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991.
Fabrication of superhydrophobic surface from a supramolecular organosilane with quadruple hydrogen bonding 总被引:5,自引:0,他引:5
A supramolecular organosilane, 2-(3-(triethoxysilyl)propylaminocarbonylamino)-6-methyl-4[1H]pyrimidinone comprising quadruple hydrogen bonds has been synthesized in one step from commercially available starting materials. The synthesized supramolecular organosilane can be stabilized and phase-separated by dimerization via the linear array of quadruple hydrogen bonds in solution. This property of the supramolecular organosilane has been exploited to fabricate structuring materials having a superhydrophobic surface property. We have successfully generated the interconnected granular structure with adequate roughness for superhydrophobicity via sol-gel process. 相似文献
992.
Hong YS Lee D Kim W Jeong JK Kim CG Sohng JK Lee JH Paik SG Lee JJ 《Journal of the American Chemical Society》2004,126(36):11142-11143
The post-polyketide synthase modification of geldanamycin (1) biosynthesis is of interest as a means of introducing structural diversity into the compound. From the inactivation of a gene encoding carbamoyltransferase, we demonstrated that the C-17 hydroxylation and the C-21 oxidation precede O-carbamoylation and that the hypothetical progeldanamycin does not possess a double bond at C-4 and C-5. More importantly, our result revealed new intermediates 4,5-dihydro-7-O-descarbamoyl-7-hydroxygeldanamycin (3) and 4,5-dihydrogeldanamycin (5), indicating that O-carbamoylation occurs prior to the C-4,5 cis double bond formation in geldanamycin biosynthesis. 相似文献
993.
Deep Eutectic Solvent-Based HS-SME Coupled with GC for the Analysis of Bioactive Terpenoids in Chamaecyparis obtusa Leaves 总被引:1,自引:0,他引:1
Headspace-solvent microextraction (HS-SME) was developed as a solvent-minimized extraction technique, but few studies have examined the applications of deep eutectic solvents (DESs) to the HS-SME of bioactive compounds. In this study, HS-SME was developed for the extraction of bioactive compounds using DESs as extraction solvents. DESs, which were prepared by mixing choline chloride (ChCl) with ethylene glycol (EG) at different ratios, were applied to the extraction of three terpenoids from Chamaecyparis obtusa leaves by HS-SME. The ChCl/EG ratio in the DESs, HS-SME conditions, such as the extraction temperature and extraction time, and sample/DES ratio were optimized. All extracts were analyzed by GC. Under optimized conditions, the limits of detection were 2.006 ng mL?1 for linalool, 3.150 ng mL?1 for α-terpineol and 2.129 ng mL?1 for terpinyl acetate. The relative standard deviations were in the range of 2.1–6.8 %. The recoveries of the three terpenoids were in the range of 79.4–103 %. HS-SME is simple and rapid compared to heat reflux extraction and ultrasonic extraction. Moreover, DESs can be used in HS-SME for the extraction of a range of bioactive and volatile compounds. 相似文献
994.
Jin‐Woong Kim Jung‐Eun Lee Jee‐Hyun Ryu Jong‐Suk Lee Su‐Jin Kim Sang‐Hoon Han Ih‐Seop Chang Hak‐Hee Kang Kyung‐Do Suh 《Journal of polymer science. Part A, Polymer chemistry》2004,42(10):2551-2557
A new colloidal silver system is presented in which a fine colloidal silver is in situ deposited onto functionalized porous poly(ethylene glycol dimethacrylate) [poly(EGDMA)] microspheres. The effectiveness of the silver deposition has been investigated through an examination of the surface characteristics of poly(EGDMA) microspheres. The result reported in this study demonstrate that the control of the surface area and surface functionality (in this study, a hydroxyl group) of poly(EGDMA) microspheres is an important factor that practically determines the degree of deposition of colloidal silver. X‐ray analysis has shown that silver nanoparticles are dispersed evenly on inner and outer surfaces and have a face center cubic phase. Preservation testing has shown that silver‐containing poly(EGDMA) microspheres have powerful antibacterial properties and, therefore, have significant potential as new preservatives. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2551–2557, 2004 相似文献
995.
Joo D. L. Laboy J. Kolomeisky A. Zhuo Q. Clouthier D. J. Chan C. P. Merer A. J. Judge R. H. 《Journal of Molecular Spectroscopy》1995,170(2)
High-resolution infrared spectra of the low-lying ν3, ν4, and ν5 fundamentals of the transient molecule DCOCl are reported. These type-A/B hybrid bands have been analyzed in detail, providing extensive rotational assignments for the DCO35Cl and DCO37Cl isotopomers. The ground state constants have been refined by a simultaneous fit of the available microwave data and FTIR combination differences from the three bands. The excited state constants have been determined by fitting assignments over a wide range of J and Ka values. A small perturbation was found at high Ka values in the ν4 band and determined to be due to a ΔKa = −2 interaction with the rotational levels of the 61 vibrational state. 相似文献
996.
Mai Ha Hoang Myung Hee Kim Min Ju Cho Kyung Hwan Kim Kyu Nam Kim Jung‐Il Jin Dong Hoon Choi 《Journal of polymer science. Part A, Polymer chemistry》2008,46(15):5064-5076
We synthesized new nonlinear optical (NLO) chromophores containing a 3,5‐bis(3,5‐bisbenzyloxy‐benzyloxy)‐benzoate dendron. Tricyanopyrroline (TCP)‐based chromophores were designed and prepared by virtue of its strong electron withdrawing property. A soluble polyimide containing 6‐({4‐[2‐(1‐allyl‐4‐cyano‐5‐dicyanomethylene‐2‐oxo‐2,5‐dihydro‐1H‐pyrrol‐3‐yl)‐vinyl]‐phenyl}‐butyl‐amino)‐hexanoyl group in the side chain was also prepared as an NLO active host polymer. A benzoate dendron was tethered at two different binding positions of the chromophore to yield two different guest molecules. Thin‐film composites of these dendronized chromophores dissolved in the NLO active polyimide host were employed to fabricate the electro‐optic (EO) samples. The EO properties of new NLO polyimides containing dendronized chromophores were compared with those of the sample with nondendronized plain chromophores. The effect of a bulky dendron on the EO properties was investigated using an in situ reflection technique. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 5064–5076, 2008 相似文献
997.
998.
999.
Suhee Song Youngeup Jin Sun Hee Kim Joo Young Shim Sooyeon Son Il Kim Kwanghee Lee Hongsuk Suh 《Journal of polymer science. Part A, Polymer chemistry》2009,47(23):6540-6551
The present investigation deals with the synthesis, characterization, and EL properties of new polyfluorenevinylenes, CzCNPFVs, with cyano‐substituted vinylene unit and carbazole pendant. In CzCNPFVs, synthesized by the Knoevenagel condensation, the carbazole pendant was introduced to improve the efficiency of reported CNPFV. The PL emission spectra of the CzCNPFVs in chloroform solution show maximum peaks at 476–479 nm. In thin films, maximum peaks of the CzCNPFVs appeared at 501–504 nm, red‐shifted around 25 nm as compared to those in solution. The emission maxima of the EL spectra of the polymers appear at around 496–504 nm. The maximum luminescence (Lmax) of CzCNPFV2 of the device with the configuration of ITO/PEDOT/CzCNPFVs/Ca/Al is 1724 cd/m2 at 8 V. The maximum luminescence efficiency of CzCNPFV1 is 0.18 cd/A. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 6540–6551, 2009 相似文献
1000.
Thomas M. Klapötke Prof. Dr. Burkhard Krumm Dr. Matthias Scherr Dr. F. Xaver Steemann Dr. Klaus Banert Prof. Dr. Young‐Hyuk Joo Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(42):11341-11345
The synthesis and structural properties (from X‐ray diffraction or B3LYP/6‐31G(d) calculations) of three energetic compounds derived from tris(chloromethyl)amine and of tris(chloromethyl)amine itself were investigated and compared to those of compounds with similar structures. The compounds have almost planar NC3 units at their amine center, and the substituents bound to the CH2 groups tend to be reactive towards further substitution. Multiple hyperconjugation was used to explain these observations. 相似文献