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1.
Martin Kellert Jan-Simon Jeshua Friedrichs Nadine Anke Ullrich Alexander Feinhals Jonas Tepper Peter Lnnecke Evamarie Hey-Hawkins 《Molecules (Basel, Switzerland)》2021,26(7)
The development of novel, tumor-selective and boron-rich compounds as potential agents for use in boron neutron capture therapy (BNCT) represents a very important field in cancer treatment by radiation therapy. Here, we report the design and synthesis of two promising compounds that combine meta-carborane, a water-soluble monosaccharide and a linking unit, namely glycine or ethylenediamine, for facile coupling with various tumor-selective biomolecules bearing a free amino or carboxylic acid group. In this work, coupling experiments with two selected biomolecules, a coumarin derivative and folic acid, were included. The task of every component in this approach was carefully chosen: the carborane moiety supplies ten boron atoms, which is a tenfold increase in boron content compared to the l-boronophenylalanine (l-BPA) presently used in BNCT; the sugar moiety compensates for the hydrophobic character of the carborane; the linking unit, depending on the chosen biomolecule, acts as the connection between the tumor-selective component and the boron-rich moiety; and the respective tumor-selective biomolecule provides the necessary selectivity. This approach makes it possible to develop a modular and feasible strategy for the synthesis of readily obtainable boron-rich agents with optimized properties for potential applications in BNCT. 相似文献
2.
3.
We present some classical solutions to a gauge theory based on quadratically nonlinear Lie algebras without a central term. We observe that instanton-like and meron-like solutions force the internal fields to behave like solitons. 相似文献
4.
Mustafa Çelebier Ertan Şahin Nilgün Ancın Nurşen Altuntaş Öztaş Selma Gül Öztaş 《应用有机金属化学》2007,21(10):viii-viii
The article referenced above was first published online on 30 August 2007 with incorrect pagination; the pagination has now been corrected online and in print. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
5.
Bahattin Gümgüm Nermin Biricik Feyyaz Durap Ismail Özdemir Nevin Gürbüz Wee Han Ang Paul J. Dyson 《应用有机金属化学》2007,21(8):711-715
Palladium(II) complexes with N,N‐bis(diphenylphosphino)aniline ligands catalyse the Heck reaction between styrene and aryl bromides, affording stilbenes in good yield. The structures of two of the complexes used as pre‐catalysts have been determined by single‐crystal X‐ray diffraction. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
6.
E. I. Ölmez D. Kut A. N. Bilge I. Ölmez 《Journal of Radioanalytical and Nuclear Chemistry》2004,259(2):227-231
In ambient air, arsenic to selenium ratio (As/Se) is generally found to be less than 1, except in areas influenced by specific
point sources, such as Cu smelters. However, the annual average of this ratio is found to be much higher than unity in Turkey.
This finding is rather unique and may provide a marker for air masses influenced by the coal-related emissions in Turkey.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
7.
Örn Helgason Haraldur P. Gunnlaugsson Siguröur Steinthorsson Steen Mørup 《Hyperfine Interactions》1992,70(1-4):981-984
Mössbauer spectroscopy of basalt lava samples, exhibiting reversible thermal magnetization (JS-T) curves with Curie temperatures of about 580°C, has revealed considerable amounts of maghemite (γ-Fe2O3) in many samples. In view of the expected instability, of maghemite at temperatures above 350°C, this reversibility is rather surprising. Here we report Mössbauer studies on heated lava samples, showing high content of maghemite. The samples were kept at 600°C in oxidizing, reducing, and inactive atmospheres, respectively, for different lengths of time, and then analyzed with Mössbauer spectroscopy at room temperature. The Mössbauer spectra showed that maghemite is stable in the oxidizing atmosphere for at least several hours. In the inactive atmosphere a considerable amount of maghemite still exists after two hours heating. In the reducing atmosphere maghemite had transformed to magnetite after only 30 minutes. 相似文献
8.
We consider a multiperiod mean-variance model where the model parameters change according to a stochastic market. The mean
vector and covariance matrix of the random returns of risky assets all depend on the state of the market during any period
where the market process is assumed to follow a Markov chain. Dynamic programming is used to solve an auxiliary problem which,
in turn, gives the efficient frontier of the mean-variance formulation. An explicit expression is obtained for the efficient
frontier and an illustrative example is given to demonstrate the application of the procedure. 相似文献
9.
In this paper, it is shown that some of the results of torus actions on Poincaré duality spaces, Borel’s dimension formula
and topological splitting principle to local weights, hold if ‘torus’ is replaced by ‘pro-torus’. 相似文献
10.
The pressure dependence of the experimental 7Li NMR spectra is reported for first stage lithium graphite (LiC6) intercalation compound at temperatures T = 232 and 293 K. This experiment together with the presented point charge model calculation of the 7Li quadrupole coupling constant allows an unambiguous determination of the sign of e2qQ/h which is negative: at p = 1 bar and T = 232 K. The averaged location of the electrons transferred from the Li intercalant to the graphite layers, as estimated in this study, is in excellent agreement with earlier theoretical energy-band calculations. The compressibility of LiC6 in the c-direction is predicted to be kc = 1.7 × 10-12cm2dyn-1, it agrees with estimates derived from the available phonon dispersion relations. 相似文献