Preliminary results of MCPHE by experimental studies

The influence of grooves in the U-turn areas for the multi-channel-plate heat exchangers (MCPHEs) is significant due to the friction and flow phenomena in this region. In this study, two types of MCPHE made of acrylic plates were tested: one with grooves in the U-turn area, one without. During this series of experiments, heat transfer rate, overall volumetric heat transfer coefficient, Nusselt number and overall pressure drop (i.e., including the entrance and exit losses) were measured and calculated in order to understand the overall performance of these two different constructions of MCPHE. The experimental results show that the heat exchanger without grooves in the U-turn area possessed higher heat transfer performance and lower overall pressure drop.     

A constitutive relation for pseudo-elastic behaviour in shape memory alloys

A constitutive relation to describe pseudo-elastic deformation in shape memory alloys is presented in this paper. It is capable of describing deformation behaviour of polycrystalline materials under triaxial stress state as well as of monocrystalline materials under one-dimensional condition. Total strain rate is supposed to be composed of elastic strain rate and transformation strain rate. Deformation behaviour of Cu−Zn−Sn alloy and Ti−ni alloy is simulated by use of the proposed constitutive relation. it is shown that simulated results are in a good agreement with experimental data. The project supported by National Natural Science Foundation of China.     

Full-field Measurement of Topography and Curvature by Coherent Gradient Sensing Method at High Temperature

Coherent gradient sensing (CGS) method, a real time, full-field optical technique, is insensitive to vibrations and able to provide slope and curvature maps and surface topographies, to investigate non-uniform deformations. In this paper, we analyze the thermal effects on the optical path in CGS due to air convection, and the influence of grating thickness and refractive index on the measurement accuracy. A modified governing equation is derived considering the grating thickness, which is demonstrated by testing a standard sample. Finally, we apply CGS method to measure the full-field deformation of a specimen at high temperature.     

Poly(vinylpyrrolidone)-modified graphite carbon nanofibers as promising supports for PtRu catalysts in direct methanol fuel cells

Carbon nanomaterials, including herringbone graphite carbon nanofibers (GNFH), multiwalled carbon nanotubes (MWCNT), and carbon black, were surface-modified by a new poly(vinylpyrrolidone) (PVP) grafting process as well as by the conventional acid-oxidation (AO) process, and characterized by FTIR, TGA, Raman, HRTEM, XRD, and XPS measurements. Pt nanoparticles of 1.8 nm were evenly deposited on all PVP-grafted carbon nanomaterials. The effects of the two surface modification processes on the dispersion, average Pt nanoparticle sizes, the electrocatalytic performance, and electrical conductivities of Pt-carbon nanocomposites in direct methanol oxidation were systematically studied and compared. It was found that the PVP-grafted carbon nanomaterials have much less loss in the electric conductivity and thus better electrocatalytic performance, 17-463% higher, than their corresponding acid oxidation-treated nanocomposites. The electrocatalytic performance of the Pt-carbon nanocomposites decreases in the following order: Pt-PVP-GNFH > Pt-PVP-MWCNTarc > Pt-AO-MWCNTarc > Pt-PVP-MWCNTCVD > Pt-AO-MWCNTCVD > Pt-XC-72R > Pt-AO-GNFH, with the Pt-PVP-GNFH nanocomposite having approximately 270% higher performance than that of the Pt-Vulcan XC-72R nanocomposite. In addition, PtRu-PVP-GNFH shows even better (50% higher) electrocatalytic activity than the Pt-PVP-GNFH nanocomposite at a 0.6 V applied voltage.     

Branched poly(1,4‐butylene carbonate‐co‐terephthalate)s: LDPE‐like semicrystalline thermoplastics

Branched poly[1,4‐butylene carbonate‐co‐terephthalate]s (PBCTs) have been synthesized by the addition of a small amount of glycerol propoxylate ( 1 ) or pentaerythritol ( 2 ) in the polycondensation of 1,4‐butanediol, dimethyl carbonate, and dimethyl terephthalate. To avoid gel formation, the feed amount of 1 or 2 was carefully controlled at below 0.5 mol % for 1 and below 0.3 mol % for 2 . When feed of 1 or 2 was used, a high‐molecular weight melt state (M_w ～180,000 g/mol) was reached in a total reaction time of 5.5 to 6.5 h with a yield higher than 90%. The generated PBCTs were a semicrystalline polymer (T_g ～5 °C and T_m ～120 °C) when the terephthalate content (F_[TPA]) was 45 to 50 mol %. The crystallization rate increased with increasing F_[TPA] and branch content (F_{[ 1 or 2 ]}); PBCT composed of F_[TPA] = 49 mol % and F_{[ 1 ]} = 0.44 mol % was crystallized completely in a short time, ～3 min, at a crystallization temperature of 50 °C. The branched PBCT exhibited more pronounced toughness in tensile test while providing the advantage of processibility at high shear rates due to the pronounced shear thinning in melt. It was also found that the branched PBCTs were biodegradable. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 914–923     

A unified energy approach to a class of micromechanics models for composite materials

Several micromechanics models for the determination of composite moduli are investigated in this paper, including the dilute solution, self-consistent method, generalized self-consistent method, and Mori-Tanaka's method. These micromechanical models have been developed by following quite different approaches and physical interpretations. It is shown that all the micromechanics models share a common ground, the generalized Budiansky's energy-equivalence framework. The difference among the various models is shown to be the way in which the average strain of the inclusion phase is evaluated. As a bonus of this theoretical development, the asymmetry suffered in Mori-Tanaka's method can be circumvented and the applicability of the generalized self-consistent method can be extended to materials containing microcracks, multiphase inclusions, non-spherical inclusions, or non-cylindrical inclusions. The relevance to the differential method, double-inclusion model, and Hashin-Shtrikman bounds is also discussed. The application of these micromechanics models to particulate-reinforced composites and microcracked solids is reviewed and some new results are presented.     

Functional Limit Theorems for d-dimensional FBM in HSlder Norm

In this paper, we obtain functional limit theorems for d-dimensional FBM in HSlder norm via estimating large deviation probabilities for d-dimensional FBM in HSlder norm.