Spectrofluorimetric determination of formaldehyde in maple syrup

A quick and simple method was developed for determination of formaldehyde in maple syrup. In this method, formaldehyde reacts with Fluoral P to form a complex which is chemically extracted by isobutanol and determined by spectrofluorimetry. Performance, as gauged by the limits of detection (0.16 mg/kg) and quantitation (0.21 mg/kg), recovery (>79%), and variability (1.9-16.1%, depending on fortification level and class of syrup) were superior to the current official AOAC standard method.     

Stereoselective intermolecular carboazidation of chiral allylsilanes

[reaction: see text] Easily available chiral allylsilanes were used as substrate for carboazidation reactions. For the first time, a substantial control of the stereochemistry of the azidation of acyclic nonconjugated radicals was achieved.     

Thin-layer chromatography of green leaves extracts: Zinc migrates into pheophytin on TLC silica plates with fluorescence indicator (F254)

JPC – Journal of Planar Chromatography – Modern TLC -     

Quasi-total omnidirectional light absorption in nanostructured gold films

A series of experiments and simulations have been performed to evidence the omnidirectional light absorption of planar gold structures containing a two-dimensional lattice of spherical beads or pores. We show that more than 90 % of incident light is absorbed at angles of incidence up to 65° for optimum values of the gold film thickness. We also report the tunability of the absorption wavelength by varying the size of the beads/pores.     

An Insurance Risk Model with Parisian Implementation Delays

We consider a similar variant of the event ruin for a Lévy insurance risk process as in Czarna and Palmowski (J Appl Probab 48(4):984–1002, 2011) and Loeffen et al. (to appear, 2011) when the surplus process is allowed to spend time under a pre-specified default level before ruin is recognized. In these two articles, the ruin probability is examined when deterministic implementation delays are allowed. In this paper, we propose to capitalize on the idea of randomization and thus assume these delays are of a mixed Erlang nature. Together with the analytical interest of this problem, we will show through the development of new methodological tools that these stochastic delays lead to more explicit and computable results for various ruin-related quantities than their deterministic counterparts. Using the modern language of scale functions, we study the Laplace transform of this so-called Parisian time to ruin in an insurance risk model driven by a spectrally negative Lévy process of bounded variation. In the process, a generalization of the two-sided exit problem for this class of processes is further obtained.     

Relief distribution networks: a systematic review

In the last 20 years, Emergency Management has received increasing attention from the scientific community. Meanwhile, the study of relief distribution networks has become one of the most popular topics within the Emergency Management field. In fact, the number and variety of contributions devoted to the design or the management of relief distribution networks has exploded in the recent years, motivating the need for a structured and systematic analysis of the works on this specific topic. To this end, this paper presents a systematic review of contributions on relief distribution networks in response to disasters. Through a systematic and scientific methodology, it gathers and consolidates the published research works in a transparent and objective way. It pursues three goals. First, to conduct an up-to-date survey of the research in relief distribution networks focusing on the logistics aspects of the problem, which despite the number of previous reviews has been overlooked in the past. Second, to highlight the trends and the most promising challenges in the modeling and resolution approaches and, finally, to identify future research perspectives that need to be explored.     

Radical chain reduction of alkylboron compounds with catechols

The conversion of alkylboranes to the corresponding alkanes is classically per-formed via protonolysis of alkylboranes. This simple reaction requires the use of severe reaction conditions, that is, treatment with a carboxylic acid at high temperature (>150 °C). We report here a mild radical procedure for the transformation of organoboranes to alkanes. 4-tert-Butylcatechol, a well-established radical inhibitor and antioxidant, is acting as a source of hydrogen atoms. An efficient chain reaction is observed due to the exceptional reactivity of phenoxyl radicals toward alkylboranes. The reaction has been applied to a wide range of organoboron derivatives such as B-alkylcatecholboranes, trialkylboranes, pinacolboronates, and alkylboronic acids. Furthermore, the so far elusive rate constants for the hydrogen transfer between secondary alkyl radical and catechol derivatives have been experimentally determined. Interestingly, they are less than 1 order of magnitude slower than that of tin hydride at 80 °C, making catechols particularly attractive for a wide range of transformations involving C-C bond formation.