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As a first step towards a general structure theory for comtrans algebras (modeled loosely on the Cartan theory for Lie algebras), this paper investigates comtrans algebras of bilinear spaces. Attention focuses on invariants associated with comtrans algebras, and the extent to which these invariants may serve to specify the algebras up to isomorphism within certain classes. Over fields whose characteristic differs from two, comtrans algebras of symmetric forms are determined up to isomorphism by the eigenvalues of generic adjoints, while comtrans algebras of symplectic forms are determined by the dimensions of maximal abelian subalgebras. Examples show that the multiplicity of zero as a root of the characteristic polynomial is generally independent of the dimension of a maximal abelian subalgebra. 相似文献
424.
Jonathan D. Sellars 《Tetrahedron》2009,65(28):5588-935
Silacyclic allylsilanes generated through a silene-diene Diels-Alder cycloaddition represent versatile bifunctional reagents for organic synthesis. This is demonstrated in a short stereocontrolled synthesis of (±)-Prelactone B. 相似文献
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Oxetane synthesis via cyclisation of aryl sulfonate esters on polystyrene and PEG polymeric supports
The addition of suitably protected pentaerythritols to polymer supported sulfonyl chloride with subsequent alkoxide formation and intramolecular cyclisation to generate oxetanes is described. This convenient method for the preparation of oxetanes has several advantages over analogous solution phase reactions and the methodology is extended to the preparation and use of a novel PEG-sulfonyl chloride. 相似文献
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Jonathan P. Williams Julie Ann Lough Iain Campuzano Keith Richardson Peter J. Sadler 《Rapid communications in mass spectrometry : RCM》2009,23(22):3563-3569
We report the development of an enhanced algorithm for the calculation of collision cross‐sections in combination with Travelling‐Wave ion mobility mass spectrometry technology and its optimisation and evaluation through the analysis of an organoruthenium anticancer complex [(η6‐biphenyl)RuII(en)Cl]+. Excellent agreement was obtained between the experimentally determined and theoretically determined collision cross‐sections of the complex and its major product ion formed via collision‐induced dissociation. Collision cross‐sections were also experimentally determined for adducts of this ruthenium complex with the single‐stranded oligonucleotide hexamer d(CACGTG). Ion mobility tandem mass spectrometry measurements have allowed the binding sites for ruthenium on the oligonucleotide to be determined. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
430.
Jennifer A. Aitken Jonathan W. Lekse Jin-Lei Yao Rosalynn Quinones 《Journal of solid state chemistry》2009,182(1):141-8062
EuCu2SnS4 was prepared by a stoichiometric combination of the elements heated to 700 °C for 125 h. The structure was determined by single crystal X-ray diffraction methods. The compound crystallizes in the noncentrosymmetric, orthorhombic space group Ama2 with a=10.4793(1) Å, b=10.3610(2) Å, c=6.4015(1) Å, Z=4, R1=0.99% and wR2=2.37%. The structure type is that of SrCu2GeSe4. The structure can be described as a three-dimensional network built from near perfect SnS4 and distorted CuS4 tetrahedra together with EuS8 square antiprisms. The dark red compound is a semiconductor with an optical bandgap of 1.85 eV. 相似文献