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41.
Kaishuo Yang Ehsan Sadeghi Pouya Libin Liu Dr. Ming Li Dr. Xiaoxian Yang Dr. Neil Robinson Prof. Eric F. May Prof. Michael L. Johns 《Chemphyschem》2022,23(4):e202100794
Understanding the behaviour of short-chain hydrocarbons confined to porous solids informs the targeted extraction of natural resources from geological features, and underpins rational developments in separation, storage and catalytic conversion processes. Herein, we report the application of low-field (12.7 MHz) 1H nuclear magnetic resonance (NMR) relaxation measurements to characterise ethane dynamics within mesoporous silica materials exhibiting mean pore diameters between 6 and 50 nm. Our measurements provide NMR-based adsorption isotherms within the range 25–50 bar and at ambient temperature, incorporating the ethane condensation point (40.7 bar at our experimental temperature of 23.6 °C). The quantitative nature of the acquired data is validated via a direct comparison of NMR-derived excess adsorption capacities with ex situ gravimetric ethane adsorption measurements, which are demonstrated to agree to within 0.2 mmol g−1 of the observed ethane capacity. NMR relaxation time distributions are further demonstrated as a means to decouple interparticle and mesopore dominated adsorption phenomena, with unexpectedly rapid relaxation rates associated with interparticle ethane gas confirmed via a direct comparison with NMR self-diffusion analysis. 相似文献
42.
Mahmoud Mollabashi R. M. Lees J. W. C. Johns 《International Journal of Infrared and Millimeter Waves》1993,14(9):1727-1753
The Fourier transform far-infrared (FTFIR) spectrum of CD3OH has been obtained from 40–220 cm–1 at a resolution of 0.002 cm–1, and partially analyzed. Numerousb-type branches have been assigned in the spectrum, ranging over torsional states fromn=0 to 3. The branches have been fitted toJ(J+1) power-series energy expansions in order to obtainJ-independent branch origins. These in turn have been fitted to the torsion-rotation Hamiltonian, and improved molecular constants have been obtained for the ground vibrational state. 相似文献
43.
Abstract— Evidence is presented for the formation of a thymine hydrate upon ultraviolet (UV) or gamma irradiation of aqueous solutions. The UV quantum efficiency exhibits a dependence on pH similar to that shown for uracil hydration, but the yield is three orders of magnitude smaller than for uracil. Hydration is not affected by wavelength, oxygen, or concentration of thymine. The reversal rate of the photohydrate to thymine is similar to the reversal rates of both isomers of the thymine hydrate formed by γ radiolysis, and depends on pH in the same way as the rate for the uracil photohydrate. The photohydrate of thymine is chromatographically identical to the cis isomer of 6-hydroxy-5, 6-dihydrothymine. 相似文献
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45.
C. Bréchignac J.W.C. Johns A.R.W. McKellar M. Wong 《Journal of Molecular Spectroscopy》1982,96(2):353-361
The ν2 fundamental band of H2CO has been studied using a combination of sub-Doppler laser Stark spectroscopy and Doppler-limited Fourier transform spectroscopy. A combined analysis of the Stark and Fourier infrared data together with previous microwave data on the ν2 = 1 state yielded improved molecular parameters for formaldehyde, including the excited state dipole moment. A small perturbation was noted at K′a = 7 which may be ascribed to a ΔKa = 2 interaction with the v3 = 1 state. Precise treatments of ν2 with K′a > 6 will thus require a combined analysis taking into account Coriolis interactions among ν4, ν6, ν3, and ν2. 相似文献
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47.
Synthesis and reactions of 5 ,8-epidioxyandrost-6-enes 总被引:1,自引:0,他引:1
W F Johns 《The Journal of organic chemistry》1971,36(17):2391-2397
48.
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B. Johns 《国际流体数值方法杂志》1982,2(3):253-261
A finite-difference method is described for the numerical integration of the one-dimensional shallow water equations over a sloping shelf that allows for a continuously moving shoreline. An application of the technique is made to the propagation of non-breaking waves towards the shoreline. The results of the computation are compared with an evaluation based upon an exact analytical treatment of the non-linear equations. Excellent agreement is found for both tsunami and tidal scale oscillations. 相似文献
50.