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11.
Krishna Dan Priya Rajdev Jolly Deb Siddhartha S. Jana Suhrit Ghosh 《Journal of polymer science. Part A, Polymer chemistry》2013,51(22):4932-4943
Synthesis of a library of amphiphilic random copolymers from a single reactive pre‐polymer and their self‐assembly is reported. Post‐polymerization modifications of the parent polymer containing pendant N‐hydroxy succinimide (NHS) ester groups with various oligooxyethylene (OE) amines produce amphiphilic random copolymers with same degree of polymerization and equal extent of randomness. 1H‐NMR and FT‐IR data indicate quantitative substitution in all cases. The critical aggregation concentration (CAC) for all the polymers is estimated to be in the range of 10?5 M. Stability of these nano‐aggregates is studied by photoluminescence using time dependent F—rster Resonance Energy Transfer (FRET) between co‐encapsulated lipophilic dyes namely DiO and DiI in the hydrophobic pocket of the aggregates. These studies suggest remarkably high stability for all systems. However those with shorter hydrophilic pendant chains are found to be even more robust. Morphology is examined by high resolution transmission electron microscopy (HRTEM) which reveals multi‐micellar clusters and vesicles for polymers containing short and longer OE segments, respectively. Encapsulation efficacy is tested with both hydrophobic and hydrophilic guest molecules. All of them can encapsulate hydrophobic guest pyrene while a hydrophilic dye Calcein can be sequestered only in vesicle forming polymers. Lower critical solution temperature (LCST) is exhibited by only one polymer that contains the shortest OE chains. All polymers exhibit excellent cell viability as determined by MTT assay. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 4932–4943 相似文献
12.
Anthony Jolly Dandan Miao Maxime Daigle Prof. Dr. Jean-François Morin 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(12):4652-4661
The solution-phase synthesis is one of the most promising strategies for the preparation of well-defined graphene nanoribbons (GNRs) in large scale. To prepare high quality, defect-free GNRs, cycloaromatization reactions need to be very efficient, proceed without side reaction and mild enough to accommodate the presence of various functional groups. In this Minireview, we present the latest synthetic approaches for the synthesis of GNRs and related structures, including alkyne benzannulation, photochemical cyclodehydrohalogenation, Mallory and Pd- and Ni-catalyzed reactions. 相似文献
13.
Winfield B. Perry William L. Jolly 《Journal of Electron Spectroscopy and Related Phenomena》1974,4(3):219-232
X-ray photoelectron spectra in the valence electron region were obtained for gaseous SiH4, SiH3CH3, Si(CH3)4, SiH3Cl, and SiF4. The experimental ionization potentials and relative peak intensities are consistent with extended Hückel theory MO calculations. The data can be rationalized without assuming substantial participation of silicon d orbitals in the bonding of these compounds. 相似文献
14.
The long-time behavior of the incompressible Navier-Stokes equations on a 2-torus is computed using several discretizations in space and in time. We compare several nonlinear Galerkin methods (NGMs) with the standard Galerkin method (SGM) in both their ability to capture the dynamic and geometric behavior of a turbulent flow accurately, and the computational efficiency with which they are solved using variable time-step integration schemes. To measure the convergence of the chaotic attractor we employ Poincaré section plots as well as density functions of instantaneous Lyapunov exponents. As expected, for the smooth (single mode) force used, the NGMs fare no better than the SGM in reproducing the correct behavior. As the number of modes for each method is increased, however, a distinct advantage in computational cost emerges for the NGMs. This trend suggests that the correct solution may be computed at considerable savings for a nonsmooth force, at higher Reynolds numbers.This work was supported in part by the U.S. Department of Energy under Grant No. DE-FG02-92ER25120, and by the U.S. Office of Naval Research under Grant No. N00014-91-J-1140. Computations were mainly performed on the Gray Y-MP at the Ohio Supercomputer Center under project PAS620. Those on the CM-200 were carried out with resources supported in part by the Army Research Office contract with the University of Minnesota Army High Performance Computing Research Center. 相似文献
15.
Static and synchronized switching noise management of replicated optical pulse trains 总被引:1,自引:0,他引:1
Demonstration is provided for the generation of high quality replicated optical pulse trains, from a single pulse. This uses the storage capability of an electro-optically switched recirculating fibre loop. For better understanding, the first step involves the development of general purpose derivations related to the evolution of the noise with near-unity loop gains. This is a basic tool to evaluate the propagation of the noise and the temporal evolution of the signal to noise ratio during the replication process. In a second step, the comparison of theoretical and experimental results will be shown to evidence good agreement, up to more than 1000 replica. Finally, experiments are performed on synchronised gain-switching inside the loop to help optimise the dynamic range of replication at the output of the system. 相似文献
16.
We study third harmonic generation in layered configuration when the fundamental exhibits bistable response. We consider two
geometries, namely, a Fabry-Perot cavity with reflection coatings and a distributed feedback structure with alternate nonlinear
layers. In both the cases for suitable choice of frequency, the power response at the fundamental frequency is bistable. We
show that bistability of the fundamental leads to a multivalued character of the generated third harmonic in both the forward
and backward directions. Moreover, we study frequency response in the case of the Fabry-Perot cavity and show that additional
structures arise in the generated third harmonic due to frequency bistability of the fundamental. Our calculations suggest
the possibility of an all optical switch at third harmonic frequency controlled by the parameters (like intensity, frequency)
of the fundamental. 相似文献
17.
We study a doubly resonant optical parametric oscillator where the pump can feed two pairs of signal-idler modes. We assume
the presence of gain at the pump frequency. We investigate the various oscillation states of interest, namely, when only the
first pair oscillates with the other pair having null amplitudes and vice versa. We demonstrate the exchange of dynamics between
the mode pairs when the relevant parameters of the cavity, namely, the phase mismatch factors or the decay rates switch because
of fluctuations. The exchange of dynamics is shown to be independent of the nature of dynamics, i.e. independent of whether
the motion isn-periodic or chaotic. We also investigate the case where both the pairs can exhibit chaotic dynamics though these states are
difficult to realize because of fluctuations. 相似文献
18.
Previous numerical simulation of the vibrational relaxation of highly excited bromine in argon at different pressures is here extended in several ways. 相似文献
19.
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