首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   654篇
  免费   31篇
  国内免费   1篇
化学   445篇
晶体学   4篇
力学   10篇
数学   104篇
物理学   123篇
  2023年   10篇
  2022年   12篇
  2021年   18篇
  2020年   18篇
  2019年   20篇
  2018年   11篇
  2017年   13篇
  2016年   19篇
  2015年   21篇
  2014年   19篇
  2013年   41篇
  2012年   49篇
  2011年   33篇
  2010年   27篇
  2009年   26篇
  2008年   37篇
  2007年   32篇
  2006年   44篇
  2005年   49篇
  2004年   26篇
  2003年   26篇
  2002年   24篇
  2001年   12篇
  2000年   12篇
  1999年   10篇
  1998年   8篇
  1997年   6篇
  1996年   4篇
  1995年   4篇
  1994年   6篇
  1993年   2篇
  1991年   4篇
  1990年   3篇
  1988年   2篇
  1985年   5篇
  1984年   2篇
  1983年   4篇
  1982年   5篇
  1980年   1篇
  1979年   1篇
  1978年   2篇
  1977年   1篇
  1976年   1篇
  1975年   1篇
  1974年   5篇
  1973年   1篇
  1972年   1篇
  1966年   1篇
  1888年   1篇
  1887年   1篇
排序方式: 共有686条查询结果,搜索用时 62 毫秒
71.
A new cembranolide, acerolide (1) together with the known compound pseudopterolide (2) were isolated from the 2-propanol extract of the soft coral Pseudopterogorgia acerosa. The structure of 1 was determined on the basis of detailed spectroscopic analysis. Compound 1 showed moderate in vitro cytotoxicity against a panel of 14 tumor cell lines.  相似文献   
72.
We report the results of the Knight shift by ?3,??Cu-NMR measurements on single-layered copper-oxide Bi?Sr(?-x)La(x)CuO(?+δ) conducted under very high magnetic fields up to 44 T. The magnetic field suppresses superconductivity completely, and the pseudogap ground state is revealed. The ?3Cu-NMR Knight shift shows that there remains a finite density of states at the Fermi level in the zero-temperature limit, which indicates that the pseudogap ground state is a metallic state with a finite volume of Fermi surface. The residual density of states in the pseudogap ground state decreases with decreasing doping (increasing x) but remains quite large even at the vicinity of the magnetically ordered phase of x ≥ 0.8, which suggests that the density of states plunges to zero upon approaching the Mott insulating phase.  相似文献   
73.
In this paper we are interested in finding solvability conditions for Riemann and Dirichlet type boundary value problems with generalized Hölder-continuous boundary data in the case of hyperanalytic functions defined in a domain of the complex plane bounded by an h-summable closed curve.  相似文献   
74.
75.
Polymer Quantum Mechanics is based on some of the techniques used in the loop quantization of gravity that are adapted to describe systems possessing a finite number of degrees of freedom. It has been used in two ways: on one hand it has been used to represent some aspects of the loop quantization in a simpler context, and, on the other, it has been applied to each of the infinite mechanical modes of other systems. Indeed, this polymer approach was recently implemented for the free scalar field propagator. In this work we compute the polymer propagators of the free particle and a particle in a box; amusingly, just as in the non polymeric case, the one of the particle in a box may be computed also from that of the free particle using the method of images. We verify the propagators hereby obtained satisfy standard properties such as: consistency with initial conditions, composition and Green’s function character. Furthermore they are also shown to reduce to the usual Schrödinger propagators in the limit of small parameter μ0μ0, the length scale introduced in the polymer dynamics and which plays a role analog of that of Planck length in Quantum Gravity.  相似文献   
76.
A DC glow discharge produced in N2 gas can generate several species that are important in different applications, such as the modification of surface properties of materials. A low-pressure glow discharge apparatus was used for the the analysis of the Ar–N2 mixture at a total pressure of 2.0 Torr, a power of 20 W and 40 l/min flow rate of gases. The emission bands were measured in the wavelength range of 200–1100 nm. The principal elements are N2, N 2+ and Ar I. The electron temperature was found in the range of 1.72–2.08 eV, and the ion density was in the order of 1010 cm?3.  相似文献   
77.
Early warning systems for monitoring toxic events may benefit from the availability of monoclonal antibodies enabling the sensitive and specific detection of anatoxin‐a, a cyanotoxin involved in numerous cases of animal poisoning resulting from toxic algal blooms in freshwaters. Through the synthesis of three functionalized derivatives of anatoxin‐a, we have succeeded in generating the first‐ever reported immunoreagents (bioconjugates and antibodies) suitable for the development of immunoanalytical approaches aimed at rapid and onsite detection of this harmful cyanotoxin.  相似文献   
78.
We synthesized two bichromophoric difluoroboron-β-diketonates (DFB) connected in para and meta positions by using cyclohexane diamine as a chiral bridge ( para and meta (R/S)-CyDFB ). TD-DFT calculations revealed that the variation in connectivity of the DFB units leads to different spatial arrangements and a chirality inversion of the bichromophoric DFB. Higher gabs values were obtained in (R/S)-CyDFB connected in para as compared to meta position. Aggregation of para (R/S)-CyDFB in mixture of solvents increase the glum values as compared to its monomeric form. Ultrasonication and heating induced the formation of highly ordered nano-helical wires of para (R/S)-CyDFB that increased the glum values to 0.015. On the other hand, meta (R/S)-CyDFB failed to form highly ordered self-assembled wires due to hindered H-binding sites. These observations indicate that the chiroptical properties of DFB bi-chromophore system can be modulated with self-assembly and spatial arrangement of the chromophores.  相似文献   
79.
In this paper, a modified Cyclotriveratrylene was synthesized and linked to a branched Polyethylenimine, and this unique polymeric material was subsequently examined as a potential supramolecular carrier for Doxorubicin. Spectroscopic analysis in different solvents had shown that Doxorubicin was coordinated within the hollow-shaped unit of the armed Cyclotriveratrylene, and the nature of the host–guest complex revealed intrinsic Van der Waals interactions and hydrogen bonding between the host and guest. The strongest interaction was detected in water because of the hydrophobic effect shared between the aromatic groups of the Doxorubicin and Cyclotriveratrylene unit. Density functional theory calculations had also confirmed that in the most stable coordination of Doxorubicin with the cross-linked polymer, the aromatic rings of the Doxorubicin were localized toward the Cyclotriveratrylene core, while its aliphatic chains aligned closer with amino groups, thus forming a compact supramolecular assembly that may confer a shielding effect on Doxorubicin. These observations had emphasized the importance of supramolecular considerations when designing a novel drug delivery platform.  相似文献   
80.
Following ecological and chemical screenings, the Antarctic sponge Phorbas areolatus was chemically investigated for the first time. Three new suberitane derivatives named isosuberitenone B, 19-episuberitenone B, and isoxaspirosuberitenone were identified together with the known compounds suberitenones A and B, and oxaspirosuberitenone after a thorough inspection of their NMR data. These compounds were found to exhibit moderate cytotoxic activity and their presence in this sponge rules out their use as a chemotaxonomic marker for Suberites sponges.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号