氢化丁苯共聚物结构的核磁共振波谱表征Ⅰ.13C谱带的归属

本文分别用JEOL FX-90Q和Bruker AM-300波谱仪测定了氢化聚丁二烯和氢化丁苯共聚物的¹H,¹³C-NMR谱,得到了分辨率较高的谱图和新的结构信息。借助DEPT技术确定了各谱带的CH或CH₂类型。利用Grant-Paul和Lindeman-Adams介绍的化学位移经验计算公式,考虑苯基对α、β和γ碳原子的影响,计算了各种三单元序列中有关碳原子的化学位移。对脂肪碳部分的28组谱带重新进行了归属。化学位移计算值与实测值基本相符,并得到了不同组成的模型聚合物¹³C-NMR谱的各谱带强度变化规律的验证。     

A global optimization design for quasi-optics power combiner of 3mm wave solid-state sources

This paper describes a global optimization design for quasi-optics power combiner of solid-state millimeter-wave sources. The operating frequency is about 100 GHz and the oscillating sources are GaAs Gunn diodes. The source-array plane is a matrix consisting of NxN (N=3,5, ..., 2k+1, where k is positive integer) diodes. The radio frequency power of the combiner is from threefold to sevenfold larger than the sum total of the single diodes power. The global optimums of the array and the location in the cuvity of the suorce-array plane will be given by a global optimizition method.     

取代基效应(SCS)与乙烯-α-烯烃共聚物的序列结构Ⅲ.定量分析

本文在分析乙烯-α-烯烃共聚物序列结构时,把代表共单体反接单元的亚甲基(CH₂)βγ和γδ分别归属给了二元组VV和三元组EEV。与此同时,CH₂-δδ和δδ⁺归属给了二元组EE。表征乙烯长序列的CH₂-δ⁺δ⁺分属二元组EE和三元组EEE,对应峰强度在EE和EEE之间的分配是处理序列分布的关键。在本文中运用序列结构的Bovey关系和Randall统计进行演算,求得了修正值△的数学表达式,严格解和近似解。在规则链条件下得到的近似解与G.J.Ray的结果完全相同。当共单体含量较少时,谱峰强度Iδ⁺δ⁺的分配接近相等。在二元组和三元组的水平上,乙烯-α-稀烃共聚物的¹³C NMR谱中共有十三个峰,属于CH₂的有十个,属于CH的有三个。利用这些谱峰的强度数据可以建立一套计算公式,由此提供共聚物序列结构的全部信息。因此这是一个研究乙烯-α-烯烃共聚物序列结构的普适方法。     

离焦散斑技术研究Kirchhoff板在动载作用期的弯曲

本文使用动态离焦散斑技术,测试板的动态弯曲获得成功。并推导了Kirchhoff板动态变形的有关分析,提出了由最大斜率确定材料常数的思想。显然,这是同离焦散斑方法所测数据直接相关的处理手法。     

Solitary wave solutions and cnoidal wave solutions to the combined KdV and mKdV equation

This paper presents a mapping approach for the construction of exact solutions to the combined KdV and mKdV equation. There exist two types of soliton solutions which will reduce back to those of the KdV and mKdV equations in some appropriate limits. Four types of the general cnoidal wave solutions are also obtained.     

Intramolecular motion and isotope effects in muonium‐substituted chloroalkyl radicals

Muon irradiation of pure liquid 3‐chloropropene, CH₂=CH-CH₂Cl, yields a primary radical, \dot\mboxCH₂-CHMu-CH₂Cl, and a secondary radical, MuCH₂-\rm\dot\mboxCH-CH₂Cl. 2‐methyl‐3‐chloropropene yields only the tertiary radical, MuCH₂-\rm\dot\mboxC(CH₃)-CH₂Cl. These three chloroalkyl radicals have been characterized by μSR and μLCR, and the hyperfine coupling constants (hfcs) have been determined over a range of temperatures, either in the pure liquid precursor or in concentrated solution. The temperature variation of the hfcs has been analyzed to obtain estimates of the barrier to internal rotation about the C_\alpha-C_\beta axis for various alkyl groups, and also their minimum energy conformations, i.e. their orientations with respect to the axis of the 2p_z orbital of the unpaired electron. The tertiary radical is particularly interesting because all three methyl‐like groups, -CH₃,-CH₂Cl and -CH₂Mu, are represented. The results can be compared to electron spin resonance data for analogous radicals, to provide information on the effects of Mu substitution for H. This revised version was published online in August 2006 with corrections to the Cover Date.     

Diffusion via splitting and remeshing via merging in vortex methods

The technique of splitting a fat vortex element (with a core width larger than some threshold) into some thin ones in order to fix the convergence problem of the core‐spreading vortex methods is convenient and efficient. In particular, it keeps the method purely Lagrangian. In the present investigation, the splitting process is further viewed as part of the physical diffusion process. A new splitting method in which several weaker child vortices surround a thinned but still strong parent vortex is proposed. It is found that because of the survival of the parent vortex, the error arising from the splitting events can be largely reduced. The computational amount on the other hand is kept reasonably large by merging similar and close‐by vortices. The merging scheme designed herein not only involves fewer restrictions but also allows merging vortices of opposite rotations through the viewpoint of remeshing. The validity and accuracy of these techniques, proposed particularly for simulations undergoing lots of splitting and merging events, are verified by successfully simulating the interactions between two Burgers vortices under an external straining field. Copyright © 2005 John Wiley & Sons, Ltd.     

Behaviors of the positive temperature coefficient of resistance of poly(styrene‐co‐n‐butylacrylate) filled with Ni‐plated core‐shell polymeric particles

Conductive composite films of poly(styrene‐co‐n‐butylacrylate) copolymers filled with low‐density, Ni‐plated core‐shell polymeric particles were prepared and their behaviors of positive temperature coefficient of resistance (PTCR) were investigated. When the conductive fillers in the composite film were loaded beyond the critical volume, 10 up to 25 vol %, composite films exhibited a unique electrical resistant transition behavior, which the electrical resistance rapidly increased by several orders of magnitude at the critical temperature. The PTCR transition temperature, in general, occurred before the glass transition temperature of polymer matrix. Further increased the conductive filler loading to 30 vol %, the overpacked conduction paths were formed in the entire composite and the PTCR effects became blurred. While the composite film treated with thermal cycle several times from room temperature up to 120 °C, the electrical resistivity increased accompanied with the shift of the PTCR transition to lower temperature. The reason might have been caused by the formed interfacial cracks within the composite film. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 322–329, 2007     

Isolation and Structure Elucidation of Nortriterpenoids from Schisandra rubriflora

Seven new highly oxygenated nortriterpenoids, rubriflorins D–J ( 1 – 7 ), were isolated from the leaves and stems of Schisandra rubriflora, and their structures were elucidated on the basis of extensive analysis of spectroscopic data. These new compounds feature the opening of ring A compared with related known nortriterpenoids isolated from the genus Schisandra and showed weak activity against HIV‐1.