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51.
A potential of mean torque is derived for a solute at infinite dilution in a uniaxial liquid crystal solvent, which contains terms originating from the dispersion interaction, and the electrostatic interaction between quadrupole moments on both molecules. It is shown that the electrostatic term is non-zero only if the solute-solvent vectors are distributed with lower than spherical symmetry. If this distribution has cylindrical symmetry then both the electrostatic and dispersion terms in the potential of mean torque are shown to depend on order parameters for the orientational distribution of the solute-solvent vectors, as well as on the order parameters of the solvent molecules. 相似文献
52.
The temperature dependence of the principal values of the refractive index in Sr1−x
CaxTiO3 (x=0.014) has been measured in the 17–275 K range under various conditions of sample illumination with 1.96 eV photons. The
spontaneous photorefractive contribution δn
ph to the temperature-induced variation of the refractive index of Sr1−x
CaxTiO3, which appears after illumination of the sample in the ferrophase (transition temperature T
c=32 K) and persists in the paraphase under heating up to 150 K, has been separated. The photoinduced polarization has been
estimated.
Fiz. Tverd. Tela (St. Petersburg) 39, 711–713 (April 1997) 相似文献
53.
C. Ziegler F. Baudenbacher H. Karl H. Kinder W. Göpel 《Fresenius' Journal of Analytical Chemistry》1991,341(3-4):308-313
Summary The influence of different preparation conditions and substrate surface orientations on the superconducting properties of thin YBa2Cu3O7–x (YBCO) films on silicon was studied. Comparative electrical and surface spectroscopic measurements were performed. SAM and SIMS depth profile analysis show an enrichment of barium at the interface between the superconductor and silicon for samples with Tc<76 K. Comparison with XPS data obtained for thin silicon films on YBCO indicates the formation of barium and yttrium silicates at the interface under these conditions. 相似文献
54.
W.G. Schmidt 《Applied Physics A: Materials Science & Processing》2002,75(1):89-99
There has been renewed interest in the structure of III-V compound semiconductor (001) surfaces caused by recent experimental
and theoretical findings, which indicate that geometries different from the seemingly well-established dimer models describe
the surface ground state for specific preparation conditions. I review briefly the structure information available on the
(001) surfaces of GaP, InP, GaAs and InAs. These data are complemented with first-principles total-energy calculations. The
calculated surface phase diagrams are used to explain the experimental data and reveal that the stability of specific surface
structures depends largely on the relative size of the surface constituents. Several structural models for the Ga-rich GaAs (001)(4×6)
surface are discussed, but dismissed on energetic grounds. I discuss in some detail the electronic properties of the recently
proposed cation-rich GaAs (001)ζ(4×2) geometry.
Received: 18 May 2001 / Revised version: 23 July 2001 / Published online: 3 April 2002 相似文献
55.
In this paper we analyse numerical models for time-dependent Boussinesq equations. These equations arise when so-called Boussinesq terms are introduced into the shallow water equations. We use the Boussinesq terms proposed by Katapodes and Dingemans. These terms generalize the constant depth terms given by Broer. The shallow water equations are discretized by using fourth-order finite difference formulae for the space derivatives and a fourth-order explicit time integrator. The effect on the stability and accuracy of various discrete Boussinesq terms is investigated. Numerical experiments are presented in the case of a fourth-order Runge-Kutta time integrator. 相似文献
56.
57.
Scott T. Knauert Jack F. Douglas Francis W. Starr 《Journal of Polymer Science.Polymer Physics》2007,45(14):1882-1897
Nanoparticles can influence the properties of polymer materials by a variety of mechanisms. With fullerene, carbon nanotube, and clay or graphene sheet nanocomposites in mind, we investigate how particle shape influences the melt shear viscosity η and the tensile strength τ, which we determine via molecular dynamics simulations. Our simulations of compact (icosahedral), tube or rod‐like, and sheet‐like model nanoparticles, all at a volume fraction ? ≈ 0.05, indicate an order of magnitude increase in the viscosity η relative to the pure melt. This finding evidently can not be explained by continuum hydrodynamics and we provide evidence that the η increase in our model nanocomposites has its origin in chain bridging between the nanoparticles. We find that this increase is the largest for the rod‐like nanoparticles and least for the sheet‐like nanoparticles. Curiously, the enhancements of η and τ exhibit opposite trends with increasing chain length N and with particle shape anisotropy. Evidently, the concept of bridging chains alone cannot account for the increase in τ and we suggest that the deformability or flexibility of the sheet nanoparticles contributes to nanocomposite strength and toughness by reducing the relative value of the Poisson ratio of the composite. The molecular dynamics simulations in the present work focus on the reference case where the modification of the melt structure associated with glass‐formation and entanglement interactions should not be an issue. Since many applications require good particle dispersion, we also focus on the case where the polymer‐particle interactions favor nanoparticle dispersion. Our simulations point to a substantial contribution of nanoparticle shape to both mechanical and processing properties of polymer nanocomposites. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1882–1897, 2007 相似文献
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