基于扩展单粒子模型的锂离子电池参数识别策略

为了精确识别电动汽车锂离子动力电池的关键状态参数,基于多孔电极理论和浓度理论,建立了一种考虑液相动力学行为的锂离子电池扩展单粒子模型.相较于传统单粒子模型,该模型增加了对负电极表面固体电解质界面膜参数的描述,并考虑了温度和液相浓度变化对锂离子电池关键参数的耦合影响.基于所建立的扩展单粒子模型,提出一种简化的参数灵敏度分析方法和有效的锂电池参数识别策略,用以确定特定工况下的高灵敏度待识别参数,进而利用遗传算法实现参数的优化求解.最后,通过对比分析本文模型和传统单粒子模型的仿真输出电压和相同工况下电池的实验输出电压验证了提出模型和参数识别方法的有效性和可行性,为电池管理系统的健康状态估计提供了理论基础.     

二氧化硫在改性BC_3表面的吸附特性研究

采用基于密度泛函理论的第一性原理方法观察修饰不同原子(Mo,Pt,Si)来调控BC_3体系的表面结构和反应活性.研究发现:单个原子吸附在BC_3表面具有不同的稳定位,Pt和Si原子吸附在H1位稳定,而Mo原子吸附在H2位稳定.单个原子在完整结构BC_3表面的扩散势垒较小,而掺杂的原子在单空位缺陷BC_3体系中具有极高的稳定性( 6.5 eV),这些掺杂原子显正电性能够有效地调制BC_3体系的电子结构、磁性以及影响二氧化硫(SO_2)的吸附强弱.与Pt原子掺杂的BC_3体系(Pt-BC_3)相比,单个SO_2分子在Si-和Mo-BC_3体系上的吸附能较大,表现出较高的灵敏特性.该研究为设计类石墨烯基功能纳米材料提供参考.     

A New type of conserved quantity deduced from Mei symmetry of nonholonomic systems in terms of quasi-coordinates

This paper studies the new type of conserved quantity which is directly induced by Mei symmetry of nonholonomic systems in terms of quasi-coordinates. A coordination function is introduced, and the conditions for the existence of the new conserved quantities as well as their forms are proposed. Some special cases are given to illustrate the generalized significance of the new type conserved quantity. Finally, an illustrated example is given to show the application of the nonholonomic system's results.     

紧凑型自聚束微波电子枪设计研究

 提出一种新的紧凑型强流电子枪结构。紧凑型自聚束微波电子枪是一个多驻波腔结构,最大特点是腔与腔之间相互没有耦合,每腔可分别独立馈入功率和调节相位。通过选择合适的馈入功率和高频相位搭配,能够得到较优的束流品质。在此基础上采用外注入电子束的结构,能进一步增大流强和降低能散度,同时消除电子反轰对阴极工作的不利影响。利用Superfish和Parmela程序对腔体结构和束流动力学反复进行计算,确定了一组结构和工作参数。模拟结果表明出束微脉冲峰值流强可以到18 A,能散度小于2‰,横向发射度小于6 πmm·mrad。最后给出腔体冷侧结果,与模拟计算结果吻合得较好。     

沉淀方法对CeO2-ZrO2系储氧材料性能的影响

利用不同沉淀方法制备了一系列CeO2-ZrO2系储氧材料,并应用BET、XRD、TPR及其储氧性能测定等方法对储氧材料进行了研究.结果表明,不同的沉淀方法对样品的结构和性能有重要的影响.并流法可得到耐高温,储氧性能好,比表面积高的储氧材料;正滴法所得样品储氧量低但稳定,其比表面积抗老化性能差;反滴法所制备的样品储氧性能好,老化后比表面积较低.三种沉淀方法均可形成CeO2-ZrO2固溶体,材料的还原性能取决于比表面积,但与储氧性能无直接关系.     

A Facile Synthesis of NiFe-Layered Double Hydroxide and Mixed Metal Oxide with Excellent Microwave Absorption Properties

Microwave-absorbing materials have attracted increased research interest in recent years because of their core roles in the fields of electromagnetic (EM) pollution precaution and information security. In this paper, microwave-absorbing material NiFe-layered double hydroxide (NiFe-LDH) was synthesized by a simple co-precipitation method and calcined for the fabrication of NiFe-mixed metal oxide (NiFe-MMO). The phase structure and micromorphology of the NiFe-LDH and NiFe-MMO were analyzed, and their microwave-absorbing properties were investigated with a vector network analyzer in 2–18 GHz. Both NiFe-LDH and NiFe-MMO possessed abundant interfaces and a low dielectric constant, which were beneficial to electromagnetic wave absorption, owing to the synergistic effect of multi-relaxation and impedance matching. The optimum reflection loss (RL) of NiFe-LDH and NiFe-MMO was −58.8 dB and −64.4 dB, respectively, with the thickness of 4.0 mm in the C band. This work demonstrates that LDH-based materials have a potential application in electromagnetic wave absorption.     

Study of X(5568) in a unitary coupled-channel approximation of BK and B_sπ

The potential of the B meson and the pseudoscalar meson is constructed up to the next-to-leading order Lagrangian, and then the BK and B_sπ interaction is studied in the unitary coupled-channel approximation. A resonant state with a mass about 5568 MeV and J~P= 0~+is generated dynamically, which can be associated with the X(5568) state announced by the D0 Collaboration recently. The mass and the decay width of this resonant state depend on the regularization scale in the dimensional regularization scheme, or the maximum momentum in the momentum cutoff regularization scheme. The scattering amplitude of the vector B meson and the pseudoscalar meson is calculated, and an axial-vector state with a mass near 5620 MeV and J~P= 1~+is produced. Their partners in the charm sector are also discussed.     

Analysis on nonlinear turning motion of multi-spherical soft robots

A modular multi-spherical soft robot, which consists of five deformable spherical cells, two friction feet, the electromagnetic valves and the control systems, is constructed. According to the deflating action and the inflating action of the spherical cells, the size and the shape of each spherical cell can be changed. With two friction feet sticking with the ground in turn, the soft robot can move forwards, make a turning motion and avoid the obstacle. This paper creates a nonlinear relation between the pressure P and the inflation radius \(\left( r \right) \) at different original radii \(\left( {r_0 } \right) \) and obtains the inflation or deflation velocity \(v_r \). Six inflating and deflating steps to finish the turning motion are presented. Based on the geometric relationship between the inflation radius (r) and the original radius \((r_0 )\) of each cell, the nonlinear turning process is described to control the center positions (x, y, z) of the spherical cell. Last, a simulation and an experiment of five spherical cells are shown to emulate the turning process. Experiment results show that the robot has a maximum turning capability of \(20{^{\circ }}\) in one period.     

Characteristics of sealed plasma electrolytic oxidation coatings with electrochemical impedance spectroscopy

<正>Plasma electrolytic oxidation(PEO) coatings are prepared on aluminium with graphite powders added into the electrolyte.The scanning electron microscopy(SEM) coupled with an energy dispersive x-ray analysis system(EDX) is used to characterize the surface and the cross-section morphologies of the coatings.The electrochemical impedance spectroscopy(EIS) is used not only to evaluate the corrosion resistance but also to analyse the structure of the coating. Results show that graphite powders are embedded in the PEO coating.The corrosion resistances of both the inner barrier and the outer porous layer are greatly improved,and the EIS could give some valuable detailed information about the coating structure.