppressed decays or D0-D0; mixing. 相似文献
997.
998.
Jijun Qiu Weidong Yu Xiangdong Gao Xiaomin Li Weizhen He Se-Jeong Park Hyung-Kook Kim Yong-Hwae Hwang 《Journal of Sol-Gel Science and Technology》2008,47(2):187-193
Silver nanoparticles well dispersed in a spherical Poly(vinylpyrollidone)(PVP) matrix were simply prepared by spray pyrolysis
of aqueous solutions of AgNO3 and PVP without any reducing agent. Highly monodisperse silver particles were obtained above the initial mass ratio of PVP/AgNO3 ∼ 1 and in a certain narrow temperature range. Below the critical mass ratio the silver particles grew to larger ones polydispersely.
As the ratio increased above it, they became smaller maintaining their monodispersity. The use of PVP considerably decreased
the reduction temperature of the silver nitrate from 450 °C to 250 °C under the same pyrolysis conditions, due to its reducing
nature. As the pyrolysis temperature increased above the decomposition temperature of PVP, the silver particles in the matrix
grew to merge to a single particle while their crystallite size did not increase as much. The spherical assemblies of the
silver nanoparticles were hardly disengaged even after severe washing off the matrix materials. The mechanism of the nanoparticle
growth was also discussed. 相似文献
999.
Jung H. Park Min G. Kim Suk-Jin Ahn Hyun M. Jang 《Journal of magnetism and magnetic materials》2009,321(13):1971-1974
An atomic-scale picture of the strain-mediated magnetoelectric (ME) coupling is delineated by carefully examining the effect of an applied electric field on the extended X-ray absorption fine structure (EXAFS) spectra of a CoFe2O4-dispersed Pb(Zr,Ti)O3 matrix (CFO-PZT) composite. These studies demonstrated a tensile-compressive strain relation between the PZT matrix and the dispersed CFO phase, thereby providing an X-ray spectroscopic evidence of the interfacial strain-mediated ME coupling. Both the dielectric anomaly observed at ∼480 °C and the decrease in the remanent magnetization under an applied electric field support the strain-mediated ME coupling in the CFO-PZT composite. 相似文献
1000.
The purpose of this article is to generalize the theory of stability of functional equations to the case of n‐Banach spaces. In this article, we prove the generalized Hyers–Ulam stabilities of the Cauchy functional equations, Jensen functional equations and quadratic functional equations on n‐Banach spaces. 相似文献