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151.
Abstract— The concentration of Escherichia coli in the input and output of a tertiary wastewater system (4 lagoons) has been monitored over an 11 month period. The integrated flux of biologically active solar ultraviolet (UV) radiation was measured during this period. By also determining (1) the effective temperature in the system, (2) the growth rate of E. coli at the effective temperature, (3) the penetration of the solar UV into the lagoons, (4) the dose-response relation for killing of E. coli by UV and (5) the retention time of water in the system, it is possible to compare the 'die off' expected from solar UV exposure to the actual 'die off' observed for different batches of water.
The observed killing of E. coli was quite close to the values calculated, considering the numerous factors involved. Solar UV light would thus seem to be a very important factor in the natural purification of water. Because each successful species must possess characteristics (physiological or behavioral) which provide adequate resistance to solar UV, the ecological role of solar UV radiation has not been widely appreciated. 相似文献
The observed killing of E. coli was quite close to the values calculated, considering the numerous factors involved. Solar UV light would thus seem to be a very important factor in the natural purification of water. Because each successful species must possess characteristics (physiological or behavioral) which provide adequate resistance to solar UV, the ecological role of solar UV radiation has not been widely appreciated. 相似文献
152.
153.
Kommareddi Nagesh S. Tata Murthy Karayigitoglu Cigdem John Vijay T. McPherson Gary L. Herman Michael F. O'Connor Charles J. Lee Young-Sook Akkara Joseph A. Kaplan David L. 《Applied biochemistry and biotechnology》1995,51(1):241-252
Applied Biochemistry and Biotechnology - Horseradish peroxidase has been used as a biocatalyst to synthesize a polymeric material from alkyl-substituted phenols. The synthesis is carried out in a... 相似文献
154.
Modeling Studies of the Formation and Destruction of NO in Pulsed Barrier Discharges in Nitrogen and Air 总被引:1,自引:0,他引:1
This paper presents the results of modeling studies on the formation and destruction of NO in pulsed barrier discharges in nitrogen and air. The goals of this work are to identify the major processes involved in the formation and destruction of NO in air discharges, to distinguish between oxidative and reductive paths for NO destruction, to explore the potential importance of excited state reactions, to evaluate the role of water in such systems, and to identify the final products in the absence of heterogeneous processes. In all cases, the systems were modeled with 100×10–4% (100 ppm) of added NO, with and without 3% added water. The focus in all of this work is chemistry in the post-pulse regime. 相似文献
155.
Abstract— The triplet state spectra of anaerobically grown cells of Rhodopseudomonas sphaeroides GIC and R. sphaeroides wild type and aerobically grown cells of R. sphaeroides wild type were examined under reducing and non-reducing conditions at 100 K. by electron paramagnetic resonance (EPR). Large differences in the zero field splitting parameters, |D| and |E| of the triplets are seen to arise in the different preparations. The spectra are assigned to the triplet states of carotenoids, some of which are closely associated with the reaction center and others are contained in the light harvesting complex. Taken together with the triplet state data on Rhodospirillum rubrum wild type previously published the trends in the zero field splitting parameters can be understood in terms of the extent of electron derealization in carotenoids of varying length. 相似文献
156.
157.
A new approach to the evaluation of two-electron repulsion integrals over contracted Gaussian basis functions is developed. The new scheme encompasses 20 distinct, but interrelated, paths from simple shell-quartet parameters to the target integrals, and, for any given integral class, the path requiring the fewest floating-point operations (FLOPS ) is that used. Both theoretical (FLOP counting) and practical (CPU timing) measures indicate that the method represents a substantial improvement over the HGP algorithm. 相似文献
158.
[reaction: see text] The photochemistry of N-acyl-5,7-dinitroindoline (1) was studied in acetonitrile using nanosecond time-resolved infrared (TRIR) spectroscopy. Upon photolysis, two nearly but not completely overlapping sets of transient IR bands are observed that are assigned to two non-interconvertible conformers of mixed acetic nitronic anhydride 7. While syn-7 reverts rapidly to 1, anti-7 is long-lived and is able to acylate amines. Results of density functional theory calculations support conclusions based on experimental TRIR data. 相似文献
159.
Xilin Ren Chingkuang Tu Deepa Bhatt J. Jefferson P. Perry John A. Tainer Diane E. Cabelli David N. Silverman 《Journal of Molecular Structure》2006,790(1-3):168-173
Incorporation of 3-fluorotyrosine and site-specific mutagenesis have been used with stopped-flow spectrophotometry and pulse radiolysis to investigate the catalytic properties of human manganese superoxide dismutase (MnSOD). All of the nine tyrosine residues in each of the four subunits of the homotetramer of human MnSOD were replaced with 3-fluorotyrosine. Previous studies showed that the crystal structures of the unfluorinated and fluorinated human MnSOD are nearly superimposable with the root-mean-square deviation for 198 -carbon atoms at 0.3 Å. However, the catalytic activity kcat/Km of the fluorinated MnSOD at 30 μM−1 s−1 was less than unfluorinated wild type at 800 μM−1 s−1. Comparison of the values of kcat/Km for fluorinated and unfluorinated wild-type andY34F MnSOD showed that this decrease for the fluorinated enzyme was in significant part due to 3-fluorotyrosine residues distant (>7 Å) from the active-site metal, not to 3-fluorotyrosine at position 34 close (5 Å) to the metal. Although many rate constants for the catalysis are decreased by this fluorination, the rate of dissociation of the product-inhibited complex appears unchanged by the presence of fluorinated tyrosines. These results suggest that Tyr34 is not a proton donor in the release of the product-inhibited complex, which involves protonation of a peroxo complex of the metal with release of hydrogen peroxide. 相似文献
160.