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11.
Simple and convenient methods for determining surface chemical composition of lignocellulosic materials are described. The
methods are based on vapor phase fluorine surface derivatization with either trifluoro acetic anhydride (TFAA), tri-fluoro
ethanol (TFE) or pentafluorophenyl hydrazine (PFPH) and subsequent Electron Spectroscopy for Chemical Analysis (ESCA). Model
cellulosic surfaces with well defined functionalities were used to optimize the derivatization reaction conditions. Detection
and accessibility of surface hydroxyl functional groups were investigated in cotton and regenerated cellulose as models. Carboxymethyl
cellulose (CMC) was used as a model surface for detection and quantification of carboxylic acid groups. Theoretical conversion
curves for derivatization reactions were calculated and used to evaluate the extent of the reactions on the model surfaces.
It was found that the conversion was higher for the regenerated cellulose and CMC than for cotton. The protocols developed
using the model surfaces were applied to a case study on wood fibers with different degrees of complexity, namely dissolving
and chemithermomechanical (CTMP) pulp. Untreated and oxygen-plasma modified pulps were compared with respect to the surface
composition of functional groups. According to the derivatization reactions, functionalities containing oxygen were significantly
increased on the plasma-treated samples. The effect of the treatment was found to be dependent on the type of pulp. Fluorine
derivatization is shown to be an unambiguous method for clear assessment of the chemical functionalities of cellulosic surfaces. 相似文献
12.
İ. B. Özdemir 《Experiments in fluids》1997,22(4):271-280
This paper is concerned with an experimental investigation of the mixing inside the vortex ring formed by the gravity slumping
motion of a dense cloud in a less dense atmosphere. The dynamics of the spreading and instantaneous structures of the turbulent
flow were examined by visualization, single and multi-point measurements of velocity and concentration for two heavy gases,
carbondioxide (CO2) and dichlorodifluoromethane (CCl2F2), in a configuration in that heavy gas, initially trapped in a reservoir, was released with the rise of a shutter into calm
air of a sector-shaped dispersion channel.
Visualization of the cloud as a whole showed a spreading motion in which an advancing frontal structure was followed by a
stratified flow with a layer of dense fluid of higher velocities near the wall and, on top of it, a layer of dilute fluid
whose concentration is controlled by the mixing mechanisms within the head. During the course of spreading, there was always
a phase in which the head attained to a constant speed of advance, which occurred as 0.13 m/s for CO2 and 0.48 m/s for CCl2F2. It was interesting to observe for CO2 that the phase of constant speed took place in between two acceleration phases; the former was due to the initial slumping
of the cloud at the exit of the reservoir, and the latter was attributed to the collapse of the head on the transition to
the passive dispersion phase.
Instantaneous two-dimensional velocity field, measured with particle image velocimeter (PIV), showed that the cloud overran
the ambient air which caused the approaching dense fluid deflected away from the wall with significant vertical velocities
and downstream-moving separation, and the air trapped under the head resulted in the density inversion which introduced further
intricacy to the turbulent structure of the head. Instabilities at the upper free shear layer due to density and velocity
discontinuity rolled into periodic array of vortices which engulfed a considerable amount of air as they were convected backwards
over the head, but the incorporation of heavy and light fluids was completed with the appearance of microscales after the
collapse on the stratified layer. Analyses of the cloud head at different downstream locations also revealed that its size
remained unchanged when the speed of advance was constant, allowing the rate of change of the cloud volume being modeled with
the rate of spreading.
Contours of concentration obtained from digitized PIV pictures confirmed the kinematic features of the mixing revealed by
the velocity field and that the concentration values within the large structures were higher than those at the upper part
of the stratified layer. Motivated by the experimental observations, a semi-empirical analysis was presented to describe the
results and based on local values of the Richardson and Reynolds numbers.
Received: 4 October 1995 / Accepted: 4 July 1996 相似文献
13.
Solubility of carbon dioxide in aqueous solutions of sodium chloride: Experimental results and correlation 总被引:2,自引:0,他引:2
The solubility of carbon dioxide in aqueous solutions of sodium chloride was measured in the temperature range from 40 to 160°C, up to 6 mol-kg salt solutions and total pressures up to 10 MPa. Pitzer's(1) equations as well as the Chen and Evans(2) model were used to correlate the new data. Results are reported and compared to literature data and correlations. 相似文献
14.
Jonas Sderberg 《Journal of Algebra》2004,280(2):610-623
In order to use dualization to study Hilbert functions of artinian level algebras we extend the notion of level sequences and cancellable sequences, introduced by Geramita and Lorenzini, to include Hilbert functions of certain artinian modules. As in the case of algebras a level sequence is cancellable, but now by dualization its reverse is also cancellable which gives a new condition on level sequences. We also give a characterization of the cancellable sequences involving Macaulay representations. 相似文献
15.
This study compared the fracture strength of Class II slot cavities restored with polymerizable restorative materials. Sixty, caries-free, posterior teeth were divided into five groups of 12 teeth. The Class II slot cavities were prepared. The teeth were restored with two packable composites (Filtek P60, Surefil), a microhybrid composite (Filtek Z250)and two ormocer (Definite, Admira). The restorations were then subjected to fracture resistance tests. The marginal ridges of the restorations were loaded at an angle of 13.5° to the long axis of the tooth in an Universal Testing Machine until failure. Analysis of mean forces indicated that, Filtek P60, Surefil and Filtek Z250 exhibited better performance than Definite and Admira. The tested resin composites differed in their mechanical properties. This study suggested that fracture behavior were highly influenced by the filler system. Overall, Filtek P60, Surefil, Filtek Z250, demonstrated good fracture resistance. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
16.
In this work we display a numerical comparison, under statistical and computational point of view, between semi-analytical Eulerian and Lagrangian dispersion models to simulate the ground-level concentration values of a passive pollutant released from a low height source. The Eulerian approach is based on the solution of the advection–diffusion equation by the Laplace transform technique. The Lagrangian approach is based on solution of the Langevin equation through the Picard’s Iterative Method. Turbulence inputs are calculated according to a parameterization capable of generating continuous values in all stability conditions and in all heights of the Planetary Boundary Layer (PBL). Numerical simulations and comparisons show a good agreement between predicted and observed concentrations values. The comparison reveals the main advantages and disadvantages between the models. 相似文献
17.
This preliminary study presents the experimental results concerning the concentrations of selected radionuclides (238U, 232K, 226Ra, 232Th) in Af?in-Elbistan, Çan, Çay?rhan, Erzurum, Göynük, Kangal, Orhaneli, Saray, Seyitömer, Soma, Tunçbilek, Yata?an and Yeniköy lignites, which are primarily utilized as fuel for thermal power plants in Turkey. Gamma-spectrometry of 39 representative lignite samples gave results with the following concentration ranges: 8 to 296 Bq/kg for 238U, 3 to 79 Bq/kg for 232Th, 17 to 360 Bq/kg for 40K, and 5 to 130 Bq/kg for 226Ra. The 238U results reported here are higher than other literature values for various world coals, earth's crust and world average. 相似文献
18.
19.
G. Buchbauer H. Spreitzer B. Öckher C. Pretterklieber I. Piringer P. Wolschann 《Monatshefte für Chemie / Chemical Monthly》1995,126(4):467-472
Summary Guided by molecular modeling studies, the synthesis of the title compound is described. The organoleptic evaluation proved the predicted real sandal like odour of (Z)-dehydro-homo--santalol.
Aus den Diplomarbeiten von C.P. (1991), I.P. und B.Ö. (1992), Universität Wien 相似文献
20.
The reaction of dimethyldiaryltin reagents Me(2)SnR(2) (R = Ph (1), p-MePh (2), m,m-Me(2)Ph (3), p-(t)BuPh (4), p-MeOPh (5), p-CF(3)Ph (6)) with BCl(3) provided a high-yielding, simple preparative route to the corresponding diarylchloroboranes R(2)BCl (R = Ph (10), p-MePh (11), m,m-Me(2)Ph (12), p-(t)BuPh (13), p-MeOPh (14), p-CF(3)Ph (15)). In some cases, the desired diarylchloroborane was not formed from an appropriate tin reagent Me(2)SnR(2) (R = o-MeOPh (7), o,o-(MeO)(2)Ph (8), o-CF(3)Ph (9)). The reaction of lithiated methyldiaryl- or methyldialkylphosphines with diarylchloroboranes or dialkylchloroboranes is discussed. Specifically, several new monoanionic bis(phosphino)borates are detailed: [Ph(2)B(CH(2)PPh(2))(2)] (25); [(p-MePh)(2)B(CH(2)PPh(2))(2)] (26); [(p-(t)BuPh)(2)B(CH(2)PPh(2))(2)] (27); [(p-MeOPh)(2)B(CH(2)PPh(2))(2)] (28); [(p-CF(3)Ph)(2)B(CH(2)PPh(2))(2)] (29); [Cy(2)B(CH(2)PPh(2))(2)] (30); [Ph(2)B(CH(2)P[p-(t)BuPh](2))(2)] (31); [(p-MeOPh)(2)B(CH(2)P[p-(t)BuPh](2))(2)] (32); [Ph(2)B(CH(2)P[p-CF(3)Ph](2))(2)] (33); [Ph(2)B(CH(2)P(BH(3))(Me)(2))(2)] (34); [Ph(2)B(CH(2)P(S)(Me)(2))(2)] (35); [Ph(2)B(CH(2)P(i)Pr(2))(2)] (36); [Ph(2)B(CH(2)P(t)Bu(2))(2)] (37); [(m,m-Me(2)Ph)(2)B(CH(2)P(t)Bu(2))(2)] (38). The chelation of diarylphosphine derivatives 25-33 and 36 to platinum was examined by generation of a series of platinum dimethyl complexes. The electronic effects of substituted bis(phosphino)borates on the carbonyl stretching frequency of neutral platinum alkyl carbonyl complexes were studied by infrared spectroscopy. Substituents remote from the metal center (i.e. on boron) have minimal effect on the electronic nature of the metal center, whereas substitution close to the metal center (on phosphorus) has a greater effect on the electronic nature of the metal center. 相似文献